ChemicalBook--->CAS DataBase List--->7790-86-5

7790-86-5

7790-86-5 Structure

7790-86-5 Structure
IdentificationMore
[Name]

CERIUM(III) CHLORIDE
[CAS]

7790-86-5
[Synonyms]

CERIUM CHLORIDE
CERIUM(III) CHLORIDE
Cerium trichloride heptahydrate
CEROUS CHLORIDE
CeCl3
Cerium chloride (CeCl3)
ceriumchloride(cecl3)
ceriumtrichloride
Cerium Chloride (Mohrs Salt)
CERIUM II CHLORIDE
Cerium(Ⅲ) chloride heptahydrate
CERIUM(III) CHLORIDE, 99.9%
Cerium(III) chloride, anhydrous, beads, #10 mesh, 99.99+% metals basis
CEROUS CHLORIDE ANHYDROUS
CERIUM(III) CHLORIDE, ANHYDROUS, BEADS,-10 MESH, 99.9+%
CERIUM(III) CHLORIDE, ANHYDROUS, BEADS,-10 MESH, 99+%
Cerium(III)chloride,anhydrous,99.5%(REO)
Cerium(III) chloride, anhydrous, pure, 99.9%
Cerium(III)chloride,anhydrous(H2O<0.5%)(99.9%-Ce)(REO)
cerium(iii) chloride, ultra dry
[EINECS(EC#)]

232-227-8
[Molecular Formula]

CeCl3
[MDL Number]

MFCD00010929
[Molecular Weight]

246.48
[MOL File]

7790-86-5.mol
Chemical PropertiesBack Directory
[Appearance]

White to Orange to Green powder to crystal.
[Melting point ]

848 °C(lit.)
[Boiling point ]

1727 °C
[density ]

3.97 g/mL at 25 °C(lit.)
[Fp ]

1727°C
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

soluble in H2O, ethanol
[form ]

beads
[color ]

White to Pale Gray
[Specific Gravity]

3.92
[Stability:]

Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.
[Water Solubility ]

Soluble in water, ethanol, acids and acetone.
[Specific Heat Capacity]

Cp(crystal):0.354593J/(g·K),at 25℃
[Crystal Structure]

UCl3 type
[Sensitive ]

Hygroscopic
[crystal system]

Six sides
[Merck ]

14,1997
[Space group]

P63/m
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.7450.7450.43190901200.2073
[InChI]

1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
[InChIKey]

VYLVYHXQOHJDJL-UHFFFAOYSA-K
[SMILES]

Cl[Ce](Cl)Cl
[CAS DataBase Reference]

7790-86-5(CAS DataBase Reference)
[EPA Substance Registry System]

Cerium chloride (CeCl3) (7790-86-5)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Environment (GHS09)
GHS05,GHS09
[Signal word ]

Danger
[Hazard statements ]

H314-H410
[Precautionary statements ]

P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3260 8 / PGIII
[WGK Germany ]

2
[RTECS ]

FK5075000
[F ]

3-10
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[HS Code ]

28461090
[Storage Class]

8B - Non-combustible corrosive hazardous materials
[Hazard Classifications]

Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1
Skin Corr. 1C
[Safety Profile]

Poison by intravenous, intraperitoneal, and subcutaneous routes. Moderately toxic by ingestion. See also CERIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-
[Toxicity]

LD50 in mice, guinea pigs (mg/kg): 352, 110 i.p. (Graca)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Rare earth chlorides
[Preparation Products]

1-Boc-4-(2-oxo-3-pyridin-4-yl-propyl)-piperidine
Hazard InformationBack Directory
[Chemical Properties]

Cerium(III) chloride is a white powder and is used for incandescent gas mantles, spectrography and polymerization of olefins.
Cerium(III) chloride
Cerium(III) chloride is mainly used as catalyst for petroleum,automobile exhaust catalyst , also used as a raw material for the production of cerium metal and other cerium compounds.
[Physical properties]

White, very fine powder; hexagonal crystal system; heptahydrate is yellow orthogonal crystal and hygroscopic; density of anhydrous salt 3.97 g/cm3; melts at 817°C; vaporizes at 1,727°C; heptahydrate begins to lose water above 90°C and becomes anhydrous at about 230°C; soluble in water and alcohol; hexahydrate has greater solubility in these solvents.
[Uses]

Cerium(III) chloride is used in incandescent gas mantles, spectrography and polymerization of olefins. It acts as a Lewis acid and used in Friedel-Crafts alkylation and acylation reactions in organic synthesis. It is used as a precursor for the preparation of other cerium salts, such as cerium(III) trifluoromethanesulfonate.
[Production Methods]

Cerium(III) chloride is prepared by the reaction of hydrochloric acid with a cerium salt, such as cerium hydroxide or carbonate, followed by crystallization;
Ce(OH)3 + 3HCl → CeCl3 + 3H2O
Ce2(CO3)3 + 6HCl → 2CeCl3 + 3CO2 + 3H2O.
[Flammability and Explosibility]

Nonflammable
[reaction suitability]

reagent type: catalyst
core: cerium
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Cerium(III) chloride, anhydrous, pure, 99.9%(7790-86-5)
[Alfa Aesar]

Cerium(III) chloride, ultra dry, 99.9% (REO)(7790-86-5)
[Sigma Aldrich]

7790-86-5(sigmaaldrich)
[TCI AMERICA]

Cerium(III) Chloride  Anhydrous,>98.0%(T)(7790-86-5)
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