ChemicalBook--->CAS DataBase List--->7787-59-9

7787-59-9

7787-59-9 Structure

7787-59-9 Structure
IdentificationMore
[Name]

BISMUTH OXYCHLORIDE
[CAS]

7787-59-9
[Synonyms]

BIRON LF-2000
BIRON MTU
BISMUTH CHLORIDE, BASIC
BISMUTH CHLORIDE OXIDE
BISMUTH(III) CHLORIDE OXIDE
BISMUTH(III) OXYCHLORIDE
BISMUTH OXYCHLORIDE
BISMUTH SUBCHLORIDE
BISMUTHYL CHLORIDE
PEARL WHITE
biju
chlorooxo-bismuthin
chlorooxo-Bismuthine
mearlite
CI 77163
BISMUTHYL(III) CHLORIDE
BISMUTH(III) OXYCHLORIDE 99.99+%
Bismuth(III) chloride oxide, 99.99%
Bismuth(III) chloride oxide powder, 99%
Bismuth(III)chlorideoxide,99.95%(metalsbasis)
[EINECS(EC#)]

232-122-7
[Molecular Formula]

BiClO
[MDL Number]

MFCD00010895
[Molecular Weight]

260.43
[MOL File]

7787-59-9.mol
Chemical PropertiesBack Directory
[Appearance]

White Lustorus powder
[Melting point ]

melts at low red heat [MER06]
[density ]

7.72 g/mL at 25 °C(lit.)
[refractive index ]

2.15
[solubility ]

H2O: insoluble(lit.)
[form ]

Powder
[color ]

Very pale brown
[Specific Gravity]

7.72
[Odor]

at 100.00?%. odorless
[Water Solubility ]

Soluble in HCl, HNO3. Insoluble in water, alcohol.
[Merck ]

14,1263
[Solubility Product Constant (Ksp)]

pKsp: 30.75
[Cosmetics Ingredients Functions]

COLORANT
[InChI]

InChI=1S/Bi.ClH.O/h;1H;/q+1;;/p-1
[InChIKey]

GLQBXSIPUULYOG-UHFFFAOYSA-M
[SMILES]

[Bi](Cl)=O
[Uses]

bismuth oxychloride is an inorganic color additive. It is used mostly in makeup manufacturing and rarely in skin care formulations. It may also be used for pearlization in cosmetics.
[CAS DataBase Reference]

7787-59-9(CAS DataBase Reference)
[EPA Substance Registry System]

Bismuthine, chlorooxo- (7787-59-9)
Hazard InformationBack Directory
[Chemical Properties]

White Lustorus powder
[General Description]

Odorless white solid. Sinks in water.
[Reactivity Profile]

BISMUTH OXYCHLORIDE emits toxic fumes of chloride ion and bismuth when heated to decomposition [USCG, 1999].
[Health Hazard]

Contact with dust causes mild eye irritation and can cause skin rashes.
[Physical properties]

White powder or tetragonal crystals; density 7.72 g/cm3; practically insoluble in water, alcohol and acetone; soluble in hydrochloric and nitric acids (with decomposition); Ksp 7.0 x 10-9.
[Preparation]

Bismuth oxychloride is made by treating bismuth chloride with water and then drying the white precipitate so formed to expel a molecule of water:
BiCl3 + 2H2O → Bi(OH)2Cl + 2HCl

Bi(OH)2Cl BiOCl + H2O
Also, the compound is prepared by treating a dilute nitric acid solution of bismuth nitrate with sodium chloride.

[Flammability and Explosibility]

Notclassified
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

2
[RTECS ]

EB2700000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

28274990
[Storage Class]

11 - Combustible Solids
Spectrum DetailBack Directory
[Spectrum Detail]

BISMUTH OXYCHLORIDE(7787-59-9)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Bismuth oxychloride, 99.99%(7787-59-9)
[Alfa Aesar]

Bismuth(III) chloride oxide, 99.999% (metals basis)(7787-59-9)
[Sigma Aldrich]

7787-59-9(sigmaaldrich)
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