| Identification | Back Directory | [Name]
Tetrabutylammonium periodate | [CAS]
65201-77-6 | [Synonyms]
Tetrabutylazanium periodate
TETRABUTYLAMMONIUM PERIODATE
Tetra-n-butylammoniumperiodate
TETRABUTYLAMMONIUM(META)PERIODAT
Tetrabutylammonium periodate,99%
TETRABUTYLAMMONIUM (META)PERIODATE
Tetrabutylaminium·periodic acidanion
Tetra-n-butylaMMoniuM (Meta)periodate, 97%
TETRABUTYLAMMONIUM (META)PERIODATE, MOIS T. W. ~10% WATER
1-Butanaminium, N,N,N-tributyl-, salt with periodic acid (1:1) | [EINECS(EC#)]
265-614-5 | [Molecular Formula]
C16H36INO4 | [MDL Number]
MFCD00011852 | [MOL File]
65201-77-6.mol | [Molecular Weight]
433.37 |
| Chemical Properties | Back Directory | [Appearance]
yellow crystalline powder | [Melting point ]
175 °C (dec.)(lit.)
| [density ]
1.2302 (estimate) | [storage temp. ]
Storage temp. 2-8°C | [solubility ]
Chloroform (Slightly), DMSO (Slightly) | [form ]
solid | [BRN ]
4621593 | [InChI]
1S/C16H36N.HIO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1 | [InChIKey]
PYVXLMQALOZKES-UHFFFAOYSA-M | [SMILES]
[O-]I(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC |
| Hazard Information | Back Directory | [Chemical Properties]
yellow crystalline powder | [Description]
Tetrabutylammonium periodate is useful reagent in oxidation of sulfides, phenacyl bromides, benzyl halides, phosphites; oxidative decarboxylation; co-oxidant in metal-catalyzed oxidation. | [Uses]
Tetrabutylammonium (meta)periodate (DCM) can be oxidated for the synthesis of aryl nitroso derivatives. It can also be used in the formation of an ionic liquid for the synthesis of aromatic carboxylic acids. | [reaction suitability]
reagent type: oxidant | [storage]
Tetrabutylammonium periodate is best stored in the dark because it readily turns yellow on exposure to light. There is no loss of oxidizing power on prolonged storage. |
| Safety Data | Back Directory | [Hazard Codes ]
O,Xi,Xn | [Risk Statements ]
8-36/37/38-20/22 | [Safety Statements ]
17-26-36-37/39 | [RIDADR ]
UN 1479 5.1/PG 2
| [WGK Germany ]
3
| [F ]
8 | [HazardClass ]
4.1 | [PackingGroup ]
II | [HS Code ]
29239000 | [Storage Class]
5.1B - Oxidizing hazardous materials | [Hazard Classifications]
Eye Irrit. 2
Ox. Sol. 2
Skin Irrit. 2
STOT SE 3 |
|
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Rhawn Reagent
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400-400-1332688 18019345275 |
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http://www.rhawn.cn |
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