ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE
- CAS No.
- 107905-52-2
- Chemical Name:
- ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE
- Synonyms
- Ethyl 2-(2,2,2-Trifluoroethyl Phosphono)propionate;ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE;Ethyl 2-(bis(2,2,2-trifluoroethoxy)phosphoryl)propanoate;2-[Bis(2,2,2-trifluoroethoxy)phosphinyl]propanoic Acid Ethyl Ester;Propanoic acid, 2-[bis(2,2,2-trifluoroethoxy)phosphinyl]-, ethyl ester
- CBNumber:
- CB1110483
- Molecular Formula:
- C9H13F6O5P
- Molecular Weight:
- 346.16
- MDL Number:
- MFCD04039536
- MOL File:
- 107905-52-2.mol
- MSDS File:
- SDS
Boiling point | 115-120°C/20mmHg |
---|---|
Density | 1.381±0.06 g/cm3(Predicted) |
storage temp. | Refrigerator |
solubility | Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly) |
form | Oil |
color | Clear Colourless to Pale Yellow |
CAS DataBase Reference | 107905-52-2 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H319-H302-H335-H315 |
Precautionary statements | P264-P270-P301+P312-P330-P501-P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P |
HS Code | 2931599090 |
ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE price More Price(4)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TRC | E900050 | Ethyl2-[Bis(2,2,2-trifluoroethyl)phosphono]Propionate | 107905-52-2 | 100mg | $120 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | OPC0000902 | ETHYL-2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO]PROPIONATE 95.00% | 107905-52-2 | 1G | $739.2 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | OPC0000902 | ETHYL-2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO]PROPIONATE 95.00% | 107905-52-2 | 5G | $960.75 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | OPC0000902 | ETHYL-2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO]PROPIONATE 95.00% | 107905-52-2 | 10G | $2333.1 | 2021-12-16 | Buy |
ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE Chemical Properties,Uses,Production
Chemical Properties
Colourless Liquid
Uses
A wittig reagent.
Uses
Ethyl 2-[Bis(2,2,2-trifluoroethyl)phosphono] Propionate is an organic synthesis reagent, mainly used in organic synthesis and chemical production.
Synthesis
KHMDS (7.50 mL, 3.75 mmol, 0.5 M in toluene) was added to a solution of 18- crown-6 (4.10 g, 15.51 mmol), THF (20 mL), and bis (2,2,2-trifluoroethyl) phosphite (1) (0.50 mL, 3.41 mmol) by syringe in a dropwise manner at -78 ℃. Following 15 min, ethyl 2-bromopropionate (0.40 mL, 3.08 mmol) was added to the round bottom flask and the reaction mixture was allowed to stir for 4 hr at room temperature. Following the standard workup procedure, the crude product was then purified by flash column chromatography (3:1 to 2:1 hexanes:EtOAc, Rf = 0.33 in 1:1 hexanes:EtOAc) yielding Ethyl 2-[Bis(2,2,2-trifluoroethyl)phosphono] Propionate (112 mg, 0.33 mmol, 10.5%) as a yellow syrup.
ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE Preparation Products And Raw materials
ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
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LEAP CHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 24738 | 58 |
J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
3B Pharmachem (Wuhan) International Co.,Ltd. | 821-50328103-801 18930552037 | 3bsc@sina.com | China | 15848 | 69 |
Chemsky(shanghai)International Co.,Ltd. | 021-50135380 | shchemsky@sina.com | China | 32344 | 50 |
Nanjing BAM Biomedical Technology Co., Ltd. | 18066080842 13952020641 | bamd@foxmail.com | China | 713 | 55 |
Nanjing Qishi Biotechnology Co. Ltd. | 19822610310 | 3122922726@qq.com | China | 1346 | 58 |
Shenzhen Polymeri Biochemical Technology Co., Ltd. | +86-400-002-6226 | sales@rrkchem.com | China | 56086 | 58 |
Nanjing Chengqian Pharmaceutical Technology Co., Ltd. | 025-52791040 18652036685 | haozhongwen@126.com | China | 731 | 58 |
Energy Chemical | 021-58432009 400-005-6266 | marketing1@energy-chemical.com | China | 44843 | 58 |
Cato Research Chemicals Inc. | 020-81960175-877 18933936954 | tianwen.zhan@cato-chem.com | China | 7734 | 58 |