1-Aminoanthrachinon
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- CAS-Nr.
- 82-45-1
- Bezeichnung:
- 1-Aminoanthrachinon
- Englisch Name:
- 1-Aminoanthraquinone
- Synonyma:
- 1-AMINOANTHRAQUINONE;1-aminoanthracene-9,10-dione;1AAQ;CI 37275;Fast Red AL;diazofastredal;Smoke Orange G;Diazo Fast Red AL;1-Aminoanthrachinon;1-AMINOANTHRAQUIONE
- CBNumber:
- CB9435391
- Summenformel:
- C14H9NO2
- Molgewicht:
- 223.23
- MOL-Datei:
- 82-45-1.mol
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1-Aminoanthrachinon Eigenschaften
- Schmelzpunkt:
- 253-255 °C (lit.)
- Siedepunkt:
- 364.52°C (rough estimate)
- Dichte
- 1.1814 (rough estimate)
- Brechungsindex
- 1.4700 (estimate)
- storage temp.
- room temp
- Löslichkeit
- Soluble in alcohol, benzene, chlroform, ether, glacial acetic acid, HCl
- Aggregatzustand
- powder to crystal
- Colour Index
- 37275
- pka
- -0.51±0.20(Predicted)
- Farbe
- Orange to Brown to Dark red
- Wasserlöslichkeit
- 312.5ug/L(25 ºC)
- Merck
- 14,417
- BRN
- 396360
- Stabilität:
- Stable. Incompatible with acids, acid chlorides, acid anhydrides, chloroformates, strong oxidizing agents.
- CAS Datenbank
- 82-45-1(CAS DataBase Reference)
- NIST chemische Informationen
- 1-Aminoanthraquinone(82-45-1)
- EPA chemische Informationen
- 1-Aminoanthraquinone (82-45-1)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| R-Sätze: |
36/37/38 |
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| S-Sätze: |
24/25 |
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| RIDADR |
3077 |
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| WGK Germany |
1 |
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| RTECS-Nr. |
CB5075000 |
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| TSCA |
Yes |
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| HazardClass |
9 |
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| PackingGroup |
III |
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| HS Code |
29223900 |
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| Bildanzeige (GHS) |
  
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P305+P351+P338,P337+P313P |
| H320 |
Causes eye irritation |
Serious eye damage/eye irritation |
Category 2B |
Warnung |
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P264, P305+P351+P338,P337+P313 |
| H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizität (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
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| H373 |
Kann die Organe schädigen bei längerer oder wiederholter Exposition. |
Spezifische Zielorgan-Toxizität (wiederholte Exposition) |
Kategorie 2 |
Warnung |
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P260, P314, P501 |
| H410 |
Sehr giftig für Wasserorganismen mit langfristiger Wirkung. |
Langfristig (chronisch) gewässergefährdend |
Kategorie 1 |
Warnung |
![GHS hazard pictograms]() src="/GHS09.jpg" width="20" height="20" /> |
P273, P391, P501 |
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| Sicherheit |
| P260 |
Dampf/Aerosol/Nebel nicht einatmen. |
| P261 |
Einatmen von Staub vermeiden. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P273 |
Freisetzung in die Umwelt vermeiden. |
| P304+P340 |
BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
| P314 |
Bei Unwohlsein ärztlichen Rat einholen / ärztliche Hilfe hinzuziehen. |
| P391 |
Verschüttete Mengen aufnehmen. |
| P405 |
Unter Verschluss aufbewahren. |
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1-Aminoanthrachinon Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
deep brown crystalline powder. Soluble in hot nitrobenzene, toluene, xylene, ether, acetic acid, chloroform, benzene, slightly soluble in cold ethanol, insoluble in water.
Verwenden
1-Aminoanthraquinone is the most important intermediate for manufacturing acid, reactive, disperse, and vat dyes.
Application
1-Aminoanthraquinone has the ability to increase the solubility of anthraquinone derivatives in supercritical carbon dioxide. It is widely used in the preparation of various anthraquinone dyes. It also bridges Pt nanoparticles on carbon nanotubes as efficient electrocatalysts.
synthetische
1-Aminoanthraquinone (1-AAQ) is synthesized by the condensation of 2-substituted benzoic acid and xylene to yield 2-substituted-dimethylbenzophenone, subsequent oxidation of the methyl groups, ring closure to form a 1-substituted anthraquinone carboxylic acid, replacement of the 1-substituent with ammonia, and decarboxylation.
Hazard
Toxicity studies showed histopathological changes in the kidneys and spleen, loss of breastfeeding behaviour, decreased pup survival on day 4 after birth, repeated doses and reproductive toxicity less than 40 mg/kg/day (lowest tested dose) of NOAEL.
No adverse effects on reproductive parameters or teratogenicity were observed. caused excitability, weight loss, and liver and kidney changes in an inhalation study in rats; orthocytotic anaemia, weight loss, and organ changes (liver, spleen and heart) in a 2-week oral study in guinea pigs; and was not irritating to the skin or eyes of rabbits.
