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Vinyl bromide

Vinyl bromide
Vinyl bromide structure
CAS No.
593-60-2
Chemical Name:
Vinyl bromide
Synonyms
C2H3Br;R1140B1;Bromethen;NCI-C50373;SAYTEX VBR;Bromoethene;bromo-ethen;Bromethylen;Vinylbromid;-139 (lit.)
CBNumber:
CB5853922
Molecular Formula:
C2H3Br
Formula Weight:
106.95
MOL File:
593-60-2.mol

Vinyl bromide Properties

Melting point:
−139 °C(lit.)
Boiling point:
16 °C750 mm Hg(lit.)
Density 
1.517 g/mL at 25 °C(lit.)
vapor density 
3.8 (15 °C, vs air)
vapor pressure 
1551 mm Hg ( 37.8 °C)
refractive index 
n20/D 1.410
Flash point:
1 °F
storage temp. 
2-8°C
explosive limit
15%
Water Solubility 
insoluble
BRN 
1361370
Exposure limits
TLV-TWA 5 ppm (~22 mg/m3)(ACGIH); Lowest Detectable Level (NIOSH); car cinogenicity: Suspected Human Carcinogen (ACGIH), Animal Sufficient Evidence (IARC).
Stability:
Stable, but may polymerize in sunlight. Reacts violently with all types of oxidizer. Incompatible with strong oxidizing agents, peroxides, copper, copper alloys, plastics. Highly flammable.
InChIKey
INLLPKCGLOXCIV-UHFFFAOYSA-N
CAS DataBase Reference
593-60-2(CAS DataBase Reference)
NIST Chemistry Reference
Ethene, bromo-(593-60-2)
EPA Substance Registry System
Ethene, bromo-(593-60-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  F+,T,F
Risk Statements  45-12-19-36/37-22-11
Safety Statements  53-9-16-29-33-45-26
RIDADR  UN 1993 3/PG 1
WGK Germany  3
RTECS  KU8400000
3-10
Autoignition Temperature 986 °F
HazardClass  2.1
PackingGroup  II
HS Code  29033990
Hazardous Substances Data 593-60-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H280 Contains gas under pressure; may explode if heated Gases under pressure Compressed gas
Liquefied gas
Dissolved gas
Warning P410+P403
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P410+P403 Protect from sunlight. Store in a well-ventilated place.

NFPA 704

Diamond Hazard Value Description
0
1
Health  
Flammability   0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride)
Instability   1 Normally stable, but can become unstable at elevated temperatures and pressures (e.g. propene)
Special  

(NFPA, 2010)

Vinyl bromide price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 434191 Vinyl bromide solution 1.0 M in THF 593-60-2 100ml $76.7 2018-11-13 Buy
Sigma-Aldrich 434191 Vinyl bromide solution 1.0 M in THF 593-60-2 800ml $332 2018-11-13 Buy
TCI Chemical V0127 Vinyl Bromide (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L) 593-60-2 100mL $96 2018-11-22 Buy
Sigma-Aldrich V1902 Vinyl bromide 98% 593-60-2 100g $143 2018-11-20 Buy
Sigma-Aldrich V1902 Vinyl bromide 98% 593-60-2 900g $375 2018-11-20 Buy

Vinyl bromide Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Chemical Properties

Vinyl bromide is a colorless gas or liquid at low ambient temperature. Pleasant odor. Shipped as a liquefied compressed gas with 0.1% phenol added to prevent polymerization.

Uses

Vinyl bromide is used as a fire retardant inplastics.

General Description

Boiling point 60°F. Liquid at low ambient temperatures. Specific gravity 1.51. A suspected carcinogen. Under exposure to fire or heat containers may rupture violently and rocket.

Air & Water Reactions

Highly flammable, with air forms peroxides

Reactivity Profile

VINYL BROMIDE is a light sensitive, peroxidizable monomer may initiate exothermic polymerization of the bulk material [Handling Chemicals Safely 1980.. p. 958]. Vinyl bromide will react violently with oxidants.

Health Hazard

Vapors may cause dizziness or asphyxiation without warning. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases.

Health Hazard

Inhalation of this gas at high concentrationscan produce anesthesia and kidney damage.Exposure to 2.5% concentration in air pro duced anesthetic effects in rats. A 15-minuteexposure to 10% concentration was fatal torats (ACGIH 1986). Kidney injury occurredat a 5% exposure level. Human toxicity datafor this compound are not available. The liq uid is mild to moderately irritating to theeyes.
Vinyl bromide manifested carcinogenicproperties in laboratory animals. It producedliver and blood tumors in rats and mice.Its cancer-causing effects in humans arenot known. However, on the basis of itssimilarity to vinyl chloride, it is suspectedto be a human carcinogen.

Fire Hazard

EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Silane will ignite spontaneously in air. May polymerize explosively when heated or involved in a fire. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. Can react violently with oxidzing materials. May polymerize in sunlight. To fight fire, use CO2, dry chemical, or water spray. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES and VINYL CHLORIDE.

Potential Exposure

Vinyl bromide is used as an intermediate in organic synthesis and for the preparation of plastics by polymerization and copolymerization; as a comonomer with acrylonitrile and other vinyl monomers in modacrylic fibers; in the production of flame-retardant synthetic fibers.

Shipping

UN1085 Vinyl bromide, stabilized, Hazard Class: 2.1; Labels: 2.1-Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

Incompatibilities

Vinyl bromide is a dangerous chemically unstable compound that may polymerize spontaneously in heat, sunlight and possibly exposure to UV. Dangerously reactive with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, acetylene, strong acids, strong bases, copper compounds. Add 0.1% phenol to gas to prevent polymerization.

Waste Disposal

Return refillable compressed gas cylinders to supplier. Nonrefillable cylinders should be disposed of in accordance with local, state and federal regulations. Allow remaining gas to vent slowly into atmosphere in an unconfined area or exhaust hood. Refillabletype cylinders should be returned to original supplier with any valve caps and outlet plugs secured and valve protection caps in place.

Vinyl bromide Preparation Products And Raw materials

Raw materials

Preparation Products


Vinyl bromide Suppliers

Global( 80)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32452 55
Hangzhou FandaChem Co.,Ltd.
0086 158 5814 5714 (Mobile; WhatsApp; Telegram)
+86-571-56059825 fandachem@gmail.com CHINA 2734 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 25796 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23959 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20084 58
Hubei xin bonus chemical co. LTD
13657299721
zhangyuzhu@xhlchem.com CHINA 17424 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40275 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
021-67121385 Sales-CN@TCIchemicals.com China 24560 81
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44045 61

View Lastest Price from Vinyl bromide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-08 Vinyl bromide
593-60-2
US $1.00 / KG 1KG 99% Customized career henan chemical co

Vinyl bromide Spectrum


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