ChemicalBook >> CAS DataBase List >>BrettPhos Pd G3
BrettPhos Pd G3
- CAS No.
- 1470372-59-8
- Chemical Name:
- BrettPhos Pd G3
- Synonyms
- BuBrettPhos Pd G3;BrettPhos-G3-Pd;BrettPhos Pd G3;BrettPhos Pd G3 95%;BrettPhos Palladacycle Gen.3;BrettPhosPdG3 BrettPhos Pd G3;BrettPhos Pd G3 ISO 9001:2015 REACH;BrettPhosPalladacycle3rdGeneration,98%;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'...;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu
- CBNumber:
- CB62686118
- Molecular Formula:
- C48H66NO5PPdS
- Molecular Weight:
- 906.51
- MDL Number:
- MFCD22572666
- MOL File:
- 1470372-59-8.mol
- MSDS File:
- SDS
Last updated:2024-03-18 16:05:02
Melting point | 150-193°C (decomposition) |
---|---|
storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
form | Powder |
color | yellow to beige |
InChIKey | ASZHREKEHVNFFW-UHFFFAOYSA-N |
SMILES | P(C1CCCCC1)(C1CCCCC1)(C1C(=CC=C(OC)C=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H315-H319-H335 |
Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a |
WGK Germany | 3 |
HS Code | 2843909000 |
BrettPhos Pd G3 price More Price(34)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 761605 | BrettPhos Pd G3 95% | 1470372-59-8 | 1g | $308 | 2024-03-01 | Buy |
Sigma-Aldrich | 761605 | BrettPhos Pd G3 95% | 1470372-59-8 | 5g | $1310 | 2024-03-01 | Buy |
Alfa Aesar | 047250 | BrettPhos Palladacycle 3rd Generation, 98% | 1470372-59-8 | 1g | $460 | 2024-03-01 | Buy |
Alfa Aesar | 047250 | BrettPhos Palladacycle 3rd Generation, 98% | 1470372-59-8 | 5g | $1470.65 | 2024-03-01 | Buy |
Strem Chemicals | 46-0322 | Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 3] | 1470372-59-8 | 100mg | $44 | 2024-03-01 | Buy |
BrettPhos Pd G3 Chemical Properties,Uses,Production
Reaction
- Catalyst used in the regioselective synthesis of benzimidazolones via cascade C-N coupling of monosubstituted ureas.
- Catalyst used in a mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow .applications to the synthesis of functionalized heterocycles.
Uses
BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.
It may be used in the synthesis of following compounds:
- [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf.
- [Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf.
- [Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.
- Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.
General Description
BrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. BrettPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
BrettPhos Pd G3 Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 143)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 432 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 7621 | 58 |
Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 19536 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5601 | 58 |
View Lastest Price from BrettPhos Pd G3 manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2022-07-25 | BrettPhos Pd G3
1470372-59-8
|
US $1.10 / g | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | ||
2021-06-11 | Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3
1470372-59-8
|
US $10.00-10.00 / g | 1g | 0.98 | 50kg | Wuhan LPBchem Technology Co.,Ltd | ||
2020-11-16 | BrettPhos Pd G3
1470372-59-8
|
US $65.00 / KG | 1KG | 99 | 10000KG | Longyan Tianhua Biological Technology Co., Ltd |
- BrettPhos Pd G3
1470372-59-8
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3
1470372-59-8
- US $10.00-10.00 / g
- 0.98
- Wuhan LPBchem Technology Co.,Ltd
- BrettPhos Pd G3
1470372-59-8
- US $65.00 / KG
- 99
- Longyan Tianhua Biological Technology Co., Ltd
1470372-59-8(BrettPhos Pd G3)Related Search:
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BrettPhos Pd G3 95%
[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium
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Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%
BrettPhos Pd G3
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
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[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1’- biphenyl)-2-(2’-amino-1,1’-biphenyl)]palladium(II) methanesulfonate methanesulfonate
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 3]
BrettPhos Palladacycle Gen.3
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3
Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)-
BrettPhosPalladacycle3rdGeneration,98%
BrettPhos Pd G3 ISO 9001:2015 REACH
2-(2-aminophenyl)phenyl]palladio methanesulfonate, dicyclohexyl({3,6-dimethoxy-2-[2,4,6-tris(propan-2-yl)phenyl]phenyl})phosphane
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'...
BrettPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
BuBrettPhos Pd G3
BrettPhos-G3-Pd
BrettPhosPdG3 BrettPhos Pd G3
(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate[BrettPhos Pd G3]
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)-
1470372-59-8
C48H66NO5PPdS
Buchwald Ligands&Precatalysts
Buchwald Precatalysts Series
Pd