| Identification | More | [Name]
NICKEL(II) BROMIDE TRIHYDRATE | [CAS]
7789-49-3 | [Synonyms]
NICKEL(+2)BROMIDE
NICKEL BROMIDE
NICKEL BROMIDE (OUS)
NICKEL BROMIDE TRIHYDRATE
NICKEL DIBROMIDE
NICKEL(II) BROMIDE
NICKEL(II) BROMIDE-3-HYDRATE
NICKEL(II) BROMIDE TRIHYDRATE
NICKELOUS BROMIDE
NICKEL BROMIDE, 99.998%
Nickel bromide (NiBr2), trihydrate | [EINECS(EC#)]
236-665-0 | [Molecular Formula]
Br2H6NiO3 | [MDL Number]
MFCD00149807 | [Molecular Weight]
272.55 | [MOL File]
7789-49-3.mol |
| Chemical Properties | Back Directory | [Appearance]
(1) Brownish-yellow solid or yellow,
lustrous scales.(2) Deliquescent, greenish scales; loses 3H2O at 300C. Soluble
in water, alcohol, ether, and ammonium hydroxide. | [Melting point ]
963 °C(lit.) | [density ]
5.098 g/mL at 25 °C(lit.)
| [form ]
powder
| [Water Solubility ]
Soluble in water, alcohol | [Sensitive ]
Hygroscopic | [Merck ]
14,6502 | [Exposure limits]
ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 | [Major Application]
battery precursors
catalysts
material synthesis precursor | [InChI]
1S/2BrH.Ni.3H2O/h2*1H;;3*1H2/q;;+2;;;/p-2 | [InChIKey]
UQPSGBZICXWIAG-UHFFFAOYSA-L | [SMILES]
O.O.O.Br[Ni]Br | [CAS DataBase Reference]
7789-49-3(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS08,GHS09 | [Signal word ]
Danger | [Hazard statements ]
H317-H334-H341-H350i-H360D-H372-H410 | [Precautionary statements ]
P202-P260-P273-P280-P302+P352-P308+P313 | [Hazard Codes ]
T,N | [Risk Statements ]
R45:May cause cancer.
R22:Harmful if swallowed.
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3077 9/PG 3
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [Storage Class]
6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects | [Hazard Classifications]
Aquatic Acute 1
Aquatic Chronic 1
Carc. 1A Inhalation
Muta. 2
Repr. 1B
Resp. Sens. 1
Skin Sens. 1
STOT RE 1 Inhalation |
| Hazard Information | Back Directory | [Hazard]
See nickel. | [Chemical Properties]
(1) Brownish-yellow solid or yellow,
lustrous scales.(2) Deliquescent, greenish scales; loses 3H2O at 300C. Soluble
in water, alcohol, ether, and ammonium hydroxide. | [Chemical Properties]
The green hexahydrate NiBr2-6H2O readily evolves water; crystallization from aqueous
solutions above 29° yields the trihydrate NiBr2-3H2O. The hexahydrate can be dehydrated
to a dihydrate over concentrated sulphuric acid at 5°. The environment of the nickel atoms in NiBr2-6H20 is 2Br and 4H20 and in NiBr2-2H20 4Br and 2H20 ; in both cases the Ni-Br distance is 2.6 and the Ni-O distance 2.0 ?. | [Uses]
It is used in Soporific and sedatives pharmaceutical Industry, Photosensitive industry, Analytical Chemistry, and also electrolyte in high energy battery. | [Preparation]
Anhydrous NiBr2 is most conveniently prepared by the action of
bromine on nickel, either at red heat or in ethereal solution at room temperature74 or by
dehydration of the hexahydrate at about 140°. It crystallizes with the CdCl2 type structure, the nickel atoms being surrounded octahedrally by bromine atoms at 2.57 ?. | [reaction suitability]
reagent type: catalyst
core: nickel |
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