ChemicalBook--->CAS DataBase List--->999-81-5

999-81-5

999-81-5 Structure

999-81-5 Structure
IdentificationMore
[Name]

Chlormequat chloride
[CAS]

999-81-5
[Synonyms]

(2-CHLORETHYL)TRIMETHYLAMMONIUM CHLORIDE
(2-CHLOROETHYL)TRIMETHYLAMMONIUM CHLORIDE
AC 38555
ATLAS QUINTACEL
CCC700
CECECE
CEKU-CCC
CHLORMEQUAT
CHLORMEQUAT CHLORIDE
CHLOROCHOLINE CHLORIDE
CHOLINE DICHLORIDE
CROPSAFE 5C
CYCLOCEL(R)
CYCOCEL
CYCOCEL(R)
CYCOGAN
HORMOCEL
(2-chloroethyl)
chlormequat-chloride(aliphaticalkylquaternaries)
chlormequatchloride,aqueoussolution
[EINECS(EC#)]

213-666-4
[Molecular Formula]

C5H13Cl2N
[MDL Number]

MFCD00011869
[Molecular Weight]

158.07
[MOL File]

999-81-5.mol
Chemical PropertiesBack Directory
[Definition]

A phytocidal bipyridilium quaternary ammonium salt.
[Appearance]

Chlormequat chloride is a white to yellowish crystalline solid with a fish-like odor.
[Melting point ]

239-243 °C (dec.)(lit.)
[Boiling point ]

260.3°C (rough estimate)
[density ]

1.2228 (rough estimate)
[refractive index ]

1.5500 (estimate)
[storage temp. ]

0-6°C
[solubility ]

DMSO (Slightly), Methanol (Slightly)
[form ]

Crystalline Powder or Crystals
[color ]

White to off-white
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents. Corrodes many metals. Very hygroscopic.
[Water Solubility ]

almost transparency
[Sensitive ]

Hygroscopic
[Merck ]

14,2104
[BRN ]

3563994
[Henry's Law Constant]

3.2×109 mol/(m3Pa) at 25℃, Maniere et al. (2011)
[Major Application]

agriculture
environmental
[InChI]

1S/C5H13ClN.ClH/c1-7(2,3)5-4-6;/h4-5H2,1-3H3;1H/q+1;/p-1
[InChIKey]

UHZZMRAGKVHANO-UHFFFAOYSA-M
[SMILES]

[Cl-].C[N+](C)(C)CCCl
[CAS DataBase Reference]

999-81-5(CAS DataBase Reference)
[EPA Substance Registry System]

999-81-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
[RIDADR ]

UN 2811 6.1/PG 3
[WGK Germany ]

2
[RTECS ]

BP5250000
[F ]

3-10
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29239000
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 4 Oral
[Safety Profile]

Human poison by ingestion and intravenous routes. Moderately toxic by skin contact. Human systemic effects: respiratory depression. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported.
[Hazardous Substances Data]

999-81-5(Hazardous Substances Data)
[Toxicity]

LD50 in mice (mg/kg): 7 i.v., 54 orally (Hennighausen, Wiegershausen)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Trimethylamine-->Dichloroethane-->Bromocholine chloride-->CHOLINE
Hazard InformationBack Directory
[General Description]

White crystals with a fishlike odor. Used as a plant growth regulator. Said to be effective for cereal grains, tomatoes, and peppers.
[Reactivity Profile]

CHLORMEQUAT CHLORIDE(999-81-5) is incompatible with strong oxidizing agents. CHLORMEQUAT CHLORIDE(999-81-5) is corrosive to unprotected metals.
[Air & Water Reactions]

Very hygroscopic. Water soluble. Aqueous solutions are acidic.
[Hazard]

Toxic; corrosive.
[Health Hazard]

Inhalation of spray and prolonged or repeated contact with skin should be avoided.
[Potential Exposure]

