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927-63-9

927-63-9 Structure

927-63-9 Structure
IdentificationMore
[Name]

3-Dimethylaminoacrolein
[CAS]

927-63-9
[Synonyms]

3-(DIMETHYLAMINO)ACROLEIN
3-DIMETHYLAMINOACRYLALDEHYDE
(E)-3-(DIMETHYLAMINO)ACRYLALDEHYDE
n,n-dimethylamino-2-propen-3-al
(2E)-3-(Dimethylamino)-2-propenal
2-Propenal, 3-(dimethylamino)-
beta-(Dimethylamino)acrolein
(2E)-3-(DIMETHYLAMINO)PROP-2-ENAL
3-(Dimethylamino)-2-propene-1-one
3-(Dimethylamino)propenal
[EINECS(EC#)]

213-157-7
[Molecular Formula]

C5H9NO
[MDL Number]

MFCD00006999
[Molecular Weight]

99.13
[MOL File]

927-63-9.mol
Chemical PropertiesBack Directory
[Boiling point ]

270-273 °C(lit.)
[density ]

0.99 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.584(lit.)
[Fp ]

>230 °F
[storage temp. ]

2-8°C
[form ]

Liquid
[pka]

6.79±0.70(Predicted)
[color ]

Clear yellow to brown
[BRN ]

969389
[InChI]

InChI=1S/C5H9NO/c1-6(2)4-3-5-7/h3-5H,1-2H3
[InChIKey]

RRLMPLDPCKRASL-UHFFFAOYSA-N
[SMILES]

C(=O)C=CN(C)C
[CAS DataBase Reference]

927-63-9(CAS DataBase Reference)
[NIST Chemistry Reference]

N,N-Dimethylamino-2-propen-3-al(927-63-9)
Questions And AnswerBack Directory
[Description]

3-Dimethylaminoacrolein is an organic compound with the formula Me2NC(H)=CHCHO. It is a pale yellow water-soluble liquid. The compound has a number of useful and unusual properties, e.g. it causes a reversal of the hypnotic effect of morphine in miceand has astimulating effect in humans.
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3267 8/PG 2
[WGK Germany ]

3
[F ]

8-19
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29223990
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Skin Corr. 1B
Hazard InformationBack Directory
[Uses]

3-Dimethylaminoacrolein was used in synthesis of:
  • benzochlorins, benzoisobacteriochlorins and benzobacteriochlorins
  • styryl-substituted Z/E-chlorin derivatives with chlorophyll-a skeleton
  • Y shaped cyanines having dimethylamino end groups
[Synthesis]

3-Dimethylaminoacrylaldehyde can be regarded as an amino-substituted unsaturated aldehyde compound, which can be prepared from N,N-dimethylformamide and ethyl alkenyl ether by condensation reaction.
Spectrum DetailBack Directory
[Spectrum Detail]

3-Dimethylaminoacrolein(927-63-9)1HNMR
3-Dimethylaminoacrolein(927-63-9)IR
3-Dimethylaminoacrolein(927-63-9)FT-IR
3-Dimethylaminoacrolein(927-63-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

927-63-9(sigmaaldrich)
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