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BrettPhosPalladacycle

BrettPhosPalladacycle structure

CAS No.: 1148148-01-9

Chemical Name:: BrettPhosPalladacycle

Synonyms: BrettPhos Pd G1;BrettPhos precatalyst;BrettPhos Palladacycle;BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct;BrettPhos Palladacycle Gen. 1;chloro-(2-phenylethylamino)palladium;[2-(2-aminoethyl)phenyl]palladium(1+);(BrettPhos) palladium(II) phenethylamine chloride;Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-...;dicyclohexyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane

CBNumber:: CB52614378

Molecular Formula:: C43H63ClNO2PPd

Molecular Weight:: 798.83

MDL Number:: MFCD12545956

MOL File:: 1148148-01-9.mol

Last updated:2023-04-23 13:52:06

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BrettPhosPalladacycle Properties

Melting point	198-204 °C
form	Powder
color	white

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P305+P351+P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26

BrettPhosPalladacycle price More Price(18)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	718750	BrettPhos Pd G1, Methyl t-Butyl Ether Adduct may contain up to 1 mole equivalent of MTBE, 97%	1148148-01-9	1g	$533	2024-03-01	Buy
Sigma-Aldrich	718750	BrettPhos Pd G1, Methyl t-Butyl Ether Adduct may contain up to 1 mole equivalent of MTBE, 97%	1148148-01-9	5g	$1450	2024-03-01	Buy
Strem Chemicals	46-0267	Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II), min. 98% [BrettPhos Palladacycle Gen. 1]	1148148-01-9	100mg	$62	2024-03-01	Buy
Strem Chemicals	46-0267	Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II), min. 98% [BrettPhos Palladacycle Gen. 1]	1148148-01-9	500mg	$180	2024-03-01	Buy
Sigma-Aldrich	718750	BrettPhos Pd G1, Methyl t-Butyl Ether Adduct may contain up to 1 mole equivalent of MTBE, 97%	1148148-01-9	100mg	$34.96	2024-03-01	Buy

Product number	Packaging	Price	Buy
718750	1g	$533	Buy
718750	5g	$1450	Buy
46-0267	100mg	$62	Buy
46-0267	500mg	$180	Buy
718750	100mg	$34.96	Buy

BrettPhosPalladacycle Chemical Properties,Uses,Production

Reaction

Catalyst for cross-coupling reactions using aryl mesylates with electron-deficient anilines.
Catalyst for rapid C-N bond-forming processes at low catalyst loading.
Cross-coupling of 3-Bromo-2-aminopyridine with primary amines.

Uses

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst for:

C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines
Amination reaction
N-arylation of aminophenols

General Description

BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to ?40 °C, and can be used in a variety of cross-coupling protocols.

BrettPhosPalladacycle Preparation Products And Raw materials

Raw materials

Preparation Products

BrettPhosPalladacycle Suppliers

Global( 83)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32686	60
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-18789408387	1057@dideu.com	China	3439	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5601	58
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD.	+86-0532-8699-9256 +8615254267723	kaley@cnfdevelop.com	China	1410	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21149	58
Wuhan LPBchem Technology Co.,Ltd	+86-027-63498399 15071314134	LPBchem@163.com	CHINA	57	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	6710	58
Baoji Guokang Healthchem co.,ltd	+8615604608665 15604608665	dominicguo@gk-bio.com	CHINA	9427	58
Zhuoer Chemical Co., Ltd	02120970332; +8613524231522	sales@zhuoerchem.com	China	3015	58

Supplier	Advantage
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Shaanxi Dideu Medichem Co. Ltd	58
Richest Group Ltd	58
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD.	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
Wuhan LPBchem Technology Co.,Ltd	58
Shanghai UCHEM Inc.	58
Baoji Guokang Healthchem co.,ltd	58
Zhuoer Chemical Co., Ltd	58

View Lastest Price from BrettPhosPalladacycle manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2021-06-11	Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) /BrettPhos Pd G1 1148148-01-9	US $10.00-10.00 / g	1g	0.98	50kg	Wuhan LPBchem Technology Co.,Ltd
2020-04-22	Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II) 1148148-01-9	US $1.00 / KG	1KG	99%	20T	Shaanxi Dideu Medichem Co. Ltd
2020-01-13	Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) 1148148-01-9	US $1.00 / g	1g	Min98%	g/kg/ton	Career Henan Chemical Co

Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) /BrettPhos Pd G1
1148148-01-9
US $10.00-10.00 / g
0.98
Wuhan LPBchem Technology Co.,Ltd

Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II)
1148148-01-9
US $1.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
1148148-01-9
US $1.00 / g
Min98%
Career Henan Chemical Co

1148148-01-9(BrettPhosPalladacycle)Related Search:

Chloro(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle] XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 Xantphos Pd G3

BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 Palladacycle Gen. 3

t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct

RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1

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Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II),98% Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II), Min. 98% [BrettPhos Palladacycle] Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoeth Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-Minoethyl)phenyl]palladiuM(II),Min.98%[BrettPhosPalladacycle] (BrettPhos) palladium(II) phenethylamine chloride Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine-(2-(2-aminoethyl)phenyl)palladium(II) chloride Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ii) Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-amino CHLORO[2-(DICYCLOHEXYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL][2-(2-AMINOETHYL)PHENYL]PALLADIUM(II),MIN.98%[BRETTPHOSPALLADACYCLEGEN.1] BrettPhos Palladacycle Gen. 1 Chloride (2-dicyclohexylphosphino-3,6-dimethoxy-2 ', 4', 6 '- triisopropyl-1,1' - biphenyl) [2 - (2-aminoethyl phenyl)] palladium (II) Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) / BrettPhos Pd G1 Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]-, (SP-4-4)- Chloro[2-(dicyclohexylphosphino)-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II) Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-... BrettPhos Pd G1 / Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) (SP-4-4)-[2-[2-(Amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]palladium Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II) [BrettPhos Palladacycle] [2-(2-aminoethyl)phenyl]palladium(1+) dicyclohexyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct BrettPhos Palladacycle BrettPhos precatalyst BrettPhos Pd G1 Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine-(2-(2-aminoethyl)phenyl)palladium(II) chloride chloro-(2-phenylethylamino)palladium 1148148-01-9 C43H63ClNO2PPd C48H74ClNO3PPd Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd