ChemicalBook--->CAS DataBase List--->557-66-4

557-66-4

557-66-4 Structure

557-66-4 Structure
IdentificationMore
[Name]

Ethylamine hydrochloride
[CAS]

557-66-4
[Synonyms]

AMINOETHANE HYDROCHLORIDE
ETHANAMINE HYDROCHLORIDE
ETHYLAMINE HCL
ETHYLAMINE HYDROCHLORIDE
ETHYLAMMONIUM CHLORIDE
MONOETHYLAMINE HCL
MONOETHYLAMINE HYDROCHLORIDE
monoethylammoniumchloride
ETHYLAMINE HYDROCHLORIDE, CRYSTALLIZED
MonethylamineHCl
Ethylammoniumchlorid
[EINECS(EC#)]

209-182-8
[Molecular Formula]

C2H8ClN
[MDL Number]

MFCD00012885
[Molecular Weight]

81.54
[MOL File]

557-66-4.mol
Chemical PropertiesBack Directory
[Appearance]

white to off-white crystals
[Melting point ]

107-108 °C(lit.)
[Boiling point ]

95.79°C (rough estimate)
[density ]

1,22 g/cm3
[refractive index ]

1.4202 (estimate)
[storage temp. ]

Store below +30°C.
[solubility ]

soluble
[form ]

Solid
[color ]

White to Off-White
[Water Solubility ]

soluble
[Sensitive ]

Hygroscopic
[Merck ]

14,3762
[BRN ]

3589312
[Stability:]

Hygroscopic
[InChI]

1S/C2H7N.ClH/c1-2-3;/h2-3H2,1H3;1H
[InChIKey]

XWBDWHCCBGMXKG-UHFFFAOYSA-N
[SMILES]

Cl[H].CCN
[CAS DataBase Reference]

557-66-4(CAS DataBase Reference)
[Storage Precautions]

Store under nitrogen
[EPA Substance Registry System]

557-66-4(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

1
[RTECS ]

KH2495000
[F ]

3-10-23
[TSCA ]

Yes
[HS Code ]

29211980
[Storage Class]

11 - Combustible Solids
[Toxicity]

LD50 orally in Rabbit: > 3200 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

N-Tritylethanamine-->Nitroethane-->2-Bromoethylamine hydrobromide
[Preparation Products]

4-(Ethylaminomethyl)pyridine-->Hexamethyldisiloxane-->N-Ethylcyclohexylamine-->N-Ethylglycine-->N-Ethyl 2-nitro-4-(trifluoromethyl)aniline-->6-Chloro-N~4~-ethylpyrimidine-2,4-diamine-->BenzaMide, N-ethyl-3-nitro--->2-(ethylamino)-2-methylpropanenitrile-->3-Thiophenecarboxamide,N-ethyl-(9CI)
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Ethylammonium chloride(557-66-4).msds
Hazard InformationBack Directory
[Chemical Properties]

white to off-white crystals
[Uses]

Ethylamine Hydrochloride a chemical used in various chemical organic syntheses and biological studies. It is used in production of resins and rubber latex; also used in oil refining and organic syntheses.
[Application]

Ethylaminehydrochloride is used as a raw material for organic synthesis. Its free base ethylamine is used in the diethyldiazene, dimethylolethyltriazone, ethylcyanopyrolidone disperse and 1,3-diethylthiourea. It is a precursor used for the preparation of benzilnitrate, detergents, rayon, rocket propellant and alkyl isocyanates, which finds application in the manufacture of pharmaceuticals.
[Preparation]

Ethylamine can be synthesized by ethanol and ammonia are combined in the presence of an oxide catalyst:
CH3CH2OH + NH3 → CH3CH2NH2 + H2O
Ethylamine could then be solvent extracted or boiled out of hoffman turned to Hydrochloride with HCl and then freebased with caustic to be distilled pure.
of course an excess of caustic when freebasing would be a good idea as it would hold onto most of the water created from the basing of a hydrochloride with caustic.
[Purification Methods]

Crystallise the hydrochloride from absolute EtOH or MeOH/CHCl3, wash with dry ether and dry it in a vacuum. [Beilstein 4 IV 310.]
[Precautions]

Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
Spectrum DetailBack Directory
[Spectrum Detail]

Ethylamine hydrochloride(557-66-4)MS
Ethylamine hydrochloride(557-66-4)1HNMR
Ethylamine hydrochloride(557-66-4)IR1
Ethylamine hydrochloride(557-66-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ethylamine hydrochloride, 99%(557-66-4)
[Alfa Aesar]

Ethylamine hydrochloride, 98%(557-66-4)
[Sigma Aldrich]

557-66-4(sigmaaldrich)
[TCI AMERICA]

Ethylamine Hydrochloride,>98.5%(T)(557-66-4)
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