BIS(TRIMETHYLSILYL)PEROXIDE
- CAS No.
- 5796-98-5
- Chemical Name:
- BIS(TRIMETHYLSILYL)PEROXIDE
- Synonyms
- Peroxybis(trimethylsilane);Bis-(trimethylsilyl)peroxid;BIS(TRIMETHYLSILYL)PEROXIDE;Silane, 1,1'-dioxybis[1,1,1-triMethyl-;triMethyl[(triMethylsilyl)peroxy]silane;Bis(trimethylsilyl)peroxide ~50% in HMDS;Bis(trimethylsilyl) Peroxide (ca. 30% in Hexane);Bis(triMethylsilyl) Peroxide (contains HexaMethyldisiloxane);Bis(trimethylsilyl) Peroxide (contains Hexamethyldisiloxane) (ca. 30% in Hexane)
- CBNumber:
- CB1330326
- Molecular Formula:
- C6H18O2Si2
- Molecular Weight:
- 178.38
- MDL Number:
- MFCD00270976
- MOL File:
- 5796-98-5.mol
- MSDS File:
- SDS
| Melting point | <0°C |
|---|---|
| Boiling point | 35 °C |
| Density | 0.829 |
| Flash point | <40°C |
| storage temp. | below 5° C |
| solubility | highly sol aprotic organic solvents. |
| form | Colourless Solution |
| Specific Gravity | 0.829 |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| CAS DataBase Reference | 5796-98-5 |
SAFETY
Risk and Safety Statements
| Risk Statements | 8-10 |
|---|---|
| Safety Statements | 17-36/37/39 |
| RIDADR | 3103 |
| TSCA | No |
| HS Code | 29319090 |
BIS(TRIMETHYLSILYL)PEROXIDE price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | B535285 | Bis(trimethylsilyl)peroxide~50%inHMDS | 5796-98-5 | 100mg | $475 | 2021-12-16 | Buy |
| TRC | B535285 | Bis(trimethylsilyl)peroxide~50%inHMDS | 5796-98-5 | 250mg | $1050 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | ORS0005351 | BIS-(TRIMETHYLSILYL)PEROXIDE 95.00% | 5796-98-5 | 100G | $1323 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | ORS0005351 | BIS-(TRIMETHYLSILYL)PEROXIDE 95.00% | 5796-98-5 | 5MG | $504.66 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | ORS0005351 | BIS-(TRIMETHYLSILYL)PEROXIDE 95.00% | 5796-98-5 | 10G | $522.81 | 2021-12-16 | Buy |
BIS(TRIMETHYLSILYL)PEROXIDE Chemical Properties,Uses,Production
Physical properties
bp 41°C/30 mmHg;7 n20 D 1.3970.
Uses
Bis(trimethylsilyl) peroxide is an organosilicon compound used as a reagent for Bayer-Villiger oxidation of ketones.
Uses
Bis(trimethylsilyl) peroxide (1)
functions as an electrophilic hydroxylating agent for aliphatic,
aromatic, and heteroaromatic anions.Reaction of their lithium
or Grignard compounds with (1) often affords trimethylsiloxy
intermediates, which undergo desilylation with HCl in methanol
to give the corresponding alcohols in good yields. In the presence
of a catalytic amount of trifluoromethanesulfonic acid, (1)
reacts with aromatic compounds to produce the corresponding
phenols after acidic workup.In these reactions the Me3SiO?
moiety is considered as a synthon of the hydroxyl cation
(i.e. OH+).
Preparation
obtained in 80–96% yields by reaction of chlorotrimethylsilane with 1,4-diazabicyclo[2.2.2]octane· (H2O2)2,hexamethylenetetramine·H2O2,or hydrogen peroxide–urea in CH2Cl2.
BIS(TRIMETHYLSILYL)PEROXIDE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15932 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
| Chemwill Asia Co.,Ltd. | 86-21-51086038 | chemwill_asia@126.com | CHINA | 23931 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006608290; 18621169109 | market03@meryer.com | China | 40241 | 62 |
| 3B Pharmachem (Wuhan) International Co.,Ltd. | 821-50328103-801 18930552037 | 3bsc@sina.com | China | 15848 | 69 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24539 | 81 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44751 | 61 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28398 | 80 |