| Identification | More | [Name]
2-Amino-4-nitrophenol | [CAS]
99-57-0 | [Synonyms]
2-AMINO-4-NITROPHENOL
2-HYDROXY-5-NITROANILINE
3-AMINO-4-HYDROXYNITROBENZENE
4-NAP
4-NITRO-2-AMINOPHENOL
PARA NITRO 2-AMINO PHENOL
P-NITRO-O-AMINOPHENOL
p-Nitro-o-aminophenol 4-Nitro-2-aminophenol
1-amino-2-hydroxy-5-nitrobenzene
1-hydroxy-2-amino-4-nitrobenzene
2-amino-4-nitrofenol
2-amino-4-nitro-pheno
4-nitro-2-aminofenol
4-nitro-2-aminofenol(czech)
amino-2nitro-4phenol
c.i.76530
ci76530
nci-c55958
p-nitroaminofenol
rodol42 | [EINECS(EC#)]
202-767-9 | [Molecular Formula]
C6H6N2O3 | [MDL Number]
MFCD00007695 | [Molecular Weight]
154.12 | [MOL File]
99-57-0.mol |
| Chemical Properties | Back Directory | [Appearance]
OCHRE CRYSTALLINE POWDER | [Melting point ]
140-143 °C (lit.) | [Boiling point ]
322.46°C (rough estimate) | [density ]
1.3617 (estimate) | [vapor pressure ]
0.005Pa at 25℃ | [refractive index ]
1.6890 (rough estimate) | [Fp ]
100 °C
| [storage temp. ]
Refrigerator, Under Inert Atmosphere | [solubility ]
DMSO (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
6.82±0.22(Predicted) | [color ]
Dark Yellow to Brown | [Water Solubility ]
slightly soluble | [Detection Methods]
HPLC | [BRN ]
776533 | [LogP]
1.26 | [CAS DataBase Reference]
99-57-0(CAS DataBase Reference) | [IARC]
3 (Vol. 57) 1993 | [EPA Substance Registry System]
99-57-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R68:Possible risk of irreversible effects.
R43:May cause sensitization by skin contact.
R40:Limited evidence of a carcinogenic effect.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing . | [RIDADR ]
2811 | [WGK Germany ]
2
| [RTECS ]
SJ6300000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29071990 | [Hazardous Substances Data]
99-57-0(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Orange prisms or yellow powder. No odor. | [Reactivity Profile]
Oxidation of this chemical may occur in the presence of air and violent decomposition may occur if 2-AMINO-4-NITROPHENOL(99-57-0) is allowed to dry out completely at elevated temperatures. 2-AMINO-4-NITROPHENOL(99-57-0) is stable when stored protected from light and under nitrogen for two weeks at temperatures up to 140° F, and storage under nitrogen for up to 24 weeks at room temperature (77° F) should produce no loss of stability. This chemical is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. 2-AMINO-4-NITROPHENOL(99-57-0) is also incompatible with iron. | [Air & Water Reactions]
Insoluble in water. | [Fire Hazard]
Flash point data for this chemical are not available. 2-AMINO-4-NITROPHENOL is probably combustible. | [Chemical Properties]
OCHRE CRYSTALLINE POWDER | [Uses]
2-Amino-4-nitrophenol is used in preparing some mordant
dyes and in some hair dyes. | [Uses]
An aromatic constituent found in hair dyes and other cosmetic products with very low levels of mutagenic activity. | [Definition]
ChEBI: 2-Amino-4-nitrophenol is a member of 4-nitrophenols. | [Synthesis Reference(s)]
Organic Syntheses, Coll. Vol. 3, p. 82, 1955
The Journal of Organic Chemistry, 45, p. 4992, 1980 DOI: 10.1021/jo01312a039 | [Flammability and Explosibility]
Nonflammable | [Purification Methods]
Crystallise the phenol from water. [Beilstein 13 IV 896.] |
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