ChemicalBook--->CAS DataBase List--->660-68-4

660-68-4

660-68-4 Structure

660-68-4 Structure
IdentificationMore
[Name]

Diethylamine hydrochloride
[CAS]

660-68-4
[Synonyms]

3,7-BIS(DIMETHYLAMINO)-5-PHENOTHIAZINIUM CHLORIDE
3,7-BIS(DIMETHYLAMINO)PHENAZATHIONIUM CHLORIDE
3,7-BIS(DIMETHYLAMINO)PHENOTHIAZIN-5-IUM CHLORIDE
BASIC BLUE 9
CALCOZINE BLUE ZF
CI 52015
CI BASIC BLUE 9
CI NO 52015
DIETHYLAMINE HCL
DIETHYLAMINE HYDROCHLORIDE
DIETHYLAMINONIUM CHLORIDE
DIETHYLAMMONIUM CHLORIDE
DNA-DYE METHYLENE BLUE
EHRLICH'S REAGENT III
LOEFFLER'S METHYLENE BLUE
METHYLENE BLUE
METHYLENE BLUE 2B
METHYLENE BLUE ACCORDING TO EHRLICH
METHYLENE BLUE ACCORDING TO LOFFLER
METHYLENE BLUE ALKALINE LOEFFLER
[EINECS(EC#)]

200-515-2
[Molecular Formula]

C4H12ClN
[MDL Number]

MFCD00012111
[Molecular Weight]

109.6
[MOL File]

660-68-4.mol
Chemical PropertiesBack Directory
[Appearance]

white to off-white crystals or crystalline powder
[Melting point ]

227-230 °C(lit.)
[Boiling point ]

320-330 °C
[bulk density]

1100kg/m3
[density ]

1.0 g/mL at 20 °C
[vapor pressure ]

<0.00001 hPa (20 °C)
[refractive index ]

1.5320 (estimate)
[Fp ]

320-330°C
[storage temp. ]

Store below +30°C.
[solubility ]

H2O: soluble50mg/mL, clear, colorless
[form ]

Liquid
[color ]

White to off-white
[Specific Gravity]

1.0475 (21℃)
[PH]

4.5-6.5 (10g/l, H2O, 20℃)
[Water Solubility ]

soluble
[Sensitive ]

Hygroscopic
[Merck ]

14,3111
[BRN ]

3590084
[InChI]

1S/C4H11N.ClH/c1-3-5-4-2;/h5H,3-4H2,1-2H3;1H
[InChIKey]

HDITUCONWLWUJR-UHFFFAOYSA-N
[SMILES]

Cl.CCNCC
[LogP]

-1.3 at 20℃
[CAS DataBase Reference]

660-68-4(CAS DataBase Reference)
[EPA Substance Registry System]

660-68-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S7:Keep container tightly closed .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[RTECS ]

SP5740000
[F ]

21
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29211200
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Skin Corr. 1A
Skin Sens. 1
STOT SE 3
[Toxicity]

LD50 orally in Rabbit: 9900 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethylamine-->Phosphinous amide, P,P-bis(3,5-dimethylphenyl)-N,N-diethyl--->Bis(3,5-dimethylphenyl)chlorophosphine-->tert-butyl 4-phenylpiperidine-1-carboxylate-->4-Phenylpiperidine
[Preparation Products]

N-(Carboxymethyl)-N-(phosphonomethyl)-glycine-->N,N-Diethyldecanamide-->1-Diethylamino-3-butanone-->1,1-Diethylurea-->N,N-Diethylcyclohexylamine-->Diethyl (trichloromethyl)phosphonate-->Oxolamine-->Bis(diethylamino)chlorophosphine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Diethylamine hydrochloride(660-68-4).msds
Hazard InformationBack Directory
[Chemical Properties]

white to off-white crystals or crystalline powder
[Uses]

Diethylamine hydrochloride acts as a precursor of atrazine and lysergic acid diethylamide. It is also used as a reactant in the production of dyes and pharmaceutical compounds such as ranitidine. Further, it is used in Mannich reaction with paraformaldehyde. In addition to this, it is employed in the synthesis of diethylaminoethyl (DEAE) cottons by reacting with cotton cellulose in the presence of sodium hydroxide.
[Flammability and Explosibility]

Notclassified
[Purification Methods]

Crystallise salt from absolute EtOH. Also crystallise it from dichloroethane/MeOH. Hygroscopic. [Beilstein 4 III 113.]
Spectrum DetailBack Directory
[Spectrum Detail]

Diethylamine hydrochloride(660-68-4)MS
Diethylamine hydrochloride(660-68-4)1HNMR
Diethylamine hydrochloride(660-68-4)13CNMR
Diethylamine hydrochloride(660-68-4)IR1
Diethylamine hydrochloride(660-68-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Diethylamine hydrochloride, 99%(660-68-4)
[Alfa Aesar]

Diethylamine hydrochloride, 99%(660-68-4)
[Sigma Aldrich]

660-68-4(sigmaaldrich)
[TCI AMERICA]

Diethylamine Hydrochloride,>98.5%(T)(660-68-4)
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