ChemicalBook--->CAS DataBase List--->5344-90-1

5344-90-1

5344-90-1 Structure

5344-90-1 Structure
IdentificationMore
[Name]

2-Aminobenzylalcohol
[CAS]

5344-90-1
[Synonyms]

2-amino-benzenemethanol
2-AMINOBENZYL ALCOHOL
(2-AMINOPHENYL)METHANOL
2-HYDROXYMETHYLANILINE
O-AMINOBENZYL ALCOHOL
O-AMINOPHENYLCARBINOL
RARECHEM AQ BD 0001
2-amino-benzenemethano
Benzenemethanol, 2-amino-
Benzyl alcohol, o-amino-
o-(Hydroxymethyl)aniline
o-amino-benzylalcoho
o-Aminobenzylic alcohol
o-aminobenzylicalcohol
2-Aminobenzylalcohol(o-Aminobenzylalcohol)
oABAIc
2-AMINOBENZYL ALCOHOL 98%
O-ACETAMINOPHENOL
2-Aminobenzene-1-methanol
o-Aminobenzenemethanol
[EINECS(EC#)]

226-293-7
[Molecular Formula]

C7H9NO
[MDL Number]

MFCD00007749
[Molecular Weight]

123.15
[MOL File]

5344-90-1.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

81-83 °C(lit.)
[Boiling point ]

162 °C15 mm Hg(lit.)
[density ]

1.0877 (rough estimate)
[refractive index ]

1.4905
[Fp ]

160°C/10mm
[storage temp. ]

2-8°C
[form ]

Crystalline Powder
[pka]

14.21±0.10(Predicted)
[color ]

Beige to gray-brown
[Water Solubility ]

Very soluble in water.
[BRN ]

1072211
[InChI]

1S/C7H9NO/c8-7-4-2-1-3-6(7)5-9/h1-4,9H,5,8H2
[InChIKey]

VYFOAVADNIHPTR-UHFFFAOYSA-N
[SMILES]

Nc1ccccc1CO
[CAS DataBase Reference]

5344-90-1(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Aminobenzyl alcohol(5344-90-1)
[EPA Substance Registry System]

5344-90-1(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[RTECS ]

DN3155000
[F ]

8-10-23
[Hazard Note ]

Irritant
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29221980
[Storage Class]

11 - Combustible Solids
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Hydroxymethyl aniline(5344-90-1).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.
2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.
[Application]

A double dehydrogenative coupling of 2-aminobenzyl alcohol with secondary aryl alcohols furnishes 2-arylquinolines in good to excellent yields under mild and sustainable conditions. The reaction is catalyzed by the molecularly defined phosphine-free nickel complex.
[General Description]

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.
[storage]

Keep Cold. Air Sensitive. Light Sensitive.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Aminobenzyl alcohol(5344-90-1)MS
2-Aminobenzyl alcohol(5344-90-1)1HNMR
2-Aminobenzyl alcohol(5344-90-1)13CNMR
2-Aminobenzyl alcohol(5344-90-1)IR1
2-Aminobenzyl alcohol(5344-90-1)IR2
2-Aminobenzyl alcohol(5344-90-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Aminobenzyl alcohol, 98%(5344-90-1)
[Alfa Aesar]

2-Aminobenzyl alcohol, 98%(5344-90-1)
[Sigma Aldrich]

5344-90-1(sigmaaldrich)
[TCI AMERICA]

2-Aminobenzyl Alcohol,>98.0%(T)(5344-90-1)
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