ChemicalBook--->CAS DataBase List--->68603-42-9

68603-42-9

68603-42-9 Structure

68603-42-9 Structure
IdentificationBack Directory
[Name]

Coconut diethanolamide
[CAS]

68603-42-9
[Synonyms]

ethylanld
nci-c55312
ninol2012e
COCAMIDE DEA
clindrol200cgn
clindrol202cgn
COCO DIETHANOLAMIDE
coconutdiethanolamine
COCONUT DIETHANOLAMIDE
COCAMIDE DIETHANOLAMINE
clindrolsuperamide100cg
Coconutoildiethanolamide
Coconut oil alkanolamide
Coconutoil,diethanolamide
Coconutacid,diethanolamide
COCOFATTYACIDDIETHANOLAMINE
Coconut diethanolaMide (CDEA)
COCAMIDE DIETHANOLAMINE (DEA)
Coconutoilacid,diethanolamide
Coconutoilacidsdiethanolamide
Coconutoilacids,diethanolamide
Coco fatty acid diethanolamide
Palm Kernel Oil Dieathanolamide
Coconutfattyacidsdiethanolamide
coconut oil acid diethanolamine
N,N-Bis(hydroxyethyl)coco amides
N,N-BIS(2-HYDROXYETHYL)COCOAMIDE
Coconutoilfattyaciddiethanolamide
Amides,coco,N,N-bis(hydroxyethyl)
Coconutoilfattyacid,diethanolamide
Coconutoilfattyacidsdiethanolamide
Coconutoilfattyacids,diethanolamide
COCONUT OIL AMIDE OF DIETHANOLAMINE
amides,coco,n,n-bis(2-hydroxyethyl)
coconutoilaciddiethanolamine(con2/1)
Coconutfattyacidamideofdiethanolamine
Amide, Kokos-, N,N-Bis(hydroxyethyl)-
n,n-bis(hydroxyethyl)coco fatty amides
N,N-bis(2-Hydroxyethyl)coconutoilamide
N,N-bis(2-hydroxyethyl)-Coconutoilamide
Coconut oil acid-diethanolamine condensate
coconutoilaciddiethanolaminecondensate(2/1)
n,n-bis(2-hydroxyethyl)coconutfattyacidamide
[EINECS(EC#)]

271-657-0
[Molecular Formula]

no
[MDL Number]

MFCD01779098
Chemical PropertiesBack Directory
[Appearance]

viscous yellow to amber liquid
[Boiling point ]

168-274°C
[density ]

0.98 g/cm3
[refractive index ]

1.4697-1.4816
[Fp ]

149 °C
[Odor]

at 100.00?%. mild ammonia
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents.
[Water Solubility ]

5-10 g/100 mL at 18 ºC
[Cosmetics Ingredients Functions]

SURFACTANT - CLEANSING
SURFACTANT - FOAM BOOSTING
EMULSION STABILISING
VISCOSITY CONTROLLING
SURFACTANT - EMULSIFYING
[Cosmetic Ingredient Review (CIR)]

Coconut diethanolamide (68603-42-9)
[Contact allergens]

Cocamide DEA, manufactured from coconut oil, is widely used in industry and at home as a surface-active agent. It is contained in hand gels, hand washing soaps, shampoos, and dish-washing liquids for its foam-producing and stabilizing properties, and in metal working fluids and polishing agents as an anticorrosion inhibitor.
[Uses]

cocamide DEA is a thickener and viscosity builder for cosmetic surfactant systems. It is added to lauryl sulfate-based liquid cleansers to help stabilize the lather and improve foam formation.
[IARC]

2B (Vol. 101) 2013
[EPA Substance Registry System]

Amides, coco, N,N-bis(hydroxyethyl)(68603-42-9)
Hazard InformationBack Directory
[Chemical Properties]

viscous yellow to amber liquid
[General Description]

Viscous amber or yellow liquid. pH (1% aqueous solution) 9.
[Air & Water Reactions]

Water soluble. Foams in water.
[Reactivity Profile]

Coconut diethanolamide is a mixture of amines. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
[Fire Hazard]

Coconut diethanolamide is probably combustible.
[Hazard]

A poison by ingestion. A moderate skin irritant.
[Description]

Cocamide DEA is also named N,N-bis(2-hydroxyethyl) coco fatty acid diethanolamide, coconut fatty acid diethanolamide, cocoyl diethanolamide, and coconut oil acid diethanolamide. It is manufactured from coconut oil and is widely used in industry and at horne as a surface-active agent. It is contained in hand gels, handwashing soaps, shampoos and dish-washing liquids for its foam-producing and stabilizing properties, and in metalworking fluids and polishing agents as an anticorrosion inhibitor.
[Application]

Coconut diethanolamide(68603-42-9) has the properties of wetting, washing, emulsifying, softening, etc. It has good foam stabilising effect on anionic surfactants. It is an indispensable raw material for a variety of cosmetic products such as liquid detergents, liquid soaps, shampoos, cleansers and cleansers. When used with soap, it is resistant to hard water.
It can also be used as an emulsifying stabiliser for cream products, and is widely used in shoe polish, printing inks, drawing supplies and so on.
It is used in the textile printing and dyeing industry as a detergent for fabrics, as well as other detergent ingredients and thickeners.
It is one of the components of spinning oil for synthetic fibres such as polypropylene. It has a good thickening effect on liquid products using anionic surfactants as the main raw material.
It has a certain antistatic conditioning effect and is less irritating to the skin.
It is widely used as an emulsifier for oily raw materials in various cosmetics and surfactant products. It is commonly used in cosmetic formulations for bath oils, shampoos, conditioners, lipsticks and hair dyes. It is also a surfactant in soap bars, light detergents and dishwashing detergents, and a degreasing agent for cottonseed.
[Synthesis]

Coconut diethanolamide is produced by the condensation reaction of an appropriate fatty acid (methyl cocoate, coconut oil, whole coconut acid, or stripped coconut fatty acids) with diethanolamine in 1:1 or 1:2 molar ratios using temperatures up to 170°C and in the presence of an alkaline catalyst. The 1:2 mixtures of fatty acids (or methyl fatty acids) with diethanolamine result in low quality diethanolamides with residual ethylene glycol and free diethanolamine. 1:1 mixtures produce higher quality diethanolamides with much less free amine, and are therefore used in lower concentrations than the 1:2 diethanolamides.
[References]

[1] XIANGHONG LI Guanben D Shuduan Deng. Nonionic surfactant of coconut diethanolamide as a novel corrosion inhibitor for cold rolled steel in both HCl and H2SO4 solutions[J]. Journal of the Taiwan Institute of Chemical Engineers, 2022, 131: Article 104171. DOI:10.1016/j.jtice.2021.104171.
[2] ANNE PINOLA. Occupational allergic contact dermatitis due to coconut diethanolamide (cocamide DEA)[J]. Contact Dermatitis, 1993, 29 5: 262-265. DOI:10.1111/j.1600-0536.1993.tb03562.x.
[3] MD J F F J. Allergy to cocamide DEA[J]. American Journal of Contact Dermatitis, 1998, 9 1: Pages 40-41. DOI:10.1016/S1046-199X(98)90144-0.
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H318-H315
[Precautionary statements ]

P280-P305+P351+P338-P310-P264-P280-P302+P352-P321-P332+P313-P362
[TSCA ]

TSCA listed
[Safety Profile]

A poison by ingestion. A moderate skin irritant. Questionable carcinogen with experimental Carcinogenic data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
[Hazardous Substances Data]

68603-42-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Coconut oil-->Diethanolamine-->fatty acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Coconut diethanolamide (68603-42-9).msds
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