| Identification | More | [Name]
N-(1-Cyclohexen-1-yl)morpholine | [CAS]
670-80-4 | [Synonyms]
1-(4-MORPHOLINO)CYCLOHEXENE
1-MORPHOLINO-1-CYCLOHEXENE
1-MORPHOLINOCYCLOHEXENE
1-(N-MORPHOLINO)CYCLOHEXENE
4-(1-CYCLOHEXEN-1-YL)MORPHOLINE
4-CYCLOHEX-1-ENYLMORPHOLINE
4-(CYCLOHEXEN-1-YL)MORPHOLINE
AKOS BBS-00000855
MORPHOLINE, 4-(1-CYCLOHEXEN-1-YL)-
N-(1-CYCLOHEXEN-1-YL)MORPHOLINE
N-MORPHOLINO-1-CYCLOHEXENE
1(1-Cyclohexenyl)morpholine
1-Morpholin-1-ylcyclohexene
4-(1-cyclohexen-1-yl)-morpholin
4-(1-Cyclohexenyl)morpholine
Cyclohexanone morpholine enamine
Morpholinocyclohexene
N-(cyclohex-1-en-1-yl)morpholine
4-cyclohexenylmorpholine
1-(N-morpholino)cyclohexane | [EINECS(EC#)]
211-579-6 | [Molecular Formula]
C10H17NO | [MDL Number]
MFCD00006163 | [Molecular Weight]
167.25 | [MOL File]
670-80-4.mol |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
9 | [TSCA ]
Yes | [HS Code ]
29349990 |
| Hazard Information | Back Directory | [Description]
1-Morpholinocyclohexene (N-(1-Cyclohexen-1-yl)morpholine) falls under the category of organic compounds called morpholine class of heterocyclic amines. This colorless liquid possesses a distinct amine-like odor and displays remarkable versatility with widespread applications in multiple industries, including agrochemicals and cosmetics. Moreover, it is a valuable solvent, corrosion inhibitor, and integral component in lubricants[1].
| [Chemical Properties]
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID | [Synthesis Reference(s)]
Synthesis, p. 529, 1984 DOI: 10.1055/s-1984-30893 | [Synthesis]
The general procedure for the synthesis of 1-morpholino-1-cyclohexene from morpholine and cyclohexanone is as follows: to a solution of morpholine (10.5 mL, 0.12 mol, 1.2 eq.) in anhydrous toluene (70 mL) was added cyclohexanone (10.4 mL, 0.10 mol, 1.0 eq.), followed by the addition of p-toluenesulfonic acid (0.20 g, 1.16 mmol. 0.016 eq.) as a catalyst. The reaction mixture was heated to reflux for 5 hours. Upon completion of the reaction, the reaction solution was cooled and subsequently concentrated under reduced pressure to afford the target product 1-morpholino-1-cyclohexene in 85% yield. | [References]
[1] R. Nesi. “Reactions of 3,5-dimethyl-4-nitroisoxazole with cyclic enamines and 1-diethylaminopropyne.” Heterocycles 32 1 (1991): 1913–1921.
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