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4-Nitrophthalimide

CAS No.
89-40-7
Chemical Name:
4-Nitrophthalimide
Synonyms
5-NITROISOINDOLINE-1,3-DIONE;5-NITROPHTHALIMIDE;AKOS B028733;4-Nitrophtalimide;4-nitro-phthalimid;4-NITROPHTHALIMIDE;4-Nirtophthalimide;P-NITRO-PHTHALIMIDE;PHTHALIMIDE, 4-NITRO-;4-Nitrophthalimide>
CBNumber:
CB3681521
Molecular Formula:
C8H4N2O4
Molecular Weight:
192.13
MDL Number:
MFCD00005884
MOL File:
89-40-7.mol
Modify Date:
2022-08-15 17:36:34

4-Nitrophthalimide Properties

Melting point 206 °C
Boiling point 328.09°C (rough estimate)
Density 1.5513 (rough estimate)
refractive index 1.4900 (estimate)
storage temp. Sealed in dry,Room Temperature
pka 7.79±0.20(Predicted)
color Yellow powder
Water Solubility <0.01 g/100 mL at 18 ºC
BRN 180224
Stability Stable. Combustible. Incompatible with moisture, water, strong oxidising agents, strong bases.
InChIKey ANYWGXDASKQYAD-UHFFFAOYSA-N
CAS DataBase Reference 89-40-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 26NA19UI3U
NIST Chemistry Reference 4-Nitro-phthalimide(89-40-7)
EPA Substance Registry System 4-Nitrophthalimide (89-40-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26-36-24/25
WGK Germany  3
RTECS  TI5625000
Hazard Note  Irritant
TSCA  Yes
HS Code  29251900
Toxicity mmo-sat 333 mg/plate EMMUEG 11(Suppl 12),1,88

4-Nitrophthalimide price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 332097 4-Nitrophthalimide 98% 89-40-7 5g $67.9 2022-05-15 Buy
Sigma-Aldrich 332097 4-Nitrophthalimide 98% 89-40-7 25g $286 2022-05-15 Buy
TCI Chemical N0247 4-Nitrophthalimide >98.0%(HPLC)(T) 89-40-7 25g $28 2022-04-27 Buy
TCI Chemical N0247 4-Nitrophthalimide >98.0%(HPLC)(T) 89-40-7 500g $272 2022-04-27 Buy
Alfa Aesar A12040 4-Nitrophthalimide, 98% 89-40-7 5g $37 2022-04-27 Buy
Product number Packaging Price Buy
332097 5g $67.9 Buy
332097 25g $286 Buy
N0247 25g $28 Buy
N0247 500g $272 Buy
A12040 5g $37 Buy

4-Nitrophthalimide Chemical Properties,Uses,Production

Chemical Properties

slight yellow powder

Uses

4-Nitrophthalimide is used as intermediate of organic synthesis and fluorescent dyes, it can be used to produce azo dyes, luminol, etc. It can also be used to prepare 4-nitrophthalonitrile, 5-cyanophthalide and other drug intermediates.

Preparation

4-Nitrophthalimide is synthesized from phthalimide by nitration. Cool the fuming nitric acid to below 5°C, slowly add concentrated sulfuric acid dropwise, and control the temperature to 10-13°C. Plus phthalimide. Leave at room temperature overnight. Then, it was poured into ice water with stirring, and the precipitate was precipitated below 20°C. Filter, wash with water, dry, and then recrystallize from ethanol to obtain 4-nitrophthalimide with a yield of 60%.

General Description

Yellow powder.

Air & Water Reactions

4-Nitrophthalimide can be hydrolyzed. . Insoluble in water.

Reactivity Profile

A nitrated amine. Amines are combustible. The combustion of amines yields noxious NOx. REACTIVITY - Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Aromatic nitro compounds range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

Fire Hazard

Flash point data for 4-Nitrophthalimide are not available, however 4-Nitrophthalimide is probably combustible.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits toxic vapors of NOx.

Global( 336)Suppliers
Supplier Tel Email Country ProdList Advantage
Frapp's ChemicalNFTZ Co., Ltd.
+86 (576) 8169-6106 sales@frappschem.com China 886 50
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29803 60
Beijing Cooperate Pharmaceutical Co.,Ltd
010-60279497 sales01@cooperate-pharm.com CHINA 1815 55
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 22021 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29960 58
Shenzhen Nexconn Pharmatechs Ltd
15013857715 admin@nexconn.com CHINA 3004 58
Jinan Shengqi pharmaceutical Co,Ltd
86+18663751872 christine@shengqipharm.com CHINA 494 58
Jinan Finer Chemical Co., Ltd
531-88989536 +8615508631887 sales@finerchem.com China 2991 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 +86-19930503282 alice@crovellbio.com China 5922 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 23034 58

View Lastest Price from 4-Nitrophthalimide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2022-02-25 4-Nitrophthalimide
89-40-7
US $25.12 / Kg/Drum 25Kg/Drum 99.00%HPLC 10tons/month Asia Chem I and E (Jiangsu) Co Ltd
2021-12-01 4-Nitrophthalimide
89-40-7
US $10.70 / Kg/Bag 10g 99% 10000kg Hebei Crovell Biotech Co Ltd
2021-08-17 4-Nitrophthalimide
89-40-7
US $1.00 / KG 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
AKOS B028733 5-NITRO-1,3-DIHYDRO-2H-ISOINDOL-1,3-DIONE 5-NITRO-1H-ISOINDOLE-1,3(2H)-DIONE 4 - nitro phthalates forMyl aMine 5-NITROISOINDOLE-1,3-DIONE 4-NITRO-1,2-BENZENE DICARBOXYLIC ACID, IMIDE 4-NITROPHTHALIMIDE PHTHALIMIDE, 4-NITRO- P-NITRO-PHTHALIMIDE 1H-Isoindole-1,3(2H)-dione, 5-nitro- 4-nitro-phthalimid 5-nitro-1h-isoindole-3(2h)-dione 4-Nirtophthalimide 5-Nitro-2H-isoindole-1,3-dione 4-Nitrophthalimide,98% 4-Nitrophtalimide 4-Nitrophthalimide> 4-Nitrophthalimide ISO 9001:2015 REACH 4-NITRO PHTHALIMIDE/4-Nitrophthalimide 5-NITROPHTHALIMIDE 5-NITROISOINDOLINE-1,3-DIONE 89-40-7 C8H4N2O4 Organic Building Blocks Cyclic Imides Building Blocks Carbonyl Compounds Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts N Stains and Dyes Stains&Dyes, A to