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108-05-4

108-05-4 Structure

108-05-4 Structure
IdentificationMore
[Name]

Vinyl acetate
[CAS]

108-05-4
[Synonyms]

ACETIC ACID VINYL ESTER
ACETIC ACID VINYL ESTER MONOMER
Ethenyl ethanoate
VAM
VINYL ACETATE
VINYL ACETATE MONOMER
1-Acetoxyethylene
Acetate de vinyle
acetatedevinyle
acetatedevinyle(french)
Acetic acid, ethylene ether
Aceticacid,ethenylester
aceticacid,ethyleneester
aceticacid,ethyleneether
aceticacidethenylester
acetoxyethene
CH3CO2CH=CH2
Ethanoic acid, ethenyl ester
ethanoicacid,ethenylester
Ethenyl acetate
[EINECS(EC#)]

203-545-4
[Molecular Formula]

C4H6O2
[MDL Number]

MFCD00008713
[Molecular Weight]

86.09
[MOL File]

108-05-4.mol
Chemical PropertiesBack Directory
[Description]

Vinyl acetate monomer (VAM) is a colourless liquid, immiscible or slightly soluble in water. VAM is a flammable liquid. VAM has a sweet, fruity smell (in small quantities), with sharp, irritating odour at higher levels. VAM is an essential chemical building block used in a wide variety of industrial and consumer products. VAM is a key ingredient in emulsion polymers, resins, and intermediates used in paints, adhesives, coatings, textiles, wire and cable polyethylene compounds, laminated safety glass, packaging, automotive plastic fuel tanks, and acrylic fibres. Vinyl acetate is used to produce polyvinyl acetate emulsions and resins. Very small residual levels of vinyl acetate have been found present in products manufactured using VAM, such as moulded plastic items, adhesives, paints, food packaging containers, and hairspray.
[Appearance]

Vinyl acetate is a colorless, flammable liquid. The odor threshold is 0.12 ppm 0.3 ppm (NY, NJ).
[Appearance]

colourless mobile liquid with a sweet, irritating odour
[mp ]

-93 °C
[bp ]

72-73 °C(lit.)
[density ]

0.934 g/mL at 25 °C(lit.)
[vapor density ]

3 (vs air)
[vapor pressure ]

88 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.395(lit.)
[Fp ]

20 °F
[storage temp. ]

0-6°C
[Stability:]

Stable. Highly flammable. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid, 2-aminoethanol, light. Susceptible to polymerization; commercial product may be stabilized by the addition of hydroquinone.
[Water Solubility ]

23 g/L (20 ºC)
[Sensitive ]

Light Sensitive
[Merck ]

14,9992
[BRN ]

1209327
[CAS DataBase Reference]

108-05-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Acetic acid ethenyl ester(108-05-4)
[EPA Substance Registry System]

108-05-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,T
[Risk Statements ]

R11:Highly Flammable.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S7:Keep container tightly closed .
[RIDADR ]

UN 1301 3/PG 2
[WGK Germany ]

2
[RTECS ]

AK0875000
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29153200
[HS Code ]

29333999
[Safety Profile]

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by ingestion, inhalation, and intraperitoneal routes. A skin and eye irritant. Experimental reproductive effects. Human mutation data reported. Highly dangerous fire hazard when exposed to heat, flame, or oxidzers. A storage hazard, it may undergo spontaneous exothermic polymerization. Reaction with air or water to form peroxides that catalyze an exothermic polymerization reaction has caused several large industrial explosions. Reaction with hydrogen peroxide forms the explosive peracetic acid. Reacts with oxygen above 50℃ to form an unstable explosive peroxide. Reacts with ozone to form the explosive vinyl acetate ozonide. Solution polymerization of the acetate dmolved in toluene has resulted in large industrial explosions. Polymerization reaction with dibenzoyl peroxide + ethyl acetate may release ignitable and explosive vapors. The vapor may react vigorously with desiccants (e.g., sihca gel or alumina). Incompatible (explosive) with 2-amino ethanol, chlorosulfonic acid, ethylenediamine, ethyleneimine, HCl, HF, HNO3, oleum, peroxides, H2SO4. See also ESTERS.
[Hazardous Substances Data]

108-05-4(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Acetic acid glacial-->Palladium chloride-->Acetylene-->Platinum
[Preparation Products]

