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85-86-9

85-86-9 Structure

85-86-9 Structure
IdentificationMore
[Name]

Solvent Red 23
[CAS]

85-86-9
[Synonyms]

1-[4-(PHENYLAZO)PHENYLAZO]-2-NAPHTHOL
1-[[P-(PHENYLAZO)PHENYL]AZO]-2-NAPHTHOL
CERASIN RED
CI 26100
CI NO 26100
D AND C RED NO 17
FAT PONCEAU G
FAT SOLUBLE SUDAN
HERXHEIMER FAT STAIN
OIL RED
OIL RED AS
OIL RED O, B OR 3B
OIL RED O, B OR 3B, SCARLET B
SCARLET B
SOLVENT RED 23
SUDAN
SUDAN 3
SUDAN G
SUDAN III
SUDAN III STAIN
[EINECS(EC#)]

201-638-4
[Molecular Formula]

C22H16N4O
[MDL Number]

MFCD00003905
[Molecular Weight]

352.39
[MOL File]

85-86-9.mol
Chemical PropertiesBack Directory
[Appearance]

reddish brown powder
[Melting point ]

199 °C (dec.)(lit.)
[Boiling point ]

486.01°C (rough estimate)
[density ]

1.2266 (rough estimate)
[refractive index ]

1.6620 (estimate)
[storage temp. ]

Amber Vial, Refrigerator
[solubility ]

Insoluble in water; soluble in benzene, chloroform; moderately soluble in acetone, ether, petroleum ether; slightly soluble in ethanol, xylene
[Colour Index ]

26100
[form ]

Powder
[pka]

13.45±0.50(Predicted)
[color ]

Red-brown
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[λmax]

507 nm, 354 nm
[Merck ]

14,8884
[BRN ]

2016384
[Biological Applications]

Antiseptic; preventing prostate cancer; medical devices; dental impression materials
[Major Application]

cleaning products
cosmetics
food and beverages
personal care
[Cosmetics Ingredients Functions]

COLORANT
HAIR DYEING
[InChI]

1S/C22H16N4O/c27-21-15-10-16-6-4-5-9-20(16)22(21)26-25-19-13-11-18(12-14-19)24-23-17-7-2-1-3-8-17/h1-15,27H/b24-23+,26-25+
[Contact allergens]

Solvent Red 23 is an oil-soluble red azo-dye used in cosmetic products in Japan. Cases were reported in hairdressers, who also reacted to PPD (the molecule is likely to be hydrolyzed into PPD) and to p-aminoazobenzene. One case of contact dermatitis was reported in the metal industry.
[InChIKey]

FHNINJWBTRXEBC-HXEHWPEMSA-N
[SMILES]

Oc1ccc2ccccc2c1\N=N\c3ccc(cc3)\N=N\c4ccccc4
[LogP]

5.740 (est)
[CAS DataBase Reference]

85-86-9(CAS DataBase Reference)
[IARC]

3 (Vol. 8, Sup 7) 1987
[EPA Substance Registry System]

85-86-9(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

reddish brown powder
[Uses]

Weakly acidic azo dye. Biological stain.
[Definition]

ChEBI: A bis(azo) compound that is 2-naphthol substituted at position 1 by a 4-{[(2-methylphenyl)diazenyl]phenyl}diazenyl group. A fat-soluble dye predominantly used for demonstrating triglycerides in frozen sections, but which may also stain some protein bound l pids in paraffin sections.
[Uses]

Dye. Biological stain.
[Description]

Solvent Red 23 is an oil-soluble red azo dye used in cosmetic products in Japan. Cases were reported in hairdressers, who also reacted to PPD and to paminoazobenzene. One case of contact dermatitis was reported in the metal industry.
[Preparation]

4-(Phenyldiazenyl)benzenamine diazotization, and Naphthalen-2-ol coupling. Note: some goods by 4-(Phenyldiazenyl)benzenamine and 2-Methyl-4-(o-tolyldiazenyl)benzenamine mixture as diazo components and have to.
[Properties and Applications]

yellow red to red. Soluble in ethanol and acetone, soluble in benzene. In concentrated sulfuric acid to blue light green, dilution for blue solution, and a red precipitation.
Standard Light Fastness Heat-resistant(℃) water Sodium Carbonate(5%) Hydrochloric acid(5%)
Melting point Stable
ISO Good 195 70≥ 120

Sublimation

Insoluble No change No change
[Purification Methods]

Crystallise the dye from EtOH, EtOH/water or *benzene/absolute EtOH (1:1). [Beilstein 16 II 75, 16 III 148, 16 IV 248.]
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Warning
[Hazard statements ]

H317-H315-H319-H335-H341
[Precautionary statements ]

P201-P305+P351+P338-P405-P501a-P261-P272-P280-P302+P352+P333+P313+P363-P501
[Hazard Codes ]

Xi
[Risk Statements ]

R10:Flammable.
R20:Harmful by inhalation.
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[RTECS ]

QK4250000
[TSCA ]

Yes
[HS Code ]

32129000
[Storage Class]

11 - Combustible Solids
[Safety Profile]

Poison by intraperitoneal route. Moderately toxic by subcutaneous and intrapleural routes. Questionable carcinogen. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
[Toxicity]

cyt-ham:ovr 20 mmol/L/5H-C ENMUDM 1,27,79
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Sudan Red(85-86-9).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Solvent Red 23(85-86-9)MS
Solvent Red 23(85-86-9)1HNMR
Solvent Red 23(85-86-9)IR1
Solvent Red 23(85-86-9)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Sudan III(85-86-9)
[Sigma Aldrich]

85-86-9(sigmaaldrich)
[TCI AMERICA]

Sudan III,>85.0%(E)(85-86-9)
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