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tBuXPhos-Pd-G3

tBuXPhos-Pd-G3 structure

CAS No.: 1447963-75-8

Chemical Name:: tBuXPhos-Pd-G3

Synonyms: tBuXPhos Pd G3;ditert-butyl-[2-(2,4,6-triisopropylphenyl)phenyl]phosphane;tBuXPhos Pd G3 97%;[(2-Di-tert-butylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate;tBuXPhos Palladacycle Gen.3;tBuXPhos Pd G3 tBuXPhos Pd G3;tBuXPhos Pd G3 95% (dried basis);Methanesulfonato(2-di-t-butylphosphino-2;METHANESULFONATO(2-DI-T-BUTYLPHOSPHINO-2,4,6-TRI-I-PROPYL-1,1-BIPHENY+;Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

CBNumber:: CB92686119

Molecular Formula:: C42H58NO3PPdS

Molecular Weight:: 794.38

MDL Number:: MFCD22666411

MOL File:: 1447963-75-8.mol

MSDS File:: SDS

Last updated:2024-03-18 16:05:02

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tBuXPhos-Pd-G3 Properties

Melting point	130-140°C
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
form	Powder
color	yellow
InChIKey	KKVLHKIBKWORMK-UHFFFAOYSA-N
SMILES	P(C1C=CC=CC=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C)(C(C)(C)C)C(C)(C)C

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS05,GHS07
Signal word	Danger
Hazard statements	H302-H315-H318-H335
Precautionary statements	P261-P280-P305+P351+P338
WGK Germany	3
HS Code	2843909000

tBuXPhos-Pd-G3 price More Price(29)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	762229	tBuXPhos Pd G3 95% (dried basis)	1447963-75-8	1g	$174	2024-03-01	Buy
Sigma-Aldrich	762229	tBuXPhos Pd G3 95% (dried basis)	1447963-75-8	5g	$647	2024-03-01	Buy
Strem Chemicals	46-0323	Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [t-BuXPhos Palladacycle Gen. 3]	1447963-75-8	250mg	$50	2024-03-01	Buy
Strem Chemicals	46-0323	Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [t-BuXPhos Palladacycle Gen. 3]	1447963-75-8	1g	$149	2024-03-01	Buy
Sigma-Aldrich	762229	tBuXPhos Pd G3 95% (dried basis)	1447963-75-8	250mg	$73.9	2024-03-01	Buy

Product number	Packaging	Price	Buy
762229	1g	$174	Buy
762229	5g	$647	Buy
46-0323	250mg	$50	Buy
46-0323	1g	$149	Buy
762229	250mg	$73.9	Buy

tBuXPhos-Pd-G3 Chemical Properties,Uses,Production

Physical properties

tBuXPhos-Pd-G3 is in the form of a dark grey crystalline powder.

Uses

tBuXPhos Pd G3 may be used to synthesize 4-cyano-7-azaindole from 4-chloro-7-azaindole by cyanation reaction. It may also be used for the α-arylation reaction of acetate esters at room temperature.

Reactions

Mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media.
Reactions of 1447963-75-8

General Description

tBuXPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. tBuXPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

storage

tBuXPhos Pd G3 should be stored in an airtight, dry and low temperature.

tBuXPhos-Pd-G3 synthesis

Synthesis of tBuXPhos-Pd-G3 from (2'-AMino-1,1'-biphenyl-2-yl)MethanesulfonatopalladiuM(II) diMer and 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL

tBuXPhos-Pd-G3 Preparation Products And Raw materials

Raw materials

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL (2'-AMino-1,1'-biphenyl-2-yl)MethanesulfonatopalladiuM(II) diMer

Preparation Products

tBuXPhos-Pd-G3 Suppliers

Global( 126)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Alfa Chemistry	+1-5166625404	Info@alfa-chemistry.com	United States	21317	58
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	+undefined-027-81388558 +undefined086-1878077615	huahandingcheng@sina.com	China	342	58
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	424	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15932	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32686	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-18789408387	1057@dideu.com	China	3439	58
Jinan Liheng Biotechnology Co., Ltd.	15865262812	info@lihengpharm.com	CHINA	938	58

Supplier	Advantage
Alfa Chemistry	58
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
Shanghai Daken Advanced Materials Co.,Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Accela ChemBio Inc.	58
Chongqing Chemdad Co., Ltd	58
Shaanxi Dideu Medichem Co. Ltd	58
Jinan Liheng Biotechnology Co., Ltd.	58

View Lastest Price from tBuXPhos-Pd-G3 manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2021-06-11	Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl）palladium(II) / tBuXPhos Pd G3 1447963-75-8	US $10.00-10.00 / g	1g	0.98	50kg	Wuhan LPBchem Technology Co.,Ltd
2020-11-16	tBuXPhos Pd G3 1447963-75-8	US $180.00 / KG	1KG	99	10000KG	Longyan Tianhua Biological Technology Co., Ltd
2020-04-19	Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 1447963-75-8	US $1.00 / KG	1KG	99%	20T	Shaanxi Dideu Medichem Co. Ltd

Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl）palladium(II) / tBuXPhos Pd G3
1447963-75-8
US $10.00-10.00 / g
0.98
Wuhan LPBchem Technology Co.,Ltd

tBuXPhos Pd G3
1447963-75-8
US $180.00 / KG
99
Longyan Tianhua Biological Technology Co., Ltd

Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
1447963-75-8
US $1.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

1447963-75-8(tBuXPhos-Pd-G3)Related Search:

XPhos Pd G3 XantPhos Pd G4 Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) SPhos Palladacycle Gen. 4 XPhos Pd G4

Xantphos Pd G3 BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2

BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3

SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2

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[2'-(Amino)[1,1'-biphenyl]-2-yl][bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [t-BuXPhos Palladacycle] Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) METHANESULFONATO(2-DI-T-BUTYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[T-BUXPHOSPALLADACYCLEGEN.3] Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato-κO)- tBuXPhos Palladacycle Gen.3 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) [t-BuXPhos Palladacycle] Methanesulfonato(2-di-t-butylphosphino-2 tBuXPhos Pd G3 tBuXPhos Pd G3 Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl）palladium(II) / tBuXPhos Pd G3 tBuXPhos Pd G3 95% (dried basis) tBuXPhos Pd G3 / Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) [(2-Di-tert-butylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate tBuXPhos Pd G3 tBuXPhos Pd G3 97% ditert-butyl-[2-(2,4,6-triisopropylphenyl)phenyl]phosphane METHANESULFONATO(2-DI-T-BUTYLPHOSPHINO-2,4,6-TRI-I-PROPYL-1,1-BIPHENY+ Methanesulfonato[(2-Di-tert-butylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 1447963-75-8 C42H58NO3PPdS C29H45PC13H13NO3PdS Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd