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120-18-3

120-18-3 Structure

120-18-3 Structure
IdentificationMore
[Name]

Naphthalene-2-sulfonic acid
[CAS]

120-18-3
[Synonyms]

2-NAPHTHALENESULFONIC ACID
BETA-NAPHTHALENESULFONIC ACID
BETA NAPTHALENE SULPHONATE
Naphthalene-2-sulfonic acid
NAPHTHALENE-2-SULPHONIC ACID
β-Naphthalene sulfonic acid
2-Naphthalenesulfonicacid,tri
beta-naphthalenesulfonic
beta-naphthylsulfonicacid
kyselina2-naftalensulfonova
2-NAPHTHALENESULFONIC ACID, TECH., 70%
2-NAPHTHALENESULFONIC ACID MONOHYDRATE(BETA-) 97+%
Naphthalene-2-sulfonic acid hydrate, tech., 70%
NAPHTHALENE-2-SULFONICACID,MONOHYDRATE(BETA-)
BETA-NAPHTHALENE-SULPHONICACID
2-NAPHTHALENESULFONIC ACID 98% HPLC
NAPHTHALENE-2-SULPHONIC ACID (FREE ACID) extrapure
2-Sulfonaphthalene
Dirinal NSK
[EINECS(EC#)]

204-375-3
[Molecular Formula]

C10H8O3S
[MDL Number]

MFCD00004089
[Molecular Weight]

208.23
[MOL File]

120-18-3.mol
Chemical PropertiesBack Directory
[Appearance]

Nondeliquescent, white plates.Soluble in water, alcohol, and ether. Combustible.
[Melting point ]

124 °C
[Boiling point ]

317.43°C (rough estimate)
[density ]

1.44 g/cm
[vapor pressure ]

2.33Pa at 20℃
[refractive index ]

1.4998 (estimate)
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

water: freely soluble(lit.)
[form ]

solid
[pka]

0.27±0.10(Predicted)
[color ]

White
[Water Solubility ]

Soluble in water.
[Sensitive ]

Hygroscopic
[Merck ]

6377
[InChI]

1S/C10H8O3S/c11-14(12,13)10-6-5-8-3-1-2-4-9(8)7-10/h1-7H,(H,11,12,13)
[InChIKey]

KVBGVZZKJNLNJU-UHFFFAOYSA-N
[SMILES]

OS(=O)(=O)c1ccc2ccccc2c1
[LogP]

-0.944 at 23℃
[Uses]

Starting point in the manufacture of β-naphthol, β-naphtholsulfonic acid, β-naphthylaminesulfonic acid, etc.
[CAS DataBase Reference]

120-18-3(CAS DataBase Reference)
[EPA Substance Registry System]

120-18-3(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H290-H314
[Precautionary statements ]

P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310
[Hazard Codes ]

C,F
[Risk Statements ]

R35:Causes severe burns.
R34:Causes burns.
R11:Highly Flammable.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 2583 8/PG 2
[WGK Germany ]

1
[RTECS ]

QK1225000
[Hazard Note ]

Corrosive
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

2904100090
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Met. Corr. 1
Skin Corr. 1A
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1-Naphthalenesulfonic acid-->Sodium 2-naphthalenesulfonate-->1-Naphthalenesulfinic acid-->DI-2-NAPHTHYLDISULPHIDE-->2-Naphthalenesulfonyl chloride-->2-Naphthalenethiol-->1,6-Naphthalenedisulfonic acid
[Preparation Products]

1-Naphthol-->2-Naphthol-->L-Leucine-->1-Aminonaphthalene-6-sulfonic acid-->Ambroxide-->1-Naphthalenesulfonic acid-->Sodium 2-naphthalenesulfonate-->disodium methylenebisnaphthalenesulphonate-->Acid Red 154-->disodium 3,3'-[cyclohexylidenebis[(2-methoxy-4,1-phenylene)azo]]bis(4,6-dihydroxynaphthalene-2-sulphonate)-->dispersant FDN-90-->1,8-DICHLORONAPHTHALENE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Naphthalenesulfonic acid(120-18-3).msds
Hazard InformationBack Directory
[Chemical Properties]

Nondeliquescent, white plates.Soluble in water, alcohol, and ether. Combustible.
[Definition]

ChEBI: A naphthalenesulfonic acid in which the sulfo group is linked to position 2 of the naphthalene ring.
[Preparation]

Naphthalene-2-sulfonic acid is prepared by sulfonation of naphthalene.
Step: With naphthalene as raw material, 98% sulfuric acid is used as sulfonating agent, and it is obtained by sulfonation at 160-166 ℃. During the sulfonation process, a small amount of α-naphthalenesulfonic acid by-product is generated. By heating, the unstable α-naphthalenesulfonic acid can be hydrolyzed at 140-150 °C to remove the sulfonic acid group, and become naphthalene and sulfuric acid. Naphthalene can be blown out. During the hydrolysis of naphthalene, a small amount of lye should be added to neutralize part of the sulfuric acid. It also acts with naphthalenesulfonic acid to form β-naphthalenesulfonic acid sodium salt crystals, which can be filtered to obtain the finished product of Naphthalene-2-sulfonic acid.
[General Description]

The fluorescence of 2-naphthalenesulfonic acid (NSA) is effectively quenched by colloidal silver via photoinduced interfacial electron transfer from the excited singlet of NSA to silver. Adsorption behavior of NSA on a conventional macroporous resin Amberlite XAD4 and hypercrosslinked resins NDA101 and NDA100 has been investigated.
[Flammability and Explosibility]

Nonflammable
[Purification Methods]

Crystallise the acid from conc HCl. The S-benzylisothiuronium salt has m 192o (from aqueous EtOH). [Berger Acta Chem Scand 8 432 1954, Beilstein 11 H 171, 11 IV 527.]
Spectrum DetailBack Directory
[Spectrum Detail]

Naphthalene-2-sulfonic acid(120-18-3)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Naphthalene-2-sulfonic acid hydrate, 95%(120-18-3)
[Sigma Aldrich]

120-18-3(sigmaaldrich)
[TCI AMERICA]

2-Naphthalenesulfonic Acid  Monohydrate,>98.0%(LC)(T)(120-18-3)
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