ChemicalBook--->CAS DataBase List--->75-22-9

75-22-9

75-22-9 Structure

75-22-9 Structure
IdentificationMore
[Name]

Borane-trimethylamine complex
[CAS]

75-22-9
[Synonyms]

BORANE-TRIMETHYLAMINE
BORANE-TRIMETHYLAMINE COMPLEX
BORON HYDRIDE TRIMETHYLAMINE
TMAB
TRIMETHYLAMINE BORANE
Trimethylamine borane (1:1)
(CH3)3NBH3
Borane, compd. with N,N-dimethylmethanamine (1:1)
Borane, compd. with trimethylamine (1:1)
borane,compd.withn,n-dimethylmethanamine(1:1)
borane,compd.withtrimethylamine(1:1)
Methanamine, N,N-dimethyl-, compd. with borane (1:1)
n,n-dimethyl-methanamincompd.withborane(1:1)
n-dimethylmethanamine)trihydro-((beta-4)-boro
n-dimethylmethanamine)trihydro-((t-4)-boro
Trimethylamine, compd. with borane (1:1)
trimethylamine,compd.withborane(1:1)
trimethylamine-borane(3)complex(1:1)
Trimethylamine-borane(3)-complex(1:1)
trimethylamineborane,tmab
[EINECS(EC#)]

200-850-4
[Molecular Formula]

C3H12BN
[MDL Number]

MFCD00012420
[Molecular Weight]

72.95
[MOL File]

75-22-9.mol
Chemical PropertiesBack Directory
[Appearance]

white crystalline powder
[Melting point ]

92-94 °C(lit.)
[Boiling point ]

172 °C(lit.)
[density ]

0.81
[Fp ]

64°C
[storage temp. ]

Refrigerator
[form ]

Powder, Crystals and/or Chunks
[color ]

White
[Water Solubility ]

decomposes
[Sensitive ]

Moisture Sensitive
[BRN ]

3905060
[InChI]

InChI=1S/C3H12BN/c1-5(2,3)4/h1-4H3
[InChIKey]

KQVSXUGMDCAISO-UHFFFAOYSA-N
[SMILES]

[N+]([BH3-])(C)(C)C
[CAS DataBase Reference]

75-22-9(CAS DataBase Reference)
[NIST Chemistry Reference]

Boron, (N,N-dimethylmethanamine)trihydro-(75-22-9)
[EPA Substance Registry System]

75-22-9(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Danger
[Hazard statements ]

H228-H315-H319-H335
[Precautionary statements ]

P210-P302+P352-P305+P351+P338
[Hazard Codes ]

F,Xn,Xi
[Risk Statements ]

R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S14:Keep away from ... (incompatible materials to be indicated by the manufacturer) .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S33:Take precautionary measures against static discharges .
[RIDADR ]

UN 1325 4.1/PG 2
[WGK Germany ]

3
[RTECS ]

PA0525000
[F ]

10-21
[TSCA ]

Yes
[HazardClass ]

4.1
[PackingGroup ]

II
[HS Code ]

29420000
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Borane-trimethylamine complex(75-22-9).msds
Hazard InformationBack Directory
[Chemical Properties]

white crystalline powder
[Uses]

Reducing agent for the preparation of plate-type palladium-zinc oxide catalys, reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents. Catalyst for regioselective reductive opening of benzylidene acetal glycosides and polarity reversal.
[reaction suitability]

reagent type: reductant
[Purification Methods]

It is sublimed using equipment described in Burg and Schlesinger [J Am Chem Soc 59 780 1937I]. Its vapour pressure is 86mm at 100o. It forms colourless hexagonal crystals varying from needles to short lumps, which are slightly soluble in H2O (1.48% at 30o), EtOH (1%), hexane (0.74%) but very soluble in Et2O, *C6H6 and AcOH. It is stable at 125o. [Burg & Schlesinger J Am Chem Soc 59 780 1937, Brown et al. J Am Chem Soc 104 325 1942, Beilstein 4 IV 140.]
Spectrum DetailBack Directory
[Spectrum Detail]

Borane-trimethylamine complex(75-22-9)MS
Borane-trimethylamine complex(75-22-9)1HNMR
Borane-trimethylamine complex(75-22-9)13CNMR
Borane-trimethylamine complex(75-22-9)IR1
Borane-trimethylamine complex(75-22-9)IR2
Borane-trimethylamine complex(75-22-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Borane-trimethylaminecomplex,98%(75-22-9)
[Alfa Aesar]

Borane-trimethylamine complex, 98%(75-22-9)
[Sigma Aldrich]

75-22-9(sigmaaldrich)
[TCI AMERICA]

Trimethylamine Borane,>95.0%(T)(75-22-9)
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