Sicherheitsprofil
Moderately toxic by intraperitoneal route. An eye irritant. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic NO,. See also AMINES
Synthese
Anthraquinone is sulfonated with nicotinic sulfuric acid in the presence of a small amount of mercury salt to generate anthraquinone-1-sulfonic acid, which is then neutralized with potassium hydroxide to form anthraquinone sulfonic acid potassium salt. Under high temperature and high pressure, ammonia and anthraquinone sulfonic acid potassium The salt action generates 1-aminoanthraquinone, and the generated sulfite reacts with the product again and the quality of the product decreases. Therefore, nitrobenzene sulfonate is usually used as an oxidant to oxidize sulfite to sulfate, which itself is reduced to m-aminobenzenesulfonic acid.
1-Aminoanthrachinon Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
VAT BLACK 27
Anthra[2,1,9-mna]naphth[2,3-h]acridin-5,10,15(16H)-trion
Disperse Red 146
1-Amino-2,4-dibromanthrachinon
Disperse Red 127
Disperse Red 53
4',4'''-Azobis[N-(9,10-dihydro-9,10-dioxo-1-anthryl)[1,1'-biphenyl]-4-carboxamid]
Anthra[9,1,2-cde]benzo[rst]pentaphen-5,10-dion, Amino-, Reaktionsprodukte mit 1-Amino-9,10-anthracendion und Tetrabrom-8,16-pyranthrendion
6,8,25,27-Tetrahydrobisnaphtho[2',3':6,7]indolo[2,3-c:2',3'-c']dinaphtho[2,3-i:2',3'-i']benzo[1,2-a:5,4-a']dicarbazol-5,7,9,14,19,24,26,28,33,38-decaon
1H-Benz[6,7]indazol[2,3,4-fgh]naphth[2'',3'':6',7']indolo[3',2':5,6]anthra[2,1,9-mna]acridin-2,7,10,15-tetron
3-(Anthrachinon-1-ylamino)anthra[2,1,9-mna]naphth[2,3-h]acridin-5,10,15(16H)-trion
1-Amino-4-hydroxy-2-(2-methoxyethoxy)anthrachinon
1-Amino-4-hydroxy-2-[(6-hydroxyhexyl)oxy]anthrachinon
Bromaminic acid
1-Amino-4-hydroxy-2-phenoxyanthrachinon
4-[(1-Amino-9,10-dihydro-4-hydroxy-9,10-dioxo-2-anthryl)oxy]-N-(3-ethoxypropyl)benzolsulfonamid
Vat Grey M
Kayalon Polyester Light Red BL-SE
DISPERSE RED 55
1-Aminoanthrachinon Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 343)Lieferanten
82-45-1(1-Aminoanthrachinon)Verwandte Suche:
Glycin
Anthrachinon
1,4-Dihydroxy-5,8-bis[[2-[(2-hydroxyethyl)amino]ethyl]amino]anthrachinondihydrochlorid
Mitoxantrone
ALTRENOGEST
Betain
1-Nitroanthrachinon
2-AMINOANTHRAQUINONE
Mitoxantrone HCL for Injection (Lyophilized Power)
1,2-Diaminoanthrachinon
1,4-Bis[(2-methylphenyl)amino]anthrachinon
1,4-Diaminoanthrachinon
1,4-Bis[(2-ethyl-6-methylphenyl)amino]anthrachinon
1,8-Diaminoanthrachinon
1-Amino-4-(methylamino)anthrachinon
1-(Methylamino)anthrachinon
1,5-Diaminochlor-4,8-dihydroxyanthrachinon
1,8-Dihydroxy-4-[[4-(2-hydroxyethyl)phenyl]amino]-5-nitroanthrachinon
- Diazo Fast Red AL
- alpha-Anthraquinonylamine
- Anthraquinone, 1-amino-
- .alpha.-Aminoanthraquinone
- 10-Anthracenedione,1-amino-9
- 1-amino-10-anthracenedione
- 1-Amino-9,10-anthraquinone
- 1-Aminoanthra-9,10-quinone
- 1-Aminoanthrachinon
- 1-amino-anthraquinon
- 9,10-Anthracenedione, 1-amino-
- 9,10-Anthracenedione,1-amino-
- alpha.-Aminoanthraquinone
- alpha-Aminoanthraquinone
- A-ANTHRAQUINONYLAMINE
- 1-Aminoanthraquinone,97%
- 1-AMINOANTHRAQUIONE
- 1-amino-9,10-anthracenedione
- CI 37275
- diazofastredal
- Smoke Orange G
- α-aminoanthrapuinone
- 1AAQ
- 1-Aminoanthraquinone,90%
- alpha.-AMinoanthraqu
- Fast Red AL
- 1-Aminoanthraquinone@100 μg/mL in Toluene
- 1-AMINOANTHRAQUINONE FOR SYNTHESIS
- 1-Amino anthraquinone ISO 9001：2015 REACH
- Factory Price of 1-Amino Anthraquinone CAS 82-45-1 From China Supplier
- 1-aminoanthracene-9,10-dione
- 1-AMINOANTHRAQUINONE
- 82-45-1
- C14H7O2NH2
- NH2C6H3COC6H4CO
- Organic Building Blocks
- Ketones
- C13 to C14
- Carbonyl Compounds
- Building Blocks
- Anthraquinones
- Aminoanthraquinones
- Intermediates of Dyes and Pigments
- Anthraquinones, Hydroquinones and Quinones
- Organics
- Aminoanthraquinones
- Anthraquinones
- A
- Stains and Dyes
- Stains&Dyes, A to
- C13 to C14
- Carbonyl Compounds
- Ketones
- bc0001
