| Identification | Back Directory | [Name]
Allylmagnesium chloride | [CAS]
2622-05-1 | [Synonyms]
Allylchloromagnesium
Chloroallylmagnesium
Allylmagnesiumchlorid
ALLYLMAGNESIUM CHLORIDE
Allyl chlorideMagnesiuM
chloro-2-propenyl-magnesiu
2-Propenylmagnesium chloride
Magnesium, chloro-2-propenyl-
Allylmagnesium chloride solution
solutionpurum,2mintetrahydrofuran
AllylMagnesiuM Chloride, 1M in THF
Allylmagnesium chloride, 1M in MeTHF
Allylmagnesium chloride, 1.0 M in THF
ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I
Allylmagnesium chloride, 1.0 M in 2-MeTHF
Allylmagnesium chloride 2M solution in THF
Allylmagnesium chloride 1M solution in DEE
Allylmagnesium chloride 1.5M solution in THF
Allylmagnesium chloride, 1.7M solution in THF
ALLYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF
Allylmagnesium Chloride 1.0 M In Tetrahydrofuran
Allylmagnesium Chloride 1.5 M in Tetrahydrofuran
Allylmagnesium chloride1.7M solution in THFAcroSeal§3
AllylMagnesiuM chloride, 1.7 M solution in THF, J&KSeal
Allylmagnesium chloride, 1.7M solution in THF, AcroSeal
AllylMagnesiuM chloride, 2.0 M solution in THF, SpcSeal
ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN
Allylmagnesium Chloride (10% in Tetrahydrofuran, ca. 1mol/L)
AllylMagnesiuM chloride, 1.7M solution in THF, AcroSeal 800ML
AllylMagnesiuM Chloride (ca. 9% in Tetrahydrofuran, ca. 0.9Mol/L)
Allylmagnesium Chloride (ca. 9% in Tetrahydrofuran, ca. 0.8mol/L)
Allylmagnesium Chloride (ca. 11% in Tetrahydrofuran, ca. 1.0mol/L) | [EINECS(EC#)]
220-067-1 | [Molecular Formula]
C3H5ClMg | [MDL Number]
MFCD00000473 | [MOL File]
2622-05-1.mol | [Molecular Weight]
100.83 |
| Chemical Properties | Back Directory | [Appearance]
clear tan to brown, amber, dark grey, dark green | [Melting point ]
-21°C | [Boiling point ]
66°C | [density ]
0.995 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
water-free area | [form ]
Liquid | [color ]
Clear tan to brown, amber, dark gray, dark green or black | [Water Solubility ]
vigorous reaction | [Sensitive ]
Air & Moisture Sensitive | [BRN ]
3587316 | [InChI]
InChI=1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1 | [InChIKey]
PLYLAFITHJUEGX-UHFFFAOYSA-M | [SMILES]
C([Mg]Cl)C=C | [EPA Substance Registry System]
Magnesium, chloro-2-propenyl-(2622-05-1) |
| Hazard Information | Back Directory | [Chemical Properties]
clear tan to brown, amber, dark grey, dark green | [Uses]
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Grignard-reactions: reagent for the introduction of the allyl group. | [Application]
Used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. | [reaction suitability]
reaction type: Grignard Reaction | [Synthesis]
Allylmagnesium chloride was prepared as follows: 20g of allyl chloride and 12vol of THF were added to the allyl halogenated alkane supply unit 11, and the mixture was shaken well, and the mixture was prepared for use. The temperature of the outer bath | [Precautions]
It reacts violently with water.
Air & moisture sensitive.
Stable under recommended storage conditions. |
|
|