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Aluminum acetylacetonate

Aluminum acetylacetonate
Aluminum acetylacetonate
CAS No.
13963-57-0
Chemical Name:
Aluminum acetylacetonate
Synonyms
Alumin;Dotite Al;AL(ACAC)3;Nacem Aluminum;ALUMINUM(III) AA;Aluminum Chelate A;Aluminum acetoacetonate;ACETYLACETONE ALUMINIUM;Alumium acety acetonate;2,4-Pentanedionoaluminum
CBNumber:
CB0410483
Molecular Formula:
C15H21AlO6
Formula Weight:
324.31
MOL File:
13963-57-0.mol

Aluminum acetylacetonate Properties

Melting point:
190-193 °C(lit.)
Boiling point:
315 °C(lit.)
Density 
1,27 g/cm3
Flash point:
314-316°C
storage temp. 
Store below +30°C.
solubility 
3g/l
form 
Crystalline Powder
color 
White to cream
PH
8 (3g/l, H2O, 20℃)
Water Solubility 
2.5 g/L (20 ºC)
BRN 
4157942
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
13963-57-0
NIST Chemistry Reference
Aluminum tris(acetylacetonate)(13963-57-0)
EPA Substance Registry System
Aluminum, tris(2,4-pentanedionato-.kappa. O,.kappa.O')-, (OC-6-11)-(13963-57-0)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T
Risk Statements  25-36/37/38-36-43
Safety Statements  26-36/37/39-45-28A-36/37
RIDADR  UN 3467 6.1/PG 2
WGK Germany  3
RTECS  BD2230000
Autoignition Temperature 500 °C
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29420000
Toxicity LD50 orally in Rabbit: 48.7 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

Aluminum acetylacetonate price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 208248 Aluminum acetylacetonate ReagentPlus , 99% 13963-57-0 100g $32.4 2018-11-13 Buy
Sigma-Aldrich 208248 Aluminum acetylacetonate ReagentPlus , 99% 13963-57-0 500g $102 2018-11-13 Buy
TCI Chemical A0241 Tris(2,4-pentanedionato)aluminum(III) >99.0%(T) 13963-57-0 25g $13 2018-11-22 Buy
TCI Chemical A0241 Tris(2,4-pentanedionato)aluminum(III) >99.0%(T) 13963-57-0 100g $28 2018-11-22 Buy
Alfa Aesar 012542 Aluminum 2,4-pentanedionate 13963-57-0 100g $29 2018-11-16 Buy

Aluminum acetylacetonate Chemical Properties,Uses,Production

Chemical Properties

Aluminium (III) acetylacetonate is a white to yellow powder or crystals in appearance. It is stable and incompatible with strong oxidizing agents.

Uses

Deposition of aluminum, catalyst.

Health Hazard

Exposures to aluminium (III) acetylacetonate cause adverse health effects. Exposures by inhalation, ingestion, and through skin contact are harmful. It causes irritation effects to the eyes, skin, and respiratory tract. Aluminium (III) acetylacetonate may release 2,4-pentanedione, which is a suspected teratogen and causes neurological health effects and harm to the unborn child. However, toxicology is not fully investigated.

Purification Methods

Recrystallise it several times from *benzene or aqueous MeOH, 216 and 286mn. max [Charles & Pawlikowski J Phys Chem 62 440 1958.] It can be purified by sublimation and has the following solubilities in g percent: *C6H6 35.9 (20o), 47.6 (40o), toluene 15.9 (20o), 22.0 (40o) and acetylacetone 6.6 (20o), 10.4 (40o). [Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3668.]

Aluminum acetylacetonate Preparation Products And Raw materials

Raw materials

Preparation Products


Aluminum acetylacetonate Suppliers

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Aluminum acetylacetonate Spectrum


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