People engaged in the manufacture, formulation, and application of this plant growth regulator said to be effective for cereal grains, tomatoes, and peppers.
[Fire Hazard]

Flash point data for this chemical are not available; however, CHLORMEQUAT CHLORIDE is probably combustible.
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

Chlormequat chloride decomposes on heating or in fire forming nitrogen oxides, carbon monoxide, and hydrogen chloride fumes. This chemical decomposes on heating with strong aqueous alkali solutions forming trimethylamine and other gaseous products. Contact with strong oxidizers may cause fire and explosions. Attacks many metals in presence of water.
[Description]

Chlormequat chloride is a white to yellowishcrystalline solid with a fish-like odor. Molecularweight=158.1; Freezing/Melting point=245℃ (decomposes); Hazard Identification (based on NFPA 704 M RatingSystem): Health 3, Flammability 0, Reactivity 0. Highly soluble in water. Carrier solvents used in commercial productsmay alter physical and toxicological properties.
[Chemical Properties]

Chlormequat chloride is a white to yellowish crystalline solid with a fish-like odor.
[Chemical Properties]

white or light yellow crystals
[Waste Disposal]

Incinerate in a unit with effluent gas scrubbing.
[Uses]

Chlorocholine Chloride is a plant growth regulator that is primarily used on ornamental plants.
[Uses]

Plant growth regulator on ornamental plants.
[Production Methods]

Chlormequat chloride is produced through a straightforward chemical synthesis involving two key reactants: ethylene dichloride and trimethylamine. Ethylene dichloride is typically heated in a reactor and trimethylamine is introduced either in liquid or gaseous form. This reaction produces chlormequat chloride via quaternization of the amine.
[Agricultural Uses]

Plant growth regulator: Said to be effective for cereal grains, tomatoes, and peppers; cotton, grapes, mango, tobacco, vegetables. In California, major uses are in greenhouse plants and flowers and in nurseries, including geraniums, azaleas, hibiscus.
[Trade name]

AC 38555®; ADJUST®, ATLAS CHLORMEQUAT®; CCC PLANT GROWTH REGULANT®; 60-CS-16®; CYCLOCEL®; CYCOCEL®; CYCOCEL-EXTRA®; CYCOGAN®; CYCOGAN EXTRA®; CYOCEL®; EI 38,555®; HICO CCC®; HORMOCEL-2CCC®; INCRECEL®; LIHOCIN®; RETACEL®; RETACIL®; STABILAN®; TUR®; WR 62®
[Biochem/physiol Actions]

Chlormequat (Chlorocholine) chloride is a synthetic plant growth regulator that inhibits gibberellin (GA) biosynthesis. It is used to study the mechanisms and effects of gibberellins on plant cell growth and differentiation.
[Mechanism of action]

Gibberellin biosynthesis inhibitor - reducing cell elongation
[storage]

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with chlormequat chloride you should be trained on its proper handlingand storage. Keep away from strong oxidizers. Store in acool, dry place and protect from heat and moisture. Sourcesof ignition, such as smoking and open flames, are prohibited where this chemical is used, handled, or stored in amanner that could create a potential fire or explosionhazard.
[Pesticide Type]

Plant Growth Regulator
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

(2-Chloroethyl)trimethylammonium chloride(999-81-5).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Chlormequat chloride(999-81-5)MS
Chlormequat chloride(999-81-5)1HNMR
Chlormequat chloride(999-81-5)13CNMR
Chlormequat chloride(999-81-5)IR1
Chlormequat chloride(999-81-5)IR2
Chlormequat chloride(999-81-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(2-Chloroethyl)trimethylammonium chloride, 98%(999-81-5)
[Alfa Aesar]

(2-Chloroethyl)trimethylammonium chloride, 98% (dry wt.), may cont. up to 5% water(999-81-5)
[Sigma Aldrich]

999-81-5(sigmaaldrich)
[TCI AMERICA]

Chlorocholine Chloride,>98.0%(T)(999-81-5)
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