| Identification | More | [Name]
4-(Chloromethyl)benzoyl chloride | [CAS]
876-08-4 | [Synonyms]
4-CHLOROMETHYLBENZOYL CHLORIDE
CMBC
P-CHLOROMETHYLBENZOYL CHLORIDE
4-CHLOROMETHYLBENZOYL CHLORIDE 98+%
Benzoyl chloride, 4-(chloromethyl)-
4-(Chloromethyl)benzoic acid chloride
4-Chloromethylbenzoic acid chloride
p-(Chloromethyl)benzoic acid chloride
α-Chloro-p-toluoyl chloride | [EINECS(EC#)]
212-881-0 | [Molecular Formula]
C8H6Cl2O | [MDL Number]
MFCD00053224 | [Molecular Weight]
189.04 | [MOL File]
876-08-4.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light beige low melting crystalline mass | [Melting point ]
30-32 °C(lit.)
| [Boiling point ]
126-128 °C6 mm Hg(lit.)
| [density ]
1.2979 (rough estimate) | [refractive index ]
1.5605 (estimate) | [Fp ]
199 °F
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
soluble in Toluene | [form ]
Low Melting Crystalline Mass | [color ]
White to light beige | [Detection Methods]
GC | [InChI]
InChI=1S/C8H6Cl2O/c9-5-6-1-3-7(4-2-6)8(10)11/h1-4H,5H2 | [InChIKey]
RCOVTJVRTZGSBP-UHFFFAOYSA-N | [SMILES]
C(Cl)(=O)C1=CC=C(CCl)C=C1 | [CAS DataBase Reference]
876-08-4(CAS DataBase Reference) | [Storage Precautions]
Moisture sensitive |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R36/37:Irritating to eyes and respiratory system . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes . | [RIDADR ]
3261 | [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29163990 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light beige low melting crystalline mass | [Uses]
4-(Chloromethyl)benzoyl Chloride is used in the synthetic preparation of various compounds and pharmaceuticals. 4-(Chloromethyl)benzoyl Chloride was used in the synthesis of several imidazo[2,1-b]thia
zoles. | [Synthesis]
1. 4-Methylbenzyl alcohol undergoes radical chlorination with chlorine gas at 60-75°C in the presence of initiator and promoter to yield 4-(trichloromethyl)benzyl alcohol.
2. The trichloromethyl compound is hydrolyzed above 60°C to give 4-(chloromethyl |
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