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SILVER PERCHLORATE

Description References
SILVER PERCHLORATE
SILVER PERCHLORATE structure
CAS No.
7783-93-9
Chemical Name:
SILVER PERCHLORATE
Synonyms
SILVER PERCHLORATE;SILVER (I) PERCHLORATE;SILVER PERCHLORATE 99.9%;Perchloricacid,silver(1+)salt;Silver(I)perchlorate,anhydrous;perchloricacid,silver(1++)salt;Hyperchloric acid silver(I) salt;SILVER PERCHLORATE, ANHYDROUS, 97%;Silverperchlorate,anhydrous,min.97%;SILVER PERCHLORATE, ANHYDROUS REAGENT
CBNumber:
CB2180173
Molecular Formula:
AgClO4
Formula Weight:
207.32
MOL File:
7783-93-9.mol

SILVER PERCHLORATE Properties

Melting point:
486°C
Density 
2.8 g/mL at 25 °C(lit.)
solubility 
benzene: slightly soluble(lit.)
form 
Crystals
color 
White
Specific Gravity
2.806
Water Solubility 
Soluble in water and many organic solvents (benzene, toluene, pyridine)Soluble in water, benzene and toluene.
Sensitive 
Hygroscopic
Merck 
14,8523
Stability:
hygroscopic
InChIKey
YDHABVNRCBNRNZ-UHFFFAOYSA-M
CAS DataBase Reference
7783-93-9(CAS DataBase Reference)
EPA Substance Registry System
Perchloric acid, silver(1+) salt (7783-93-9)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS03,GHS05,GHS09
Signal word  Danger
Hazard statements  H272-H314-H318-H400
Precautionary statements  P221-P273-P303+P361+P353-P310-P210-P220-P260-P280-P305+P351+P338-P370+P378
Hazard Codes  O,C
Risk Statements  8-34
Safety Statements  17-26-27-36/37/39
RIDADR  UN 1481 5.1/PG 2
WGK Germany  3
3-8-10
TSCA  Yes
HazardClass  5.1
PackingGroup  II

SILVER PERCHLORATE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 674583 Silver perchlorate anhydrous, 97% 7783-93-9 5g $55.3 2019-12-02 Buy
Sigma-Aldrich 674583 Silver perchlorate anhydrous, 97% 7783-93-9 25g $194 2019-12-02 Buy
Alfa Aesar 042209 Silver perchlorate, anhydrous 7783-93-9 25g $177 2019-12-02 Buy
Alfa Aesar 042209 Silver perchlorate, anhydrous 7783-93-9 5g $46 2019-12-02 Buy
Strem Chemicals 93-4722 Silver perchlorate, anhydrous, min. 97% 7783-93-9 5g $50 2019-12-02 Buy

SILVER PERCHLORATE Chemical Properties,Uses,Production

Description

Silver perchlorate (chemical formula: AgClO4) is a silver salt of perchloric acid as both a useful source of the Ag+ ion and a catalyst in the organic chemistry. It should be noted that due to the high instability and explosiveness of the anion perchlorate contained in it, it is limited for usage in industry. It is a kind of strong oxidizer and can be used to promoting the oxidation reaction in the organic synthesis. It can also be used as a catalyst for which it can be used to replace a halide with perchlorates to form intermediate in synthesis. It can be manufactured through the heating reaction of the mixture of perchloric acid with silver nitrate, the reaction between barium perchlorate and silver sulfate, or the reaction of perchloric acid with silver oxide.

References

https://en.wikipedia.org/wiki/Silver_perchlorate
http://www.softschools.com/formulas/chemistry/silver_perchlorate_formula/393/

Chemical Properties

Colorless crystals. Soluble in water; reacts with explosive violence with many organic sol- vents; explodes on grinding.

Uses

In the explosives industry.

Purification Methods

Reflux it with *benzene (6mL/g) in a flask fitted with a Dean and Stark trap until all the water is removed azeotropically (ca 4hours). The solution is cooled and diluted with dry pentane (4mL/g of AgClO4). The precipitated AgClO4 is filtered off and dried in a desiccator over P2O5 at 1mm for 24hours [Radell et al. J Am Chem Soc 83 3958 1961]. It has also been recrystallised from perchloric acid. [Caution due to its EXPLOSIVE nature in the presence of organic matter.] Store it in the dark.

SILVER PERCHLORATE Preparation Products And Raw materials

Raw materials

Preparation Products


SILVER PERCHLORATE Suppliers

Global( 57)Suppliers
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SILVER PERCHLORATE Spectrum


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