METHYLTRIOXORHENIUM(VII)
- CAS No.
- 70197-13-6
- Chemical Name:
- METHYLTRIOXORHENIUM(VII)
- Synonyms
- MTO;METHYLTRIOXORHENIUM;METHYLRHENIUM TRIOXIDE;trioxorhenium(VII);Methyltrioxorhenium(Ⅶ);METHYLTRIOXORHENIUM(7);METHYLTRIOXORHENIUM(VII);Methyltrioxo rhenium (V11);METHYLRHENIUM TRIOXIDE(VII);Methylrhenium(VII) trioxide
- CBNumber:
- CB5353770
- Molecular Formula:
- CH3O3Re
- Molecular Weight:
- 249.24
- MDL Number:
- MFCD00192332
- MOL File:
- 70197-13-6.mol
- MSDS File:
- SDS
Melting point | 111 °C(lit.) |
---|---|
Boiling point | 65°C 0mm |
Density | d23 4.21 |
form | crystal |
color | colorless to pale-gray |
Water Solubility | Soluble in water. |
Sensitive | Moisture & Light Sensitive |
Merck | 14,6130 |
BRN | 3927932 |
FDA UNII | 883D8RDD5Q |
METHYLTRIOXORHENIUM(VII) price More Price(15)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 412910 | Methyltrioxorhenium(VII) Re 71.0-76.0 % | 70197-13-6 | 100mg | $58.9 | 2024-03-01 | Buy |
Sigma-Aldrich | 412910 | Methyltrioxorhenium(VII) Re 71.0-76.0 % | 70197-13-6 | 2g | $428 | 2024-03-01 | Buy |
TCI Chemical | M1296 | Methyltrioxorhenium(VII) >97.0%(T) | 70197-13-6 | 100mg | $38 | 2024-03-01 | Buy |
Alfa Aesar | L18478 | Methyltrioxorhenium(VII), 98% | 70197-13-6 | 500mg | $106 | 2021-12-16 | Buy |
Alfa Aesar | L18478 | Methyltrioxorhenium(VII), 98% | 70197-13-6 | 100mg | $30.7 | 2021-12-16 | Buy |
METHYLTRIOXORHENIUM(VII) Chemical Properties,Uses,Production
Reactions
Catalyst used with H2O2 for oxidation of a variety of substrates.
(a) Alkenes
(b) Secondary amines
(c) Arenes
(d) Silyl enol ethers/Silyl ketene acetals
(e) Sulfides
(f) Bayer-Villager-Type oxidation
(g) Amine oxidation
(h) Phenol oxidation
Chemical Properties
white to blue-grey crystals
Uses
Potent catalytic oxidant for converting alkenes to epoxides in a variety of solvents and 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone (Vitamin K3).
Catalytic oxidant used with urea hydrogen peroxide in an efficient conversion of imines to nitrones.
An effective antioxidant under various conditions.
Uses
Methyltrioxorhenium(VII) is used as a catalyst for various transformations such as olefin metathesis. It is associated with hydrogen peroxide and used as an oxidizing agent. It is used to prepare acid or ester from the corresponding terminalalkynes. It is a catalytic oxidant used with urea hydrogen peroxide to prepare nitrones. It reacts with 2-methylnaphthalene to get 2-methyl-1,4-naphthoquinone (Vitamin K3). Further, it catalyzes the reaction with aldehydes and diazoketones to get an alkene. In addition to this, it is used as an effective antioxidant under various conditions.
METHYLTRIOXORHENIUM(VII) Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21700 | 55 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 12321 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9802 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
sgtlifesciences pvt ltd | +8617013299288 | dj@sgtlifesciences.com | China | 12382 | 58 |
Alfa Chemistry | +1-5166625404 | Info@alfa-chemistry.com | United States | 21317 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25363 | 58 |