ChemicalBook--->CAS DataBase List--->92-77-3

92-77-3

92-77-3 Structure

92-77-3 Structure
IdentificationMore
[Name]

Naphthol AS
[CAS]

92-77-3
[Synonyms]

2-HYDROXY-3-NAPHTHOIC ACID ANILIDE
2-HYDROXY-3-NAPHTHOYLANILIDE
3-HYDROXY-2-NAPHTHANILIDE
3-HYDROXY-2-NAPHTHOIC ACID ANILIDE
3-Hydroxy-N-phenyl-2-naphthalenecarboxamide
3-HYDROXY-N-PHENYL-2-NAPHTHAMIDE
AZOIC COUPLING COMPONENT 2
azoic coupling component 4
CI 37505
c.i. 37560
CI NO 37505
NAPHTHOL AS
NAPHTHOL AS(TM)
NAPTHOL AS
TEREPHTHALBIS(O-HYDROXYANILIDE)
3-hydroxy-2-naphthanilid
3-hydroxy-n-phenyl-2-naphthalenecarboxamid
acconaphtholas
acnanaphtholc
amanilnaphtholas
[EINECS(EC#)]

202-188-1
[Molecular Formula]

C17H13NO2
[MDL Number]

MFCD00004096
[Molecular Weight]

263.29
[MOL File]

92-77-3.mol
Chemical PropertiesBack Directory
[Appearance]

beige powder
[Melting point ]

246-248 °C(lit.)
[Boiling point ]

406.53°C (rough estimate)
[density ]

1.1138 (rough estimate)
[refractive index ]

1.4500 (estimate)
[storage temp. ]

Refrigerator
[solubility ]

Insoluble in water; sparingly soluble in ethanol
[Colour Index ]

37505
[form ]

Powder
[pka]

9.70(at 25℃)
[color ]

Beige
[PH Range]

Non& uorescence (8.2) to yellow/green & uorescence (10.3)
[λmax]

394nm
[Major Application]

Sensors, recording materials, photovoltaic cells, copying materials, photoreceptors, lithographic printing plates, inks, toner, paints, textiles, detecting cancer
[Contact allergens]

Naphthol AS is a coupling agent in cotton dyeing, inducing occupational dermatitis or contact allergy in consumers in contact with cotton-dyed clothing. It has been indirectly reported as a cause of occupational allergy due to its coupling with Diazo Component 51, or as a crosssensitizer or sensitizer associated with Pigment Red 23 in red parts of tattoos. Pigmented contact dermatitis is usual in patients with a high phototype.
[CAS DataBase Reference]

92-77-3(CAS DataBase Reference)
[EPA Substance Registry System]

92-77-3(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

beige powder
[Hazard]

Low toxicity by ingestion.
[Description]

Naphtol AS is a coupling agent in cotton dying. Occupational dermatitis was reported in a woman involved in needlework, probably sensitized from occupational contact with clothes.
[Uses]

Naphtol AS was used as off-the-shelf color-based anion sensors in organic solvents.
[Preparation]

aniline and 3-Hydroxy-2-naphthoic acid?condensation.
[Properties and Applications]

rice or small red powder, melting point of 243 ~ 244 ℃, more sensitive to the air. In sodium hydroxide solution for yellow in liquid, insoluble in water and sodium carbonate solution, slightly soluble in ethanol, soluble in hot the difficulties. This product is widely used in the cotton fabric dyeing and printing. Dyeing cotton, cotton affinity is low, medium coupled ability. Can also be used for cotton yarn, polyester/cotton, PVA, viscose, silk and vinegar fiber dyeing, also can undertake direct printing, and reactive dye printing and cotton fabrics with the dye printing, discharge printing, the reactive dyes color printing and dyeing, and used to make quick pigment, fast amine element, element and organic pigment fast sulfonylurea medications.
[Purification Methods]

