| Identification | More | [Name]
4-Methoxybenzyl bromide | [CAS]
2746-25-0 | [Synonyms]
1-(BROMOMETHYL)-4-METHOXYBENZENE
4-METHOXYBENZYL BROMIDE
METHOXYBENZYLBROMIDE(4-)
4-MethoxybenzylBromide4-Methoxybenzylbromide
p-Methoxybenzylbromide
4-Methoxybenzyl bromide ,95% | [EINECS(EC#)]
608-101-7 | [Molecular Formula]
C8H9BrO | [MDL Number]
MFCD00800380 | [Molecular Weight]
201.06 | [MOL File]
2746-25-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
240 °C | [Boiling point ]
91 °C1 mm Hg(lit.)
| [density ]
1.379 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.5780(lit.)
| [Fp ]
>230 °F
| [form ]
liquid | [color ]
Faintly hazy, faint yellow | [Detection Methods]
GC,NMR | [InChI]
InChI=1S/C8H9BrO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6H2,1H3 | [InChIKey]
GIGRWGTZFONRKA-UHFFFAOYSA-N | [SMILES]
C1(CBr)=CC=C(OC)C=C1 | [CAS DataBase Reference]
2746-25-0(CAS DataBase Reference) | [Storage Precautions]
Moisture sensitive;Store under nitrogen |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P422 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
1
| [HazardClass ]
8 | [HS Code ]
29093090 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liquid | [Uses]
4-Methoxybenzyl Bromide is a useful reactant in studying diarylpyrazoles as cyclooxygenase 2 inhibitors. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 55, p. 4469, 1990 DOI: 10.1021/jo00301a051
Synthetic Communications, 6, p. 109, 1976 DOI: 10.1080/00397917608072618 | [Synthesis]
McCall et al. reacted 4-methoxybenzyl bromide with resveratrol with hydrogen bromide in n-hexane and toluene in an ice bath to finally obtain 4-methoxybenzyl bromide in 68% yield, this reaction produces by-products. |
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