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667-27-6

667-27-6 Structure

667-27-6 Structure
IdentificationMore
[Name]

Ethyl bromodifluoroacetate
[CAS]

667-27-6
[Synonyms]

BROMODIFLUOROACETIC ACID ETHYL ESTER
ETHYL BROMODIFLUOROACETATE
Acetic acid, bromodifluoro-, ethyl ester
2,2-difluoro-2-bromoacetate ethyl
Ethyl bromodifluoroacetate 98%
difluorobromo ethyl acetate
Ethylbromodifluoroacetate98%
Ethyl 2,2-difluoro-2-bromoacetate
Acetic acid, 2-bromo-2,2-difluoro-, ethyl ester
2-Bromo-2,2-difluoroacetic acid ethyl ester
Difluorobromoacetic acid ethyl ester
[EINECS(EC#)]

211-567-0
[Molecular Formula]

C4H5BrF2O2
[MDL Number]

MFCD00042069
[Molecular Weight]

202.98
[MOL File]

667-27-6.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to slightly yellow liquid
[Boiling point ]

112 °C/700 mmHg (lit.)
[bp ]

112 °C700 mm Hg(lit.)
[density ]

1.583 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.387(lit.)
[Fp ]

70 °F
[storage temp. ]

Flammables area
[solubility ]

Soluble in most organic solvents.
[form ]

Liquid
[color ]

Clear colorless to slightly yellow
[Specific Gravity]

1.583
[BRN ]

1906095
[InChIKey]

IRSJDVYTJUCXRV-UHFFFAOYSA-N
[CAS DataBase Reference]

667-27-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethyl bromodifluoroacetate(667-27-6)
Safety DataBack Directory
[Hazard Codes ]

C,F,Xi
[Risk Statements ]

R10:Flammable.
R34:Causes burns.
R36:Irritating to the eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S16:Keep away from sources of ignition-No smoking .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 2924 3/PG 2
[WGK Germany ]

3
[Hazard Note ]

Irritant/Flammable
[TSCA ]

No
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29159000
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Ethyl bromodifluoroacetate(667-27-6).msds
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to slightly yellow liquid
[Uses]

Efficient difluoroalkylation of aryl boronic acids via palladium catalysis. Novel, moisture-stable bromodifluoromethylated phosphonate, ester, and amide. Efficient coupling with aryl boronic acids via Pd catalysis.
[Uses]

Ethyl bromodifluoroacetate is usually used in the preparation of substituted ethyl 2′-pyridyldifluoroacetates,4-alkoxymethyl- and 4-aryloxymethyl-3,3-difluoropiperidines,α,α-difluoro-β-lactams,mono- and difluoromethylated phenanthridine derivatives.
Spectrum DetailBack Directory
[Spectrum Detail]

Ethyl bromodifluoroacetate(667-27-6) 13C NMR
Ethyl bromodifluoroacetate(667-27-6) 1H NMR
Ethyl bromodifluoroacetate(667-27-6) IR1
Ethyl bromodifluoroacetate(667-27-6) MS
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ethyl bromodifluoroacetate, 98%(667-27-6)
[Alfa Aesar]

Ethyl bromodifluoroacetate, 97%(667-27-6)
[Sigma Aldrich]

667-27-6(sigmaaldrich)
[TCI AMERICA]

Ethyl Bromodifluoroacetate,>97.0%(GC)(667-27-6)
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