| Identification | More | [Name]
1-Aminopyridinium iodide | [CAS]
6295-87-0 | [Synonyms]
1-AMINOPYRIDINIUM IODIDE
N-AMINOPYRIDINIUM IODIDE
pyridin-1-amine
Aminopyridinium iodide
N-Aminopyridiniumiodide,97%
Pyridin-1-ium-1-amine iodide
Pyridinium, 1-amino-, iodide | [EINECS(EC#)]
228-566-6 | [Molecular Formula]
C5H7IN2 | [MDL Number]
MFCD00051893 | [Molecular Weight]
222.03 | [MOL File]
6295-87-0.mol |
| Chemical Properties | Back Directory | [Appearance]
pinkish crystalline powder | [Melting point ]
159-161 °C(lit.)
| [density ]
1.8200 (estimate) | [storage temp. ]
2-8°C | [form ]
powder to crystal | [color ]
White to Light yellow to Light orange | [Water Solubility ]
Soluble in water (almost transparency). | [Sensitive ]
Light Sensitive | [BRN ]
3713241 | [Exposure limits]
ACGIH: TWA 0.01 ppm | [InChI]
InChI=1S/C5H7N2.HI/c6-7-4-2-1-3-5-7;/h1-5H,6H2;1H/q+1;/p-1 | [InChIKey]
NDRLPYIMWROJBG-UHFFFAOYSA-M | [SMILES]
[N+]1(N)C=CC=CC=1.[I-] | [CAS DataBase Reference]
6295-87-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
8-10-21 | [HS Code ]
29333990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
pinkish crystalline powder | [Uses]
1-Aminopyridinium iodide is a reagent used as a building block to construct fused heterocycles, synthesis of substituted pyridines, dipolar cycloadditions, ylide type reactions. | [General Description]
1-Aminopyridinium iodide, a pyridine derivative, is an important reagent for organic synthesis. It has various pharmaceutical applications. It participates in homogeneous transition metal-catalyzed reactions. Single-crystal X-ray diffraction studies suggest that the compound crystallizes in the monoclinic space group P21/c (phase II). Aza-ylide derived from 1-aminopyridinium iodide serves as a commercially available ammonia equivalent during the preparation of primary amines. |
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