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BrettPhos Pd G3

BrettPhos Pd G3 Structure
BrettPhos Pd G3 structure
CAS No.
1470372-59-8
Chemical Name:
BrettPhos Pd G3
Synonyms
BuBrettPhos Pd G3;BrettPhos-G3-Pd;BrettPhos Pd G3;BrettPhos Pd G3 95%;BrettPhos Palladacycle Gen.3;BrettPhosPdG3 BrettPhos Pd G3;BrettPhos Pd G3 ISO 9001：2015 REACH;BrettPhosPalladacycle3rdGeneration,98%;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'...;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu
CBNumber:
CB62686118
Molecular Formula:
C48H66NO5PPdS
Molecular Weight:
906.51
MDL Number:
MFCD22572666
MOL File:
1470372-59-8.mol
MSDS File:
SDS
Last updated:2024-03-18 16:05:02
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BrettPhos Pd G3 Properties

Melting point 150-193°C (decomposition)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form Powder
color yellow to beige
InChIKey ASZHREKEHVNFFW-UHFFFAOYSA-N
SMILES P(C1CCCCC1)(C1CCCCC1)(C1C(=CC=C(OC)C=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
WGK Germany  3
HS Code  2843909000

BrettPhos Pd G3 price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 761605 BrettPhos Pd G3 95% 1470372-59-8 1g $308 2024-03-01 Buy
Sigma-Aldrich 761605 BrettPhos Pd G3 95% 1470372-59-8 5g $1310 2024-03-01 Buy
Alfa Aesar 047250 BrettPhos Palladacycle 3rd Generation, 98% 1470372-59-8 1g $460 2024-03-01 Buy
Alfa Aesar 047250 BrettPhos Palladacycle 3rd Generation, 98% 1470372-59-8 5g $1470.65 2024-03-01 Buy
Strem Chemicals 46-0322 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 3] 1470372-59-8 100mg $44 2024-03-01 Buy
Product number Packaging Price Buy
761605 1g $308 Buy
761605 5g $1310 Buy
047250 1g $460 Buy
047250 5g $1470.65 Buy
46-0322 100mg $44 Buy

BrettPhos Pd G3 Chemical Properties,Uses,Production

Reaction

  1. Catalyst used in the regioselective synthesis of benzimidazolones via cascade C-N coupling of monosubstituted ureas.
  2. Catalyst used in a mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow .applications to the synthesis of functionalized heterocycles.
Reactions of 1470372-59-8

Uses

BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.
It may be used in the synthesis of following compounds:

  • [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf.
  • [Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf.
  • [Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.
  • Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.

General Description

BrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. BrettPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.


BrettPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

BrettPhos Pd G3 Suppliers

Global( 142)Suppliers
Supplier Tel Email Country ProdList Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 425 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 16233 58
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3012 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32715 60
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Jinan Carbotang Biotech Co.,Ltd. 		+8615866703830 figo.gao@foxmail.com China 7154 58
Accela ChemBio Inc. 		(+1)-858-699-3322 info@accelachem.com United States 19965 58
Chongqing Chemdad Co., Ltd 		+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39916 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5601 58
Supplier Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Jinan Carbotang Biotech Co.,Ltd. 		58
Accela ChemBio Inc. 		58
Chongqing Chemdad Co., Ltd 		58
Richest Group Ltd 		58

View Lastest Price from BrettPhos Pd G3 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
BrettPhos Pd G3 pictures 2022-07-25 BrettPhos Pd G3
1470372-59-8
 US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3 pictures 2021-06-11 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3
1470372-59-8
 US $10.00-10.00 / g 1g 0.98 50kg Wuhan LPBchem Technology Co.,Ltd
BrettPhos Pd G3 pictures 2020-11-16 BrettPhos Pd G3
1470372-59-8
 US $65.00 / KG 1KG 99 10000KG Longyan Tianhua Biological Technology Co., Ltd
  • BrettPhos Pd G3 pictures
  • BrettPhos Pd G3
    1470372-59-8
  • US $65.00 / KG
  • 99
  • Longyan Tianhua Biological Technology Co., Ltd

1470372-59-8(BrettPhos Pd G3)Related Search:

XantPhos Pd G4 Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) tBuXPhos-Pd-G3 XPhos Pd G3 SPhos Palladacycle Gen. 4
XPhos Pd G4 Xantphos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2
BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3
SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2

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Methanesulfonato2-Dicyclohexylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) BrettPhos Pd G3 95% [2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu [2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle] Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% BrettPhos Pd G3 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1’- biphenyl)-2-(2’-amino-1,1’-biphenyl)]palladium(II) methanesulfonate methanesulfonate Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 3] BrettPhos Palladacycle Gen.3 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3 Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)- BrettPhosPalladacycle3rdGeneration,98% BrettPhos Pd G3 ISO 9001：2015 REACH 2-(2-aminophenyl)phenyl]palladio methanesulfonate, dicyclohexyl({3,6-dimethoxy-2-[2,4,6-tris(propan-2-yl)phenyl]phenyl})phosphane Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'... BrettPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) BuBrettPhos Pd G3 BrettPhos-G3-Pd BrettPhosPdG3 BrettPhos Pd G3 (2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate[BrettPhos Pd G3] Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 1470372-59-8 C48H66NO5PPdS Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd