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Zirconium oxychloride

Physical Properties Uses Preparation Toxicity
Zirconium oxychloride
Zirconium oxychloride structure
CAS No.
7699-43-6
Chemical Name:
Zirconium oxychloride
Synonyms
ZROCL2;nci-c60811;chlorozirconyl;ZIRCONYL CHLORIDE;ZIRCONIUM CHLORIDE;Zirconium oxychlorid;dichlorooxo-zirconiu;Dichlorooxozirconium;ZIRCONIUM OXYCHLORIDE;zirconiumchlorideoxide
CBNumber:
CB6470074
Molecular Formula:
Cl2OZr
Formula Weight:
178.13
MOL File:
7699-43-6.mol

Zirconium oxychloride Properties

Melting point:
−15 °C
Density 
1.344 g/mL at 25 °C
form 
Liquid
color 
Clear colorless
Merck 
13,10237
Stability:
Stable. Incompatible with strong oxidizing agents, water, moisture, alkali metals.
CAS DataBase Reference
7699-43-6(CAS DataBase Reference)
EPA Substance Registry System
Zirconium, dichlorooxo- (7699-43-6)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H290-H314-H335
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C,Xn
Risk Statements  23-34-37-20/21/22-36/38
Safety Statements  26-36-45-36/37/39-36/37
RIDADR  UN 1789
WGK Germany  1
HazardClass  8
PackingGroup  III

Zirconium oxychloride price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 464198 Zirconyl chloride solution 30% in hydrochloric acid 7699-43-6 250ml $223 2019-12-02 Buy

Zirconium oxychloride Chemical Properties,Uses,Production

Physical Properties

The octahydrate is a white silky solid; tetragonal crystals consisting of tetramers; effloresces; refractive index 1.552; loses six water molecules at 150°C; becomes anhydrous at 210°C; decomposes at 400°C; soluble in water; aqueous solution acidic; also soluble in alcohol and ether; slightly soluble in hydrochloric acid.

Uses

Zirconyl chloride is used to make pigment toners and improve properties of color lakes of acid and basic dyes. Also, it is used to prepare body deodorants and antiperspirant, water repellant, dye precipitant, catalysts, and many zirconium compounds.

Preparation

The compound is prepared by dissolving zirconium tetrachloride, ZrCl4, or sodium zirconate, Na4ZrO4, in hydrochloric acid solution followed by evaporation to obtain crystals of octahydrate.
Also, the compound can be prepared by reacting zirconium tetrachloride with chlorine oxide:
ZrCl4 + Cl2O → ZrOCl2 + 2Cl2

Toxicity

Moderately toxic by ingestion, intraperitoneal and subcutaneous routes.
LD50 (intraperitioneal) (rat): 400mg/kg

Chemical Properties

Zirconium oxychloride exists as white silky crystals, soluble in water and alcohol. With water, the octahydrate is formed as tetragonal white needles. It is extremely hygroscopic and decomposes to zirconium tetrachloride (ZrCl4) and zirconium oxide (ZrO2) at 250 C. It is also formed as the octahydrate [13520-92-8] as white, tetrahedral crystals that are very soluble in water, ethyl alcohol, ether, and methanol, among others, but only slightly soluble in hydrochloric acid. When heated to decomposition, it emits toxic fumes of hydrogen chloride.

Uses

Textile, cosmetic and grease additive, antiperspirant, water repellents, chemical reagent, zirconium salts, in lakes and toners of acidic and basic dyes, oil-field acidizing aid.

Reactivity Profile

Acidic salts, such as Zirconium oxychloride, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Health Hazard

Has only a mild pharmacological action. Inhalation of dust may irritate nose and throat. Contact with eyes or skin causes irritation.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of Cl-. Used as an antiperspirant. See also ZIRCONIUM COMPOUNDS and CHLORIDES.

Purification Methods

Crystallise it repeatedly from 8M HCl to give ZrOCl2.8H2O (see below). On drying, ZrOCl2.6H2O, m 150o, is formed. The product is not free from hafnium. [Blumenthal J Chem Ed 39 607 1962.]

Zirconium oxychloride Preparation Products And Raw materials

Raw materials

Preparation Products


Zirconium oxychloride Suppliers

Global( 109)Suppliers
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Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21685 58
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View Lastest Price from Zirconium oxychloride manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-08-01 Zirconium oxychloride
7699-43-6
US $1.00 / ASSAYS 1ASSAYS 40% 100MT Henan Xiangtong Chemical Co., Ltd.
2018-09-05 Zirconium oxychloride
7699-43-6
US $1.00 / G 100G 99.9% 50000tons Hebei Ruishun Trade Co.,Ltd

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