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81406-37-3

81406-37-3 Structure

81406-37-3 Structure
IdentificationMore
[Name]

Starane
[CAS]

81406-37-3
[Synonyms]

1-METHYLHEPTYL (4-AMINO-3,5-DICHLORO-6-FLUORO-2-PYRIDYLOXY)ACETATE
1-methylheptyl [(4-amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy]acetate
((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-acetic acid 1-methylheptyl ester
FLUROXPYR 1 METHYLHEPTYL ESTER
FLUROXYPYR-1-METHYLHEPTYL ESTER
FLUROXYPYR-MEPTYL
starane
((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-aceticaci1-methylheptyl
((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-aceticaci1-methylheptylester
dowco433
starane250
xrm5084
FLUROXYPYR-1-METHYLHEPTYL ESTER PESTANAL
Acetic acid, (4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy-, 1-methylheptyl ester
fluroxypyr methylheptyl ester
4-Amino-3,5-dichloro-6-fluoro-2-pyridyloxy acetic acid 1-methylheptyl ester
4-Amino-3,5-dichloro-6-fluoro-2-pyridinyloxyacetic acid 1-methylheptyl este
4-AMINO-3,5-DICHLORO-6-FLUORO-2-PYRIDINYL)OXY)-ACETIC ACID 1-METHYLHEPTYL ESTER,95+%
[(4-Amino-3,5-dichloro-6-fluoropyridine-2-yl)oxy]acetic acid 1-methylheptyl ester
[EINECS(EC#)]

279-752-9
[Molecular Formula]

C15H21Cl2FN2O3
[MDL Number]

MFCD00144318
[Molecular Weight]

367.24
[MOL File]

81406-37-3.mol
Chemical PropertiesBack Directory
[Appearance]

White crystalline solid.
[Melting point ]

59 °C
[Boiling point ]

431.9±40.0 °C(Predicted)
[density ]

1.268±0.06 g/cm3(Predicted)
[storage temp. ]

Store at -20°C
[solubility ]

soluble in Methanol
[form ]

neat
[pka]

-1.55±0.10(Predicted)
[color ]

White to Light yellow
[Merck ]

13,4229
[Henry's Law Constant]

3.7×101 mol/(m3Pa) at 25℃, Maniere et al. (2011)
[Major Application]

agriculture
environmental
[InChI]

1S/C15H21Cl2FN2O3/c1-3-4-5-6-7-9(2)23-10(21)8-22-15-12(17)13(19)11(16)14(18)20-15/h9H,3-8H2,1-2H3,(H2,19,20)
[InChIKey]

OLZQTUCTGLHFTQ-UHFFFAOYSA-N
[SMILES]

CCCCCCC(C)OC(=O)COc1nc(F)c(Cl)c(N)c1Cl
[CAS DataBase Reference]

81406-37-3(CAS DataBase Reference)
[EPA Substance Registry System]

81406-37-3(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H312-H410
[Precautionary statements ]

P273-P280-P302+P352+P312
[Hazard Codes ]

N
[Risk Statements ]

R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3077
[WGK Germany ]

2
[RTECS ]

AF2503000
[HS Code ]

2933399990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Dermal
Aquatic Acute 1
Aquatic Chronic 1
Hazard InformationBack Directory
[Potential Exposure]

Those who manufacture, distribute or use this pyridinecarboxylic acid/pyridine herbicide.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions) if breathing has stopped, and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz ardous material, Technical Name Required.
[Incompatibilities]

May not be compatible with nitrates. Moisture may cause hydrolysis or other forms of decompo sition; forming a strong acid. Temperatures above 250℃ can cause decomposition. Methyl ester: Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is suffi ciently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solu tions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
[Chemical Properties]

White crystalline solid.
[Waste Disposal]

Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an after burner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesti cide containers.
[Uses]

Herbicide.
[Production Methods]

Fluroxypyr-meptyl exhibits optical isomerism due to the presence of a chiral centre in the meptyl ester moiety. While the fluroxypyr acid itself is not isomeric, the meptyl group, a branched alkyl chain attached via an ester linkage, contains a stereogenic carbon that gives rise to two enantiomers.
[General Description]

Fluroxypyr-1-methylheptyl ester is a selective post-emergent and systemic herbicide.
[Mechanism of action]

Selective, foliar uptake causing auxin-type response
[storage]

Store at -20°C
[Pesticide Type]

Herbicide
Spectrum DetailBack Directory
[Spectrum Detail]

Starane(81406-37-3)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

81406-37-3(sigmaaldrich)
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