| Identification | More | [Name]
2'-HYDROXY-4',6'-DIMETHOXYACETOPHENONE | [CAS]
90-24-4 | [Synonyms]
1-(2-HYDROXY-4,6-DIMETHOXYPHENYL)ETHAN-1-ONE
1-(2-HYDROXY-4,6-DIMETHOXYPHENYL)ETHANONE
2,4-DIMETHOXY-6-HYDROXYACETOPHENONE
2'-HYDROXY-4',6'-DIMETHOXYACETOPHENONE
2-HYDROXY-4,6-DIMETHOXYACETOPHENONE
4',6'-DIMETHOXY-2'-HYDROXYACETOPHENONE
4,6-DIMETHOXY-2-HYDROXYACETOPHENONE
6-HYDROXY-2,4-DIMETHOXYACETOPHENONE
BREVIFOLIN
1-Acetyl-2-hydroxy-4,6-dimethoxybenzene
2,4-Di-O-methylphloroacetophenone
2-hydroxyl-4,6-dimethoxy-acetophenone
Acetophenone, 2'-hydroxy-4',6'-dimethoxy-
Brevifolin (Zanthoxylum)
Phloracetophenone dimethyl ether
Phloroacetophenone 2,4-dimethyl ether
Xanthoxylin
xanthoxyline
Brevifolin~4,6-Dimethoxy-2-hydroxyacetophenone~Xanthoxylin
4'',6''-DIMETHOXY-2''-HYDROXYACETOPHENONE 98+% | [EINECS(EC#)]
201-978-3 | [Molecular Formula]
C10H12O4 | [MDL Number]
MFCD00017243 | [Molecular Weight]
196.2 | [MOL File]
90-24-4.mol |
| Chemical Properties | Back Directory | [Melting point ]
80-84 °C(lit.)
| [Boiling point ]
185°C/20mm | [density ]
1.172±0.06 g/cm3(Predicted) | [Fp ]
185°C/20mm | [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Soluble in hot methanol. | [form ]
powder to crystal | [pka]
9.41±0.15(Predicted) | [color ]
White to Light yellow to Light orange | [Merck ]
14,10067 | [BRN ]
1285013 | [Stability:]
Stable under recommended storage conditions., Stable Under Recommended Storage C | [InChIKey]
FBUBVLUPUDBFME-UHFFFAOYSA-N | [LogP]
2.933 (est) | [CAS DataBase Reference]
90-24-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29145090 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
3,5-Dimethoxyphenol acetate-->2',4',6'-TRIMETHOXYACETOPHENONE-->2',4',6'-Trihydroxyacetophenone monohydrate-->3,5-Dimethoxyphenol-->Acetyl chloride-->Iodomethane-->Dimethyl sulfate-->Dimethyl carbonate-->Acetic acid-->Acetone | [Preparation Products]
2-Hydroxy-3-iodo-4,6-dimethoxy acetophenone-->Robustaflavone-->Scutellarein 4',7- dimethyl ether-->2',4',6'-TRIMETHOXYACETOPHENONE-->Isolicoflavonol-->5,7-DIMETHOXYFLAVONE-->Pinostrobin-->aciculatin-->5,7-DIMETHOXYISOFLAVONE |
| Hazard Information | Back Directory | [Uses]
1-(2-Hydroxy-4,6-dimethylphenyl)-ethanone was investigated for its properties as an antibacterial agent and urease inhibitory effects. | [Uses]
2'-Hydroxy-4',6'-dimethoxyacetophenone is a chemical with potential antibacterial agent effects and urease inhibitory effects as well as synthesis applications. | [Definition]
ChEBI: Xanthoxylin is a carboxylic ester. It is functionally related to a phloroglucinol. | [Preparation]
Preparation by reaction of acetonitrile on phloroglucinol dimethyl ether (Hoesch reaction). | [Synthesis]
Prod.: by regulated (Di)methylation of Phloracetophenone with Dimethylsulfate in weak aqueous alkali. | [storage]
Store at -20°C | [References]
[1] Bulletin of the Korean Chemical Society, 2013, vol. 34, # 12, p. 3782 - 3786
[2] Patent: WO2010/19861, 2010, A1. Location in patent: Page/Page column 38; 50
[3] Patent: EP2112145, 2009, A1. Location in patent: Page/Page column 14-15
[4] Bulletin of the Korean Chemical Society, 2014, vol. 35, # 4, p. 1154 - 1158
[5] Patent: KR2015/49695, 2015, A. Location in patent: Paragraph 0063-0072 |
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