ChemicalBook--->CAS DataBase List--->8017-16-1

8017-16-1

8017-16-1 Structure

8017-16-1 Structure
IdentificationMore
[Name]

Polyphosphoric acids
[CAS]

8017-16-1
[Synonyms]

POLYPHOSPHORIC ACID
polyphosphoric acids
PPA
acidepolyphosphorique
acidesuperphosphorique
condensedphosphoricacid
condensedphosphoricacid(non-specificname)
phospholeum
superphosphoricacid
Polyphosphoic Acid
Polyphosphoric acid (83% P2O5)
PolyphosphoricacidPOviscousliq
POLYPHOSPHORIC ACID REAGENT GRADE 115&
POLYPHOSPHORIC ACID FOR SYNTHESIS
Polyphosphoricacid,ca84%(asphosphoruspentoxide)
Phosphoric acids, super-or poly-
Polyphosphoric acid, > 84% phosphate (as P2O5), pure
POLYPHOSPHORIC ACID , 84% MIN.
Polyphosphorsuren
Polyphosphoric acid PPA 105% , 115%, 116%
[EINECS(EC#)]

232-417-0
[Molecular Formula]

(H)n+2.(P)n.(O)3n+1
[MDL Number]

MFCD00084480
Chemical PropertiesBack Directory
[Appearance]

liquid
[Melting point ]

-20°C
[Boiling point ]

550 °C
[density ]

2.06 g/mL at 25 °C
[vapor pressure ]

2 hPa (20 °C)
[storage temp. ]

Store below +30°C.
[solubility ]

Methanol (Soluble), Water (Soluble)
[form ]

Viscous Liquid
[pka]

0.91[at 20 ℃]
[color ]

Colorless
[Specific Gravity]

2.06
[Odor]

Odorless
[Stability:]

Stable. Incompatible with strong bases. Hygroscopic.
[Water Solubility ]

MAY DECOMPOSE
[Sensitive ]

Hygroscopic
[Detection Methods]

T
[Merck ]

14,7580
[InChI]

1S/O5P2.H3O4P/c1-2-7-4-3-6(1)5-7;1-5(2,3)4/h;(H3,1,2,3,4)
[InChIKey]

FVYIVXLIMHNYTD-UHFFFAOYSA-N
[SMILES]

[P](=O)(O)(O)O.[p]21[o][p]([o][o]2)[o][o]1
[Uses]

Dehydrating, catalytic, and sequestering agents, for metal treating; many applications where a con- centrated monooxidizing acid is needed; laboratory reagent.
[CAS DataBase Reference]

8017-16-1(CAS DataBase Reference)
[EPA Substance Registry System]

8017-16-1(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

liquid
[Definition]

ChEBI: A polymerized phosphorus oxoacid of general formula HO[PO2OH]nH formed by condensation of orthophosphoric acid molecules and containing a backbone chain consisting of alternating P and O atoms covalent y bonded together.
[Hazard]

Toxic by ingestion; strong irritant.
[Description]

Superphosphoric acid is made by the concentration of regular wet-process acid up to P2O5 concentrations of 78%. Granular polyphosphates suitable for bulk blending are made by reacting ammonia with regular wet process acid of 52% P2O5 content and using the heat of reaction to drive off water to produce a phosphate melt of 10-43-0, with about 40% of the phosphorus in the polyphosphate form. These materials are, however, not suitable for bulk blending due to their “sticky” nature (10).
[General Description]

Polyphosphoric acid (PPA) is widely employed as acylation and alkylation reagent in various reactions. It is a strong mineral acid with excellent dehydrating properties.
[Agricultural Uses]

Polyphosphoric acid is obtained by heating the wetprocess phosphoric acid. It contains around 72% phosphorus (as P2O5) and represents a series of phosphoric acids containing more than one atom of phosphorus (such as H4P2O7). The general formula is Hn+2PnO3n+1.
[Solubility in water]

Polyphosphoric acids are miscible with water, hydrolyzing to orthophosphoric acid with the generation of heat. They are insoluble in hydrocarbons and halogenated hydrocarbons. 
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H290-H314
[Precautionary statements ]

P234-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S25:Avoid contact with eyes .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

3264
[WGK Germany ]

1
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

28092000
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Met. Corr. 1
Skin Corr. 1B
[Hazardous Substances Data]

8017-16-1(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Phosphoric acid
[Preparation Products]

5-Aminoindole-->2-(3-Chloro-4-fluorophenyl)indole-->6-Chloro-2-(trifluoromethyl)quinoline-4-carboxylic acid-->3-(Trifluoromethyl)-5,6,7,8-tetrahydro-[1,2,4]triazolo[4,3-a]pyrazine-->2-(Trifluoromethyl)-5-methylquinoline-4-carboxylic acid-->Ziprasidone-->Diphenyl phthalate-->(5-Bromo-1H-indol-2-yl)methanol-->Pyrophosphoric acid-->Ethyl 4,6-dichloro-3-formyl-1H-indole-2-carboxylate-->3-[1,1'-Biphenyl]-4-yl-1,2,3,4-tetrahydro-1-naphthol-->5-Chloroindole-2-carboxylic acid-->2-(4-Ethoxy-phenyl)-1H-indole-->Potassium triphosphate-->4-(1H-Indol-2-yl)-phenylamine-->4-bromo-2-(trifluoromethyl)quinoline-->5-Bromoindole-2-carboxylic acid-->1H-Pyrazolo[3,4-b]pyridine,3-methyl-(9CI)-->4-Oxo-9,10-dihydro-4H-benzo(4,5)-cyclohepta-(1,2b)thiophene-->2-(4-Fluorophenyl)-1H-indole-3-carbaldehyde-->6-Bromo-2,3-dihydro-4H-chromen-4-one-->4-Hydroxy-2-(trifluoromethyl)quinoline-->Ethyl 5-Bromoindole-2-carboxylate-->3-(Trifluoromethyl)-1,2,4-triazolo[4,3-a]pyrazine-->Ethyl 5-chloro-2-indolecarboxylate-->7-Bromoisoquinoline-->2,5-Bis(4-aminophenyl)-1,3,4-oxadiazole-->liquid crystalline heterocyclic polymer-->solid phosphoric acid catalyst T-49-->new scale corrosion inhibitor W-331-->6-(4-Fluorophenyl)indole-->2-(4-Bromo-phenyl)-1H-indole-->Setiptiline-->corrosion and scale inhibitor NJ-213-->corrsion inhibitor SH-1-->prefiiming agent WT-302-1-->prefilming agent-corrosion inhibitor JS-204-->SODIUMSTARCHPHOSPHATE-->cleaning and prefilming agent JC-861-->Zaltoprofen
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Polyphosphoric acids(8017-16-1).msds
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Polyphosphoric acid, ca 84% (as phosphorus pentoxide)(8017-16-1)
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