ChemicalBook--->CAS DataBase List--->613-45-6

613-45-6

613-45-6 Structure

613-45-6 Structure
IdentificationMore
[Name]

2,4-Dimethoxybenzaldehyde
[CAS]

613-45-6
[Synonyms]

2,4-DIMETHOXYBENZALDEHYDE
AKOS BBS-00003182
LABOTEST-BB LT00928518
2 4-DIMETHOXYBENZALDEHYDE 98% (GC)
2,4-Dimethoxy
Benzaldehyde, 2,4-dimethoxy-
β-resorcylaldehyde dimethyl ether
NSC 27023
2,4-Bis(methyloxy)benzaldehyde
[EINECS(EC#)]

210-342-4
[Molecular Formula]

C9H10O3
[MDL Number]

MFCD00003311
[Molecular Weight]

166.17
[MOL File]

613-45-6.mol
Chemical PropertiesBack Directory
[Appearance]

White Solid
[Melting point ]

67-69 °C (lit.)
[Boiling point ]

165 °C/10 mmHg (lit.)
[density ]

1.1708 (rough estimate)
[refractive index ]

1.5260 (estimate)
[Fp ]

165°C/10mm
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

Chloroform
[form ]

Fine Crystalline Powder
[color ]

White to slightly brown
[Water Solubility ]

insoluble
[Sensitive ]

Air Sensitive
[Usage]

A component of hair dyes
[BRN ]

607989
[InChI]

1S/C9H10O3/c1-11-8-4-3-7(6-10)9(5-8)12-2/h3-6H,1-2H3
[InChIKey]

LWRSYTXEQUUTKW-UHFFFAOYSA-N
[SMILES]

COc1ccc(C=O)c(OC)c1
[LogP]

1.660 (est)
[CAS DataBase Reference]

613-45-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzaldehyde, 2,4-dimethoxy-(613-45-6)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H335-H315-H319
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[HS Code ]

29124900
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

2,6-Dimethoxybenzaldehyde-->1,1-Dichlorodimethyl ether-->1,3-Dimethoxybenzene
[Preparation Products]

7-HYDROXYCOUMARIN-3-CARBOXYLIC ACID-->2,4-DIMETHOXYPHENETHYLAMINE-->2,4-Dimethoxybenzylamine-->Decanoic acid-->(R)-4-(2,4-diMethoxybenzyl)-3-Methylpiperazin-2-one-->METHYL 2,4-DIMETHOXYBENZOATE-->2,4-Dimethoxyphenylacetic acid-->3-Methoxy-2-nitrobenzaldehyde-->2,4-Dimethoxybenzyl alcohol-->2,4-Dimethoxybenzoic acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2,4-Dimethoxybenzaldehyde(613-45-6).msds
Hazard InformationBack Directory
[Chemical Properties]

White Solid
[Uses]

A component of hair dyes
[Reactions]

2,4-Dimethoxybenzaldehyde reacts specifically with 1,3-and 1,3,5-substituted phenols (e.g., phlorotannins) to form a colored product.
[Synthesis Reference(s)]

Synthesis, p. 166, 1984 DOI: 10.1055/s-1984-30768
[Hazard]

2,4-Dimethoxybenzaldehyde causes skin irritation and serious eye irritation, it may cause respiratory irritation.
[Synthesis]

Pyrophosphoryl chloride (2.266 g, 9 mmol) was added dropwise to a stirred mixture of cold (ice-bath) DMF (1.097 g, 15 mmol) and m-dimethoxybenzene (7.5 mmol) to give a thick green syrup. The mixture was heated at 65°C for 15 hours. The mixture was cooled
Spectrum DetailBack Directory
[Spectrum Detail]

2,4-Dimethoxybenzaldehyde(613-45-6)MS
2,4-Dimethoxybenzaldehyde(613-45-6)1HNMR
2,4-Dimethoxybenzaldehyde(613-45-6)13CNMR
2,4-Dimethoxybenzaldehyde(613-45-6)IR1
2,4-Dimethoxybenzaldehyde(613-45-6)IR2
2,4-Dimethoxybenzaldehyde(613-45-6)IR3
2,4-Dimethoxybenzaldehyde(613-45-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,4-Dimethoxybenzaldehyde, 98%(613-45-6)
[Alfa Aesar]

2,4-Dimethoxybenzaldehyde, 98%(613-45-6)
[Sigma Aldrich]

613-45-6(sigmaaldrich)
[TCI AMERICA]

2,4-Dimethoxybenzaldehyde,>98.0%(GC)(613-45-6)
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