ChemicalBook >> CAS DataBase List >>4,4'-Dibromo-2,2'-diiodobiphenyl

4,4'-Dibromo-2,2'-diiodobiphenyl

CAS No.
852138-89-7
Chemical Name:
4,4'-Dibromo-2,2'-diiodobiphenyl
Synonyms
4,4'-Dibromo-2,2'-diiodobiphenyl;2,2'-Diiodo-4,4'-dibromobiphenyl;4,4'-Dibromo-2,2'-diiodobiphenyl;4,4'-Dibromo-2,2'-diiodobiphenyl >4,4'-Dibromo-2,2'-diiodo-1,1'-biphenyl;4,4'-DibroMo-2,2'-diiodo-1,1'-biphenyl;1,1'-Biphenyl, 4,4'-dibroMo-2,2'-diiodo-;4-bromo-1-(4-bromo-2-iodophenyl)-2-iodobenzene
CBNumber:
CB52534603
Molecular Formula:
C12H6Br2I2
Molecular Weight:
563.79
MDL Number:
MFCD14582983
MOL File:
852138-89-7.mol
Last updated:2023-06-08 17:06:36

4,4'-Dibromo-2,2'-diiodobiphenyl Properties

Melting point 91℃
Boiling point 477.6±45.0 °C(Predicted)
Density 2.438
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to crystal
color White to Yellow

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P280-P305+P351+P338
HS Code  2903.99.8001

4,4'-Dibromo-2,2'-diiodobiphenyl price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D4560 4,4'-Dibromo-2,2'-diiodobiphenyl >98.0%(GC) 852138-89-7 200mg $191 2024-03-01 Buy
TRC D423008 4,4''-Dibromo-2,2’-diiodobiphenyl 852138-89-7 50mg $75 2021-12-16 Buy
TRC D423008 4,4''-Dibromo-2,2’-diiodobiphenyl 852138-89-7 250mg $210 2021-12-16 Buy
American Custom Chemicals Corporation HCH0365239 4,4'-DIBROMO-2,2'-DIIODO-1,1'-BIPHENYL 95.00% 852138-89-7 0.25G $238 2021-12-16 Buy
AK Scientific 6297AL 4,4'-Dibromo-2,2'-diiodobiphenyl 852138-89-7 1g $344 2021-12-16 Buy
Product number Packaging Price Buy
D4560 200mg $191 Buy
D423008 50mg $75 Buy
D423008 250mg $210 Buy
HCH0365239 0.25G $238 Buy
6297AL 1g $344 Buy

4,4'-Dibromo-2,2'-diiodobiphenyl Chemical Properties,Uses,Production

Uses

4,4''-Dibromo-2,2’-diiodobiphenyl (CAS# 852138-89-7) is a useful building block, and is seen in the preparation of hybrid organic/inorganic heterofluorene polymers and in low band-gap polymers for use in photovoltaics.

Synthesis

Synthesis_852138-89-7
Synthesis of 4,4'-Dibromo-2,2'-diiodobiphenyl A solution of diamine (16.0 g, 46.8 mmol) and concentrated HCl (56.0 mL) in water (64.0 mL) was cooled to 0 ??C. Next, 8.0g (116 mmol) of NaNO2 in 40 mL of water was added dropwise to the diamine solution over a period of 30 min, keeping the temperature at 0 ??C. After the addition of NaNO2 was complete, the resulting mixture was stirred for an additional 30 min. and an aqueous solution of KI (77.7 g in 150 mL of water) at-5 ??C was added dropwise over 30 min. The reaction mixture was then stirred (by mechanical stirrer) for 1h at r.t and 3 h at 60 ??C, giving a dark brown solution. The solution was then cooled to 25 ??C and the brown precipitate was collected by filtration. The crude brown solid was then purified by column chromatography (silica gel, hexane). The title compound as a white solid (7.4 g, 28 % yield). 1H NMR (CDCl3): |? (ppm) 7.04 (2H, d), 7.57 (2H, d), 8.11 (2H, s).

3460-18-2
852138-89-7
Synthesis of 4,4'-Dibromo-2,2'-diiodobiphenyl from 2,5-Dibromonitrobenzene

4,4'-Dibromo-2,2'-diiodobiphenyl Preparation Products And Raw materials

Global( 104)Suppliers
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Suzhou Victorypharm Co.,Ltd.
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CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58

View Lastest Price from 4,4'-Dibromo-2,2'-diiodobiphenyl manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4,4'-Dibromo-2,2'-diiodobiphenyl pictures 2019-12-26 4,4'-Dibromo-2,2'-diiodobiphenyl
852138-89-7
US $0.10 / KG 1KG 95%-99% 1kg; 100kg Career Henan Chemical Co
2,2'-Diiodo-4,4'-dibromobiphenyl 1,1'-Biphenyl, 4,4'-dibroMo-2,2'-diiodo- 4,4'-Dibromo-2,2'-diiodobiphenyl 4,4'-DibroMo-2,2'-diiodo-1,1'-biphenyl 4-bromo-1-(4-bromo-2-iodophenyl)-2-iodobenzene 4,4'-Dibromo-2,2'-diiodobiphenyl > 4,4'-Dibromo-2,2'-diiodobiphenyl 4,4'-Dibromo-2,2'-diiodo-1,1'-biphenyl 852138-89-7 852138-89-1 C12H6Br2I2