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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate structure

CAS No.: 35193-64-7

Chemical Name:: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

Synonyms: (R)-(-)-BNP ACID;(R)-(-)-BPA;(R)-(-)-BNPA;(11bS)-;(S)-(+)-BPA;(S)-(+)-BNPA;(S)-(+)-BNDHP.;(S)-(+)-BNP ACID;(S)-(+)-1,1'-Binapht;Galactose Impurity 11

CBNumber:: CB5107331

Molecular Formula:: C20H13O4P

Molecular Weight:: 348.29

MDL Number:: MFCD00010045

MOL File:: 35193-64-7.mol

MSDS File:: SDS

Last updated:2024-02-07 18:17:11

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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Properties

Melting point	≥300 °C
alpha	607.5 º (c=1.4,MeOH)
Boiling point	619.5±38.0 °C(Predicted)
Density	1.49±0.1 g/cm3(Predicted)
refractive index	595 ° (C=1, MeOH)
storage temp.	Sealed in dry,Room Temperature
solubility	Soluble in DMSO and methanol (hot).
pka	1.14±0.20(Predicted)
form	Powder
color	white
optical activity	[α]22/D +595°, c = 1.35 in methanol
BRN	4787775
CAS DataBase Reference	35193-64-7(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315

Precautionary statements

Hazard Codes

Risk Statements

Safety Statements

WGK Germany

RTECS

RZ2475100

10-23

HS Code

29199000

NFPA 704

	1
2		0

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate price More Price(37)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	248940	(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate 97%	35193-64-7	1g	$114	2024-03-01	Buy
Sigma-Aldrich	248940	(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate 97%	35193-64-7	5g	$249	2024-03-01	Buy
TCI Chemical	B1144	(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >97.0%(T)	35193-64-7	1g	$59	2024-03-01	Buy
TCI Chemical	B1144	(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >97.0%(T)	35193-64-7	100mg	$16	2024-03-01	Buy
Alfa Aesar	L14137	(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%	35193-64-7	1g	$57.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
248940	1g	$114	Buy
248940	5g	$249	Buy
B1144	1g	$59	Buy
B1144	100mg	$16	Buy
L14137	1g	$57.65	Buy

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties,Uses,Production

Reaction

Asymmetric hetero Diels-Alder reaction catalyzed by chiral lanthanide(III) complex.
Highly efficient Mannich reaction
Acidic Resolving agent for certain amine/racemic mixtures.

Chemical Properties

white to light yellow crystal powde

Uses

Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

Uses

The S enantiomer of binaphthol derivative as chiral quenching agent.

Purification Methods

Recrystallise it from EtOH. Reflux for 3hours in N NaOH is required to hydrolyse the cyclic phosphate. [Jacques et al. Tetrahedron Lett 4617 1971, Arnold et al. Tetrahedron 24, 343 1983.]

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Suppliers

Global( 282)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	6709	58
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	424	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15965	58
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12722	58
SIMAGCHEM CORP	+86-13806087780	sale@simagchem.com	China	17367	58

Supplier	Advantage
Shanghai UCHEM Inc.	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
Shanghai Daken Advanced Materials Co.,Ltd	58
Nanjing ChemLin Chemical Industry Co., Ltd.	60
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Accela ChemBio Inc.	58
Chongqing Chemdad Co., Ltd	58
Zhengzhou Alfa Chemical Co.,Ltd	58
SIMAGCHEM CORP	58

View Lastest Price from (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-02-23	(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-64-7	US $65.00-213.00 / g	25g	0.98	25kg	Shanghai UCHEM Inc.
2024-02-07	(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-64-7	US $0.00-0.00 / kg	1kg	99	500	XINXIANG RUNYU MATERIAL CO., LTD.
2019-07-06	(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-64-7	US $1.00 / kg	1kg	98%	100KG	Career Henan Chemical Co

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
US $65.00-213.00 / g
0.98
Shanghai UCHEM Inc.

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
US $0.00-0.00 / kg
99
XINXIANG RUNYU MATERIAL CO., LTD.

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
US $1.00 / kg
98%
Career Henan Chemical Co

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Spectrum

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)MS (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)IR (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)Raman (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)FT-IR

35193-64-7((S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate)Related Search:

(S)-(-)-1,1'-Bi-2-naphthol Clindamycin phosphate 1,1'-Bi-2-naphthol SULPHOSUCCINIC ACID ESTER 1,1'-BINAPHTHYL

(+/-)-1,1''-BINAPHTHYL-2,2''-DIYL HYDROGENPHOSPHATE 99%,(+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE,1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE Water treatment agent POE (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (R)-3,3'-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE

(S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

1of3

(S)-(+)-BNP ACID (S)-(+)-BNPA (S)-(+)-BPA (S)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOPHEPIN-4-OXID (S)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE (S)-(+)-1,1'-BINAPHTHELENE-2,2'-DIYL-PHOSPHATE (S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE S-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE (S)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE S(+)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE S(+)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE (S)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE (S)-4-HYDROXYDINAPHTHO[2,1-D:1'',2''-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE: (S)-(+)-BNP ACID (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+% (11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-Oxide (S)-(+)-1,1μ-Binaphthalene-2,2μ-diyl hydrogen phosphate, (S)-4-Hydroxydinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98% [aS,(+)]-2,2'-Phosphinicobisoxy-1,1'-binaphthalene (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate,99% (S)-(+)-1,1'-Binapht (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate (11bS)- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate (S)-(+)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide, (S)-(+)-BNDHP (11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate,(S)-(-)-BNDHP (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE R(-)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE (R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE (R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID (R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE 2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE (+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE (S)-(+)-BNDHP. S-(+)BNP ACID / S-(-)-1,1''-BINAPHTHYL-2,2''-DIPHEMYL PHOSPHINE (S)-(+)-1,1-Binaphthyl-2,2'-dihydrogenphosphate (S)-(+)-1,1'-binaphthyl-2 (S)-(+)-BINAPHTHYL-2,2'-DIYL HYDROGENPHO SPHATE S-(+)-1,1Binaphthalene-2,2Dihydrogen Phosphate (S)-(+)-1,1'-Binaphthyl-2,2'-diylhydrogenephosphate (S)-(+)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE (S)-(+)-1,1'-Binaphthyl-2,2'-d (S)-(+)-1,1'-Binaphthyl-2,2'-diylhydrogenphosphate,min.98% Dinaphtho2,1-d:1,2-f1,3,2dioxaphosphepin, 4-hydroxy-, 4-oxide, (11bS)- S)-(+)-1,1'-Binaphthyl-2,2'-diyl (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 97% (S)-(+)-1,1'-Biphthyl-2,2'-diyl hydrogenphosphate (S)-1,1'-Binaphthalene-2,2'-diyl Hydrogen Phosphate,99%e.e. (S)-(+)-1,1'-Binaphthalene-2,2'-diyl-phosphate for synthesis Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-, 4-oxide, (S)- (11bS)-4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (S)-(+)-1,1'-BINAPHTHE (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate > (R)-(-)-BPA (R)-(-)-BNPA (R)-(-)-BNP ACID (+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate