| Identification | More | [Name]
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex | [CAS]
95464-05-4 | [Synonyms]
[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), COMPLEX WITH DICHLOROMETHANE (1:1)
[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DCM ADDUCT
[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DICHLOROMETHANE ADDUCT
[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II) DICHLOROMETHANE COMPLEX
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE
[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) CHLORIDE, 1:1 COMPLEX WITH DICHLOROMETHANE
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE, COMPLEX WITH DICHLOROMETHANE
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE, DICHLOROMETHANE
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE COMPLEX
DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]-PALLADIUM DICHLOROMETHANE ADDUCT
DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE ADDUCT
DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE COMPLEX
[PdCl2(dppf)]CH2Cl2
Palladium[PdCl2(dppf)]CH2Cl2
PALLADIUM, [1,1''-BIS(DIPHENYLPHOSPHINO-.KAPPA.P)FERROCENE]DICHLORO-, (SP-4-2)-, COMPD. WITH DICHLOROMETHANE
Pd（dppf）2Cl2
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd 13%
[1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(R) tablets
ChemDose(R), [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II )complex with dichloromethane impregnated tablets
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE ADDUCT | [EINECS(EC#)]
619-128-9 | [Molecular Formula]
C35H30Cl4FeP2Pd 10* | [MDL Number]
MFCD00792899 | [Molecular Weight]
816.64 | [MOL File]
95464-05-4.mol |
| Chemical Properties | Back Directory | [Appearance]
orange/red solid | [Melting point ]
275-280 °C(lit.)
| [density ]
1 g/cm3 | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Powder | [color ]
orange-red | [Water Solubility ]
Insoluble in water. | [Detection Methods]
NMR | [Stability:]
Light Sensitive | [InChI]
InChI=1S/2C17H11P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-6,9-12,18H;1H2;2*1H;;/q;;;;;+2;/p-2 | [InChIKey]
VRMVBERIWPSLSJ-UHFFFAOYSA-L | [SMILES]
C(Cl)Cl.[Cl-][Pd+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-] | [CAS DataBase Reference]
95464-05-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302+H312+H332-H315-H319-H335 | [Precautionary statements ]
P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338 | [Hazard Codes ]
Xn | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect. | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves . | [WGK Germany ]
3 | [TSCA ]
No | [HS Code ]
28439000 |
| Hazard Information | Back Directory | [Chemical Properties]
orange/red solid | [Uses]
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines,it is also used as a catalyst for Suzuki and Stile couplings.
| [Uses]
suzuki reaction | [Uses]
Used as a catalyst for Suzuki and Stile couplings. | [Application]
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst | [Synthesis]
1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;
2. Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;
3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex crystal, yield 90.46%.
In this method, the target product 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%. |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the borylation of aryl halides.
- β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates.
- Catalyst for modified Negishi coupling.
- Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.
- Catalyst for Stille allylation.
- Catalyst for the amination of aryl bromides.
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|