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874-98-6

874-98-6 Structure

874-98-6 Structure
IdentificationMore
[Name]

3-METHOXYBENZYL BROMIDE
[CAS]

874-98-6
[Synonyms]

1-BROMOMETHYL-3-METHOXYBENZENE
3-METHOXYBENZYL BROMIDE
3-(Bromomethyl)anisole,1-(Bromomethyl)-3-methoxybenzene
3-Methoxybenzyl bromide 98%
m-Methoxybenzylbromide
3-Methoxybenzyl bromide ,98%
(3-Methoxyphenyl)bromomethane
3-(Bromomethyl)anisole
[Molecular Formula]

C8H9BrO
[MDL Number]

MFCD00216590
[Molecular Weight]

201.06
[MOL File]

874-98-6.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless liquid
[Boiling point ]

152 °C(lit.)
[density ]

1.436 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.575(lit.)
[Fp ]

>230 °F
[storage temp. ]

-20°C Freezer
[solubility ]

soluble in Chloroform
[form ]

Liquid
[color ]

Clear colorless to light yellow
[Detection Methods]

HPLC,GC,NMR
[InChI]

1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3
[InChIKey]

ZKSOJQDNSNJIQW-UHFFFAOYSA-N
[SMILES]

COc1cccc(CBr)c1
[CAS DataBase Reference]

874-98-6(CAS DataBase Reference)
[Storage Precautions]

Store under nitrogen
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[Hazard Note ]

Corrosive
[HazardClass ]

8
[HS Code ]

29049090
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Skin Corr. 1B
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethyl acetate-->Diethyl ether-->Petroleum ether-->Sodium bicarbonate-->Carbon tetrachloride-->N-Bromosuccinimide-->Phosphorus tribromide-->tert-Butyl methyl ether-->3-Methylanisole-->m-Anisyl alcohol
[Preparation Products]

2-Bromo-5-methoxytoluene-->M-TyraMine HydrobroMide-->4-[(3-Methoxybenzyl)oxy]benzaldehyde-->Cyclopropyl 2-(3-methoxyphenyl)ethyl ketone-->1-(3-Methoxy-benzyl)-1H-pyrazol-4-ylamine
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Uses]

3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives.
It may be used in the synthesis of the following:
  • 6-(3-methoxyphenyl)-hexane-2,4-dione
  • N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine
  • 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate
  • 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole
[Uses]

3-Methoxybenzyl bromide is a benzyl bromide derivative used as a benzyl group rearrangement catalyst.
[General Description]

3-Methoxybenzyl bromide is a benzyl bromide derivative.
Spectrum DetailBack Directory
[Spectrum Detail]

3-METHOXYBENZYL BROMIDE(874-98-6)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Methoxybenzylbromide(874-98-6)
[Sigma Aldrich]

874-98-6(sigmaaldrich)
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