1,6-HEXANEDIAMINE
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1,6-HEXANEDIAMINE Properties
- Melting point:
- 42-45 °C(lit.)
- Boiling point:
- 204-205 °C
- Density
- 0.89 g/mL at 25 °C(lit.)
- vapor density
- 4 (vs air)
- vapor pressure
- 0.25 hPa (20 °C)
- refractive index
- n
20/D 1.439(lit.)
- Flash point:
- 201 °F
- storage temp.
- 2-8°C
- solubility
- alcohol: soluble(lit.)
- form
- Solution
- pka
- 11.857(at 0℃)
- color
- White, may discolor during storage
- PH
- 12.4 (100g/l, H2O, 25℃)
- explosive limit
- 0.9-7.6%(V)
- Water Solubility
- 490 g/L (20 ºC)
- Sensitive
- Hygroscopic
- Merck
- 14,4695
- BRN
- 1098307
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, organic materials.
- CAS DataBase Reference
- 124-09-4(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,6-Hexanediamine(124-09-4)
- EPA Substance Registry System
- 1,6-Hexanediamine(124-09-4)
SAFETY
- Risk and Safety Statements
- Hazard and Precautionary Statements (GHS)
Hazard Codes | C | ||
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Risk Statements | 34-37-21/22-20/21/22 | ||
Safety Statements | 26-36/37/39-45-22-27 | ||
RIDADR | UN 2735 8/PG 3 |
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WGK Germany | 3 |
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RTECS | MO1180000 |
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F | 10-34 | ||
Autoignition Temperature | 305 °C | ||
TSCA | Yes | ||
HS Code | 2921 22 00 | ||
HazardClass | 8 | ||
PackingGroup | III | ||
Hazardous Substances Data | 124-09-4(Hazardous Substances Data) | ||
Toxicity | LD50 orally in Rabbit: 850 mg/kg LD50 dermal Rabbit 1110 mg/kg |
Symbol(GHS): |
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Hazard statements: |
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Precautionary statements: |
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1,6-HEXANEDIAMINE price More Price(15)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 422002 | Hexamethylenediamine technical grade, 70% | 124-09-4 | 1l | $59.3 | 2018-11-13 | Buy |
Sigma-Aldrich | 422002 | Hexamethylenediamine technical grade, 70% | 124-09-4 | 2.5l | $132 | 2018-11-13 | Buy |
TCI Chemical | D0095 | 1,6-Diaminohexane >99.0%(GC)(T) | 124-09-4 | 25g | $20 | 2018-11-22 | Buy |
TCI Chemical | D0095 | 1,6-Diaminohexane >99.0%(GC)(T) | 124-09-4 | 500g | $61 | 2018-11-22 | Buy |
Alfa Aesar | A14212 | 1,6-Diaminohexane, 98+% | 124-09-4 | 100g | $17.7 | 2018-11-13 | Buy |
1,6-HEXANEDIAMINE Chemical Properties,Uses,Production
Chemical Properties
White to cream solidChemical Properties
HMDA is a hygroscopic, colorless solid (pellets or flakes). Weak, fishy odor.Uses
Formation of high polymers, e.g., nylon 66.Definition
ChEBI: A C6 alkane-alpha,omega-diamine.General Description
A clear colorless liquid. Burns although some effort is required to ignite. Soluble in water. Corrosive to metals and tissue. Produces toxic oxides of nitrogen during combustion. Used to make nylon.Air & Water Reactions
Water soluble.Reactivity Profile
HEXAMETHYLENEDIAMINE is hygroscopic. Can react with strong oxidizing materials. Incompatible with acids, acid chlorides and acid anhydrides. Also incompatible with ketones, aldehydes, nitrates, phenols, isocyanates, monomers and chlorinated compounds .Hazard
Toxic by ingestion, strong irritant to tissue. Combustible.Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.Fire Hazard
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.Contact allergens
Hexamethylenediamine is used with adipic acid in the synthesis of polyamide plastics.Potential Exposure
HMDA is used as a textile intermedi ate; a raw material for nylon fiber and plastics; in wet strength resins; in the manufacture of oil-modified and moisture-area types of urethane coatings; in the manufac ture of polyamides for printing inks, dimer acids, and tex tiles; and as an oil and lubricant additive (probably as a corrosion inhibitor); as boiler feed water additives; also used in paints and as a curing agent for epoxy resins; mak ing adhesives.First aid
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, includ ing resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medi cal attention. If convulsions are not present, give a glass or two of water or milk to dilute the substance. Do not induce vomiting. Assure that the person’s airway is unobstructed and