Poly(vinyl alcohol)-->Bromoacetaldehyde diethyl acetal-->((1R,4S)-2-Azabicyclo[2.2.1]hept-5-en-3-one-->METHYL 5-FORMYL-2-METHYL-3-FUROATE-->Tazobactam acid-->2-Acetylbutyrolactone-->1,1-Dimethoxy-2-(2-methoxyethoxy)ethane-->2-TRIFLUOROMETHYLQUINOLINE-7-CARBOXYLIC ACID-->POLY(VINYL ACETATE)-->Adhesive for nonwoven fabric-->stiffening agent for synthetic fibre 855-->VINYL STEARATE-->Pressure sensitive adhesive-->PALMITIC ACID VINYL ESTER-->Starch, hydrogen phosphate acetate-->LT-01 emulsion-->PR-I retanning agent-->maleic acid-vinyl acetate copolymer-->irradiation initiated starch-g-vinyl acetate water absorbent agent-->Acetylated Dishtarch Phosphate-->emulsion used for paper series PC-->POLY(ETHYLENE-CO-METHACRYLIC ACID)-->Vinyl acetate-acrylate copolymer,emulsion-->STARCH ACETATE-->coating adhensive SSS-85-->5-NORBORNEN-2-YL ACETATE-->Ethylene-vinyl acetate copolymer
Hazard InformationBack Directory
[General Description]

A clear colorless liquid. Flash point 18°F. Density 7.8 lb/gal. Slightly soluble in water. Vapors are heavier than air. Vapors irritate the eyes and respiratory system. May polymerize if heated or contaminated. If polymerization occurs inside a container, the container may violently rupture. Used to make adhesives, paints, and plastics.
[Reactivity Profile]

VINYL ACETATE(108-05-4) may undergo spontaneous exothermic polymerization on exposure to light. Reacts with air or water to produces peroxides that initiate explosively violent polymerization. Reacts with hydrogen peroxide to form explosive peracetic acid. Reacts with oxygen to form explosive peroxides. Forms explosive VINYL ACETATE(108-05-4) ozonide on contact with ozone. Undergoes violent or explosive reactions with 2-aminoethanol, chlorosulfonic acid, ethylenediamine, mineral acids (hydrochloric acid, hydrofluoric acid, nitric acid, sulfuric acid, oleum), and peroxides [Lewis, 3rd ed., 1993, p. 1311]. Polymerization initiated by dibenzoyl peroxide in ethyl acetate accelerated out of control, ignited and exploded [Vervalin, 1973, p. 81]. Polymerization in toluene solution has caused several large industrial explosions [MCA Case History No. 2087].
[Air & Water Reactions]

Highly flammable. Slightly soluble in water.
[Health Hazard]

Vinyl acetate has been related to reproductive abnormalities. It is a skin and upper respiratory tract irritantand a central nervous system depressant. Exposure caused gradual deterioration of heart muscles.
[Potential Exposure]

Vinyl acetate is used primarily in polymerization processes to produce polyvinyl acetate; polyvinyl alcohol, and vinyl acetate copolymer. The polymers, usually made as emulsions, suspensions, solutions, or resins, are used to prepare adhesives, paints, paper coatings, and textile finishes. Low molecular weight vinyl acetate is used as a chewing gum base.
[Fire Hazard]

When heated to decomposition, VINYL ACETATE burns and emits acrid fumes. Highly dangerous when exposed to heat, flames or oxidizers; explosion hazard with strong acids and strong oxidizers. Incompatible with alumina, oxidizing materials, 2-aminoethanol, chlorosulfonic acid; ethyleneimine; 36% hydrochloric acid; 48.7% hydrofluoric acid; 70% nitric acid; oleum; 96% sulfuric acid; ethylene diamine; peroxides and silica gel. Avoid light or any polymerizing initiator. Hazardous polymerization can be initiated by organic and inorganic peroxides; azo compounds; redox systems (including organometallic components); light; and high energy radiation.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN1301 Vinyl acetate, stabilized, Hazard Class: 3; Labels: 3-Flammable liquid.
[Incompatibilities]

Vinyl acetate may undergo spontaneous exothermic polymerization on exposure to light. Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, strong light and UV. The vapor may react vigorously with silica gel or aluminum, acids, bases, silica gel; alumina, oxidizers, azo compounds. Ozone readily polymerizes in elevated temperatures, under the influence of light, or peroxides. Usually contains a stabilizer to prevent polymerization.
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Vinyl acetate(108-05-4).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Vinyl acetate(108-05-4)MS
Vinyl acetate(108-05-4)IR2
Vinyl acetate(108-05-4)13CNMR
Vinyl acetate(108-05-4)Raman
Vinyl acetate(108-05-4)1HNMR
Vinyl acetate(108-05-4)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Vinyl acetate, stabilized, 99+%(108-05-4)
[Alfa Aesar]

Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone(108-05-4)
[Sigma Aldrich]

108-05-4(sigmaaldrich)
[TCI AMERICA]

Vinyl Acetate Monomer  (stabilized with HQ),>99.0%(GC)(108-05-4)
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