| Identification | More | [Name]
2-Aminobenzylalcohol | [CAS]
5344-90-1 | [Synonyms]
2-amino-benzenemethanol
2-AMINOBENZYL ALCOHOL
(2-AMINOPHENYL)METHANOL
2-HYDROXYMETHYLANILINE
O-AMINOBENZYL ALCOHOL
O-AMINOPHENYLCARBINOL
RARECHEM AQ BD 0001
2-amino-benzenemethano
Benzenemethanol, 2-amino-
Benzyl alcohol, o-amino-
o-(Hydroxymethyl)aniline
o-amino-benzylalcoho
o-Aminobenzylic alcohol
o-aminobenzylicalcohol
2-Aminobenzylalcohol(o-Aminobenzylalcohol)
oABAIc
2-AMINOBENZYL ALCOHOL 98%
O-ACETAMINOPHENOL
2-Aminobenzene-1-methanol
o-Aminobenzenemethanol | [EINECS(EC#)]
226-293-7 | [Molecular Formula]
C7H9NO | [MDL Number]
MFCD00007749 | [Molecular Weight]
123.15 | [MOL File]
5344-90-1.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
81-83 °C(lit.)
| [Boiling point ]
162 °C15 mm Hg(lit.)
| [density ]
1.0877 (rough estimate) | [refractive index ]
1.4905
| [Fp ]
160°C/10mm | [storage temp. ]
2-8°C
| [form ]
Crystalline Powder | [pka]
14.21±0.10(Predicted) | [color ]
Beige to gray-brown | [Water Solubility ]
Very soluble in water. | [BRN ]
1072211 | [InChI]
1S/C7H9NO/c8-7-4-2-1-3-6(7)5-9/h1-4,9H,5,8H2 | [InChIKey]
VYFOAVADNIHPTR-UHFFFAOYSA-N | [SMILES]
Nc1ccccc1CO | [CAS DataBase Reference]
5344-90-1(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Aminobenzyl alcohol(5344-90-1) | [EPA Substance Registry System]
5344-90-1(EPA Substance) |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.
2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate. | [Application]
A double dehydrogenative coupling of 2-aminobenzyl alcohol with secondary aryl alcohols furnishes 2-arylquinolines in good to excellent yields under mild and sustainable conditions. The reaction is catalyzed by the molecularly defined phosphine-free nickel complex.
| [General Description]
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. | [storage]
Keep Cold. Air Sensitive. Light Sensitive.
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