Crystallise it from xylene or AcOH which forms plates m 243-244o [Schnopper et al. Anal Chem 31 1542 1959]. [Beilstein 12 H 505.]
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H315-H317-H319-H411
[Precautionary statements ]

P261-P264-P272-P273-P280-P302+P352+P333+P313+P363-P305+P351+P338+P337+P313-P391-P501
[Hazard Codes ]

Xi,N
[Risk Statements ]

R43:May cause sensitization by skin contact.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

1
[RTECS ]

QJ1897400
[F ]

10-21
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29242990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium carbonate-->Phosphorus trichloride-->Aniline-->Chlorobenzene-->3-Hydroxy-2-naphthoic acid-->3-Hydroxy-2-naphthoic acid-->Aniline-->1-Naphthylamine
[Preparation Products]

Pigment Red 21-->Master-batches-->Pigment Fast Scarlet G-->Bronze Red-->Coating Brilliant Red-->Pigment Permanent Red RB-->Pigment Red 22-->Scarlet 808-->4,4'-bis[[2-hydroxy-3-[(phenylamino)carbonyl]-1-naphthyl]azo][1,1'-biphenyl]-2,2'-disulphonic disodium acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Naphthol AS(92-77-3).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Naphthol AS(92-77-3)MS
Naphthol AS(92-77-3)1HNMR
Naphthol AS(92-77-3)13CNMR
Naphthol AS(92-77-3)IR1
Naphthol AS(92-77-3)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Naphthol AS, 99%(92-77-3)
[Sigma Aldrich]

92-77-3(sigmaaldrich)
[TCI AMERICA]

3-Hydroxy-2-naphthanilide,>97.0%(LC)(T)(92-77-3)
92-77-3 suppliers list
Company Name: Henan yingchuang  Gold
Telephone: 16650708709
Website: www.hnyingchuang.com/
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: 3B Pharmachem (Wuhan) International Co.,Ltd.  
Telephone: 18930552037
Website: www.chemicalbook.com/showsupplierproductslist13285/0_en.htm
Company Name: TCI (Shanghai) Development Co., Ltd.  
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Shanghai Longsheng chemical Co.,Ltd.  
Telephone: 58099637 13585536065
Website: www.shlshg.com
Company Name: Shandong Xiya Chemical Co., Ltd  
Telephone: 13355009207 13355009207
Website: http://www.xiyashiji.com
Company Name: Sichuan Kulinan Technology Co., Ltd  
Telephone: 400-1166-196 18981987031
Website: http://www.hx-r.com/
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400 638 7771
Website: www.heowns.com
Company Name: Maya High Purity Chemicals  
Telephone: +86 (573) 82222445 (0)18006601000 452520369
Website: www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm
Company Name: Chengdu Ai Keda Chemical Technology Co., Ltd.  
Telephone: 4008-755-333 18080918076
Website: http://www.aikeshiji.com
Company Name: Shanghai civi chemical technology co.,Ltd  
Telephone: 86-21-34053660
Website: www.labgogo.com
Company Name: Thermo Fisher Scientific  
Telephone: 800-810-5118
Website: www.thermo.com.cn
Company Name: Beijing innoChem Science & Technology Co.,Ltd.  
Telephone: 400-810-7969 010-59572699
Website: www.inno-chem.com.cn
Company Name: Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.  
Telephone: 025-66113011 13913916777
Website: www.aikonchem.com/
Company Name: 9ding chemical ( Shanghai) Limited  
Telephone: 4009209199
Website: www.9dingchem.com
Company Name: Shanghai Aladdin Bio-Chem Technology Co.,LTD  
Telephone: 400-6206333 13167063860
Website: www.aladdin-e.com/
Tags:92-77-3 Related Product Information
135-19-3 106-49-0 591-27-5 95-53-4 90-15-3 92-78-4 135-65-9 104-94-9 78628-80-5 100-63-0 135-62-6 4273-92-1 1914-99-4 3689-20-1 4433-79-8 132-68-3 92-74-0 18531-94-7