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Vinyl bromide

Vinyl bromide
Vinyl bromide structure
CAS No.
593-60-2
Chemical Name:
Vinyl bromide
Synonyms
C2H3Br;R1140B1;Bromethen;NCI-C50373;SAYTEX VBR;Bromoethene;bromo-ethen;Bromethylen;Vinylbromid;-139 (lit.)
CBNumber:
CB5853922
Molecular Formula:
C2H3Br
Formula Weight:
106.95
MOL File:
593-60-2.mol

Vinyl bromide Properties

Melting point:
−139 °C(lit.)
Boiling point:
16 °C750 mm Hg(lit.)
Density 
1.517 g/mL at 25 °C(lit.)
vapor density 
3.8 (15 °C, vs air)
vapor pressure 
1551 mm Hg ( 37.8 °C)
refractive index 
n20/D 1.410
Flash point:
1 °F
storage temp. 
2-8°C
explosive limit
15%
Water Solubility 
insoluble
BRN 
1361370
Exposure limits
TLV-TWA 5 ppm (~22 mg/m3)(ACGIH); Lowest Detectable Level (NIOSH); car cinogenicity: Suspected Human Carcinogen (ACGIH), Animal Sufficient Evidence (IARC).
Stability:
Stable, but may polymerize in sunlight. Reacts violently with all types of oxidizer. Incompatible with strong oxidizing agents, peroxides, copper, copper alloys, plastics. Highly flammable.
InChIKey
INLLPKCGLOXCIV-UHFFFAOYSA-N
CAS DataBase Reference
593-60-2(CAS DataBase Reference)
EWG's Food Scores
4
FDA UNII
83NRW59KFY
NIST Chemistry Reference
Ethene, bromo-(593-60-2)
Proposition 65 List
Vinyl Bromide
EPA Substance Registry System
Vinyl bromide (593-60-2)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS07,GHS08,GHS04
Signal word  Danger
Hazard statements  H225-H302-H319-H335-H350-H280
Precautionary statements  P201-P210-P280-P308+P313-P370+P378-P403+P235-P301+P312+P330-P410+P403
Hazard Codes  F+,T,F
Risk Statements  45-12-19-36/37-22-11
Safety Statements  53-9-16-29-33-45-26
RIDADR  UN 1993 3/PG 1
WGK Germany  3
RTECS  KU8400000
3-10
Autoignition Temperature 986 °F
HazardClass  2.1
PackingGroup  II
HS Code  29033990
NFPA 704
4
2 1

Vinyl bromide price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 434191 Vinyl bromide solution 1.0 M in THF 593-60-2 100ml $77.5 2019-12-02 Buy
Sigma-Aldrich 434191 Vinyl bromide solution 1.0 M in THF 593-60-2 800ml $336 2019-12-02 Buy
TCI Chemical V0127 Vinyl Bromide (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L) 593-60-2 100mL $82 2020-06-24 Buy
Sigma-Aldrich V1902 Vinyl bromide 98% 593-60-2 100g $145 2019-12-02 Buy
Sigma-Aldrich V1902 Vinyl bromide 98% 593-60-2 900g $379 2019-12-02 Buy

Vinyl bromide Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Chemical Properties

Vinyl bromide is a colorless gas or liquid at low ambient temperature. Pleasant odor. Shipped as a liquefied compressed gas with 0.1% phenol added to prevent polymerization.

Uses

Vinyl bromide is used as a fire retardant inplastics.

Production Methods

VB can be produced by the catalytic addition of hydrogen bromide to acetylene in the presence of mercury and copper halide catalysts or by partial dehydrobromination of ethylene dibromide with alcoholic potassium hydroxide.

General Description

Boiling point 60°F. Liquid at low ambient temperatures. Specific gravity 1.51. A suspected carcinogen. Under exposure to fire or heat containers may rupture violently and rocket.

Air & Water Reactions

Highly flammable, with air forms peroxides

Reactivity Profile

VINYL BROMIDE is a light sensitive, peroxidizable monomer may initiate exothermic polymerization of the bulk material [Handling Chemicals Safely 1980.. p. 958]. Vinyl bromide will react violently with oxidants.

Health Hazard

Vapors may cause dizziness or asphyxiation without warning. Some may be toxic if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases.

Health Hazard

Inhalation of this gas at high concentrationscan produce anesthesia and kidney damage.Exposure to 2.5% concentration in air pro duced anesthetic effects in rats. A 15-minuteexposure to 10% concentration was fatal torats (ACGIH 1986). Kidney injury occurredat a 5% exposure level. Human toxicity datafor this compound are not available. The liq uid is mild to moderately irritating to theeyes.
Vinyl bromide manifested carcinogenicproperties in laboratory animals. It producedliver and blood tumors in rats and mice.Its cancer-causing effects in humans arenot known. However, on the basis of itssimilarity to vinyl chloride, it is suspectedto be a human carcinogen.

Fire Hazard

EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Silane will ignite spontaneously in air. May polymerize explosively when heated or involved in a fire. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. Can react violently with oxidzing materials. May polymerize in sunlight. To fight fire, use CO2, dry chemical, or water spray. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES and VINYL CHLORIDE.

Potential Exposure

Vinyl bromide is used as an intermediate in organic synthesis and for the preparation of plastics by polymerization and copolymerization; as a comonomer with acrylonitrile and other vinyl monomers in modacrylic fibers; in the production of flame-retardant synthetic fibers.

Carcinogenicity

Vinyl bromide is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

Shipping

UN1085 Vinyl bromide, stabilized, Hazard Class: 2.1; Labels: 2.1-Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

Incompatibilities

Vinyl bromide is a dangerous chemically unstable compound that may polymerize spontaneously in heat, sunlight and possibly exposure to UV. Dangerously reactive with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, acetylene, strong acids, strong bases, copper compounds. Add 0.1% phenol to gas to prevent polymerization.

Waste Disposal

Return refillable compressed gas cylinders to supplier. Nonrefillable cylinders should be disposed of in accordance with local, state and federal regulations. Allow remaining gas to vent slowly into atmosphere in an unconfined area or exhaust hood. Refillabletype cylinders should be returned to original supplier with any valve caps and outlet plugs secured and valve protection caps in place.

Vinyl bromide Preparation Products And Raw materials

Raw materials

Preparation Products


Vinyl bromide Suppliers

Global( 93)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22625 55
Hangzhou FandaChem Co.,Ltd.
0086 158 5814 5714 (Mobile
+86-571-56059825 fandachem@gmail.com CHINA 3268 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 30043 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23977 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28231 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 10157 58
Zhonglan Industry Co., Ltd.
(86) 531-82956570
(86) 531-82956571 sales@zhonglanindustry.com CHINA 4895 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23045 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 35434 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 20535 58

View Lastest Price from Vinyl bromide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-08 Vinyl bromide
593-60-2
US $1.00 / KG 1KG 99% Customized career henan chemical co

Vinyl bromide Spectrum


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