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CYCLOPENTADIENYLTRIMETHYLSILANE

CAS No.
3559-74-8
Chemical Name:
CYCLOPENTADIENYLTRIMETHYLSILANE
Synonyms
CPTMS;NSC 176274;Trimethylsilyl)1;Trimethylsilylcyclopentadien;TRIMETHYLSILYLCYCLOPENTADIENE;CYCLOPENTADIENYLTRIMETHYLSILANE;5-Trimethylsilylcyclopentadiene;1-(Trimethylsilyl)cyclopentadiene;TRIMETHYLSILYL)1,3-CYCLOPENTADIENE;2,4-Cyclopentadienyltrimethylsilane
CBNumber:
CB4263535
Molecular Formula:
C8H14Si
Molecular Weight:
138.28
MDL Number:
MFCD00010666
MOL File:
3559-74-8.mol
Last updated:2023-12-26 11:30:52

CYCLOPENTADIENYLTRIMETHYLSILANE Properties

Melting point -19 °C
Boiling point 32-34 °C12 mm Hg(lit.)
Density 0.833 g/mL at 25 °C(lit.)
refractive index n20/D 1.465
Flash point 29 °C
storage temp. -20°C
form liquid
Specific Gravity 0.833
color colorless
Sensitive Moisture Sensitive
CAS DataBase Reference 3559-74-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P210-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  23-24/25-36/37/39-26-16
RIDADR  UN 1993 3/PG 3
WGK Germany  3
10
HazardClass  3
PackingGroup  III
HS Code  29310099
NFPA 704
3
2 1

CYCLOPENTADIENYLTRIMETHYLSILANE price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 257885 Trimethylsilyl cyclopentadiene, mixture of isomers 3559-74-8 10g $345 2024-03-01 Buy
Alfa Aesar H27192 Trimethylsilylcyclopentadiene, mixture of isomers tech. 90% 3559-74-8 10g $239 2021-12-16 Buy
Alfa Aesar H27192 Trimethylsilylcyclopentadiene, mixture of isomers tech. 90% 3559-74-8 1g $53 2021-12-16 Buy
Strem Chemicals 14-7950 Trimethylsilylcyclopentadiene, 97% (mixture of isomers) 3559-74-8 1g $44 2024-03-01 Buy
Strem Chemicals 14-7950 Trimethylsilylcyclopentadiene, 97% (mixture of isomers) 3559-74-8 5g $158 2024-03-01 Buy
Product number Packaging Price Buy
257885 10g $345 Buy
H27192 10g $239 Buy
H27192 1g $53 Buy
14-7950 1g $44 Buy
14-7950 5g $158 Buy

CYCLOPENTADIENYLTRIMETHYLSILANE Chemical Properties,Uses,Production

Description

Cyclopentadienyltrimethylsilane (also known as trimethylsilyl cyclopentadiene) is a kind of organosilicon compound. It is used in the synthesis of some metal cyclopentadienyl complexes and has attracted interest for its structure owing to its property undergoing rapid sigmatropic rearrangement. It is a useful reactant involved in numerous reactions such as Diels-Alder reactions, synthesis of ring-functionalized molybdenocene complexes, allyl isomerization, aromatization of C5 rings and synthesis of N-hydroxyindoles via nucleophilic addition.

Sources

https://en.wikipedia.org/wiki/Trimethylsilyl_cyclopentadiene
https://www.sigmaaldrich.com/catalog/product/aldrich/257885?lang=en&region=US

Chemical Properties

Clear colorless liquid

Uses

Reactant involved in:

  • Diels-Alder reactions
  • Synthesis of ring-functionalized molybdenocene complexes
  • Allyl isomerization
  • Aromatization of C5 rings
  • Synthesis of N-hydroxyindoles via nucleophilic addition

Uses

Reactant involved in:• ;Diels-Alder reactions1,2• ;Synthesis of ring-functionalized molybdenocene complexes3• ;Allyl isomerization4• ;Aromatization of C5 rings5• ;Synthesis of N-hydroxyindoles via nucleophilic addition6

General Description

Trimethylsilyl cyclopentadiene reacts with ruthenium trichloride in alcohol solvent to yield ruthenocene.

CYCLOPENTADIENYLTRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 85)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 10248 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Hubei Co-Formula Material Tech Co., Ltd.
+86-27-84459282 sales@cfmats.com CHINA 882 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-18789408387 1057@dideu.com China 3537 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 9320 58

View Lastest Price from CYCLOPENTADIENYLTRIMETHYLSILANE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
CYCLOPENTADIENYLTRIMETHYLSILANE pictures 2023-12-26 CYCLOPENTADIENYLTRIMETHYLSILANE
3559-74-8
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Trimethylsilylcyclopentadiene  pictures 2020-01-07 Trimethylsilylcyclopentadiene
3559-74-8
US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd
		5-trimethylsilylcyclopentadiene pictures 2019-12-31 5-trimethylsilylcyclopentadiene
3559-74-8
US $1.00 / g 1KG Min98% HPLC g/kg/ton Career Henan Chemical Co

CYCLOPENTADIENYLTRIMETHYLSILANE Spectrum

TRIMETHYLSILYLCYCLOPENTADIENE Trimethylsilylcyclopentadiene (mixture of isomers) CPTMS CYCLOPENTADIENYLTRIMETHYLSILANE (2,4-CYCLOPENTADIEN-1-YL)TRIMETHYLSILANE 1-Trimethylsilyl-2,4-cyclopentadiene 5-Trimethylsilylcyclopentadiene Cyclopenta-2,4-dienyl-trimethyl-silane Silane, 2,4-cyclopentadien-1-yltrimethyl- 5-(TRIMETHYLSILYL)-1,3-CYCLOPENTADIENE Trimethylsilylcyclopentadien Trimethylsilylcyclopentadiene,97%(mixtureofisomers) Trimethylsilyl)1 TRIMETHYLSILYL)1,3-CYCLOPENTADIENE Trimethyl(2,4-cyclopentadienyl)silane Cyclopentadienyltrimethylsilane,70%,tech. Trimethylsilylcyclopentadiene, mixture of isomers, tech. 90% 2,4-Cyclopentadienyltrimethylsilane NSC 176274 1-(Trimethylsilyl)cyclopentadiene 1,3-Cyclopentadiene, 5-(trimethylsilyl)- CYCLOPENTADIENYLTRIMETHYLSILANE ISO 9001:2015 REACH Trimethylsilylcyclopentadiene, mixture of isomers, tech. 90%, Cyclopenta-2,4-dien-1-yltrimethylsilane 3559-74-8 C5H5SiCH33 Organic Building Blocks Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Si-(C)4 Compounds Alkenes Building Blocks Cyclic Building Blocks Chemical Synthesis Organic Building Blocks organosilicon compounds Si (Classes of Silicon Compounds) Si-(C)4 Compounds Silicon Compounds (for Synthesis) Synthetic Organic Chemistry Alkenes Cyclic Organic Building Blocks