| Identification | More | [Name]
2-Furfurylthio-3-methylpyrazine | [CAS]
65530-53-2 | [Synonyms]
2-FURFURYLTHIO-3(5/6)-METHYL PYRAZINE
2-FURFURYLTHIO-3-METHYLPYRAZINE
2-METHYL-3(5/6)(FURFURYLTHIO) PYRAZINE
2-METHYL-3(5)(6)-FURFURYLTHIOPYRAZINE MIXTURE
2-METHYL-3,5 OR 6-(FURFURYLTHIO)-PYRAZINE
FEMA 3189
FEMA NUMBER 3189
FURFURYLTHIO-3-METHYLPYRAZINE
METHYL(FURFURYLTHIO)PYRAZINE
2-FURFURYLTHIO-( 3 OR 5)-METHYLPYRAZINE
2-FURFURYLTHIO-3(OR5OR6)METHYL PYRAZINE FEMA NO.3189
2-Furfurylthio-3(or5or6)methylpyrazine]
Femano.3189
Pyrazine, (3-furanylmethyl)thiomethyl-
3-FURFURYLTHIO-2-METHYLPYRAZINE | [EINECS(EC#)]
267-918-3 | [Molecular Formula]
C10H10N2OS | [MDL Number]
MFCD00055031 | [Molecular Weight]
206.26 | [MOL File]
65530-53-2.mol |
| Chemical Properties | Back Directory | [density ]
1.210 g/mL at 25 °C | [FEMA ]
3189 | [refractive index ]
n20/D1.600 | [Fp ]
110 °C | [Odor]
at 0.10 % in dipropylene glycol. sulfurous nutty roasted coffee cooked meat | [Odor Type]
coffee | [JECFA Number]
1082 | [InChI]
InChI=1S/C10H10N2OS/c1-8-10(12-5-4-11-8)14-7-9-3-2-6-13-9/h2-6H,7H2,1H3 | [InChIKey]
PFRSWMCUERVSAT-UHFFFAOYSA-N | [SMILES]
C1(SCC2OC=CC=2)=NC=CN=C1C | [LogP]
1.97 | [CAS DataBase Reference]
65530-53-2(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid with aroma like roasted coffee. Boiling point 153 ~ 156 ℃ (1333Pa). Refractive index (nD20) 1.5970. | [Uses]
GB 2760--1996 stipulates that 2-Furfurylthio-3-methylpyrazine is temporarily allowed to use food spices. | [Definition]
ChEBI: 2-Methyl-3 or 5 or 6-(furfurylthio)pyrazine (mixture of isomers) is an aryl sulfide. | [Research]
FFM as a food spice is in accord with GB 2760 -1996 standard. It can be used for soft drinks, cold drinks, baked goods, and seasonings. Therefore, the damage caused by 2-Furfurylthio-3-methylpyrazine (FFM) as a corrosion inhibitor to humans and the ecological environment is very small. In addition, FFM has good solubility in 0.5 mol/L H 2SO. Electrochemical experiment data show that FFM can exhibit a prominent anti-corrosion nature for copper in H 2SO 4 medium in the temperature range of 298 K to 313 K . Potentiodynamic polarization curve results show that the corrosion inhibition efficiency of FFM can be as high as 97.9% at a concentration of 5 mmol/L. The surface morphology test results show that adding 5 mmol/L FFM in H 2SO 4 medium makes the copper sample relatively flat after soaking for 20 hours, and the roughness value is only 7.84 nm. The XPS experimental results show that the S and N atoms in the FFM molecule can form N -Cu and S -Cu bonds on the copper surface to generate chemical adsorption. Besides, the FFM adsorption on the copper/solution surface[1].
| [References]
[1] Lei Guo . “Eco-friendly food spice 2-Furfurylthio-3-methylpyrazine as an excellent inhibitor for copper corrosion in sulfuric acid medium.” Journal of Molecular Liquids 317 (2020): Article 113915.
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