ChemicalBook--->CAS DataBase List--->95-84-1

95-84-1

95-84-1 Structure

95-84-1 Structure
IdentificationMore
[Name]

2-Amino-p-cresol
[CAS]

95-84-1
[Synonyms]

2-AMINO-4-CRESOL
2-AMINO-4-METHYLPHENOL
2-AMINO-P-CRESOL
2-HYDROXY-5-METHYLANILINE
3-AMINO-4-HYDROXYTOLUENE
6-HYDROXY-M-TOLUIDINE
CRESAMINE
O-AMINO-P-CRESOL
O-AMINO-P-METHYLPHENOL
2-amino-4-methyl-pheno
2-AMINO-PARA-CRESOL, 97%
Phenol, 2-amino-4-methyl-
2-AMINO-4-METHYLPHENOL/2-AMINO-P-CRESOL/3-AMINO-4-HYDROXYTOLUENE
2-Amino-p-cresol (OH=1)
2-Amino-p-cresol, 2-Hydroxy-5-methylaniline, 3-Amino-4-hydroxytoluene
(2-Hydroxy-5-methylphenyl)amine
1-Amino-2-hydroxy-5-methylbenzene
5-Methyl-2-hydroxyaniline
4-Methyl-2-aminophenol
[EINECS(EC#)]

202-457-3
[Molecular Formula]

C7H9NO
[MDL Number]

MFCD00007699
[Molecular Weight]

123.15
[MOL File]

95-84-1.mol
Chemical PropertiesBack Directory
[Appearance]

White crystal powder
[Melting point ]

133-136 °C(lit.)
[Boiling point ]

229.26°C (rough estimate)
[density ]

1.0877 (rough estimate)
[refractive index ]

1.5706 (estimate)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

slightly soluble
[form ]

Flakes or Crystalline Powder
[pka]

10.06±0.18(Predicted)
[color ]

Beige to gray-brown
[Water Solubility ]

slightly soluble
[Detection Methods]

HPLC
[BRN ]

606494
[InChI]

InChI=1S/C7H9NO/c1-5-2-3-7(9)6(8)4-5/h2-4,9H,8H2,1H3
[InChIKey]

ZMXYNJXDULEQCK-UHFFFAOYSA-N
[SMILES]

C1(O)=CC=C(C)C=C1N
[CAS DataBase Reference]

95-84-1(CAS DataBase Reference)
[EPA Substance Registry System]

95-84-1(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Skull and Crossbones (GHS06)
GHS07,GHS06
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H301-H335
[Precautionary statements ]

P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

2
[RTECS ]

SJ6078000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29222900
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium sulfide-->2-Nitro-p-cresol-->tert-butyl 2-hydroxy-5-methylphenylcarbamate-->4-DIMETHYLAMINOAZOBENZENE-4'-ARSENIC ACID-->2-PHENYLAZO-4-METHYLPHENOL
[Preparation Products]

Fluorescent Brightener 135-->Fluorescent Brightener Pf-->N-(2-hydroxy-5-methylphenyl)-N'-phenylthiourea-->2-Mercapto-5-methylbenzoxazole-->2,6-Dimethyl-2H-benzo[b][1,4]oxazin-3(4H)-one-->2,5-Dimethylbenzoxazole-->Reactive blue 40-->Mordant Green 10-->SOLOCHROME GREEN V-->2-[[4-[[4-[bis(2-hydroxyethyl)amino]-6-chloro-1,3,5-triazin-2-yl]amino]phenyl]azo]-p-cresol-->2H-1,4-Benzoxazine, 3-(4-chlorophenyl)-6-methyl-
Hazard InformationBack Directory
[General Description]

Brown powder.
[Reactivity Profile]

2-AMINO-4-METHYLPHENOL(95-84-1) reacts with strong oxidizing agents.
[Air & Water Reactions]

2-AMINO-4-METHYLPHENOL may be sensitive to prolonged exposure to air. Insoluble in water.
[Fire Hazard]

Flash point data for this chemical are not available, however 2-AMINO-4-METHYLPHENOL is probably combustible.
[Chemical Properties]

White crystal powder
[Uses]

2-Amino-4-methylphenol was used in the synthesis of novel functionalized spiropyran derivatives of 2H-1,3-benzoxazinone series.
[Purification Methods]

Recrystallise the cresol from H2O, Et2O or toluene. It sublimes in vacuo as plates or needles. The hydrochloride has m 222-224o (dec, from aqueous EtOH). [Beilstein 13 H 601, 13 I 227, 13 II 338, 13 III 1576.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Amino-4-methylphenol(95-84-1).msds
Spectrum DetailBack Directory
[Spectrum Detail]

2-Amino-p-cresol(95-84-1)MS
2-Amino-p-cresol(95-84-1)1HNMR
2-Amino-p-cresol(95-84-1)IR1
2-Amino-p-cresol(95-84-1)IR2
2-Amino-p-cresol(95-84-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Amino-p-cresol, 97%(95-84-1)
[Alfa Aesar]

2-Amino-4-methylphenol, 98%(95-84-1)
[Sigma Aldrich]

95-84-1(sigmaaldrich)
[TCI AMERICA]

2-Amino-p-cresol,>98.0%(T)(95-84-1)
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