ChemicalBook--->CAS DataBase List--->92-41-1

92-41-1

92-41-1 Structure

92-41-1 Structure
IdentificationMore
[Name]

Naphthalene-2,7-disulfonic acid
[CAS]

92-41-1
[Synonyms]

2,7-NAPHTHALENE DISULFONIC ACID
naphthalene-2,7-disulfonic acid
naphthalene-2,7-disulphonic acid
3,6-Naphthalenedisulfonic acid
Ebert-Merz α-acid
[EINECS(EC#)]

202-154-6
[Molecular Formula]

C10H8O6S2
[MDL Number]

MFCD00035734
[Molecular Weight]

288.3
[MOL File]

92-41-1.mol
Chemical PropertiesBack Directory
[Appearance]

White, crystalline solid.Soluble in water. Combustible.
[Melting point ]

199°C
[Boiling point ]

400.53°C (rough estimate)
[density ]

1.6867 (rough estimate)
[refractive index ]

1.6950 (estimate)
[storage temp. ]

2-8°C
[pka]

-0.33±0.40(Predicted)
[Uses]

Intermediate for dyes.
[CAS DataBase Reference]

92-41-1(CAS DataBase Reference)
[EPA Substance Registry System]

92-41-1(EPA Substance)
Safety DataBack Directory
[RIDADR ]

1759
[TSCA ]

TSCA listed
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

2904100090
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

1,8-Dihydroxynaphthylene-3,6-disulfonic acid-->ERIO GREEN B-->2,7-Dibromonaphthalene-->ERIO GREEN B-->2,7-NAPHTHALENEDITHIOL
Hazard InformationBack Directory
[Chemical Properties]

White, crystalline solid.Soluble in water. Combustible.
[Definition]

ChEBI: A naphthalenesulfonic acid in which the sulfo groups are attached to positions 2 and 7 of the naphthalene ring.
[Production Methods]

The 2,7-disulfonic acid is always the main product of high-temperature sulfonation of naphthalene, but at 160 C it converts slowly to an equilibrium mixture containing ca. 30 % of the 2,6-isomer. Crystallization of the pure product from conventional sulfonation is difficult, and alternative processes, (for example, reaction of naphthalene vapor with sulfur trioxide in the gas phase at 220 C) are said to give a purer product.
[Purification Methods]

Crystallise the acid from conc HCl. The disulfonamide has m 273o (from EtOH). [Beilstein 11 II 119, 11 III 463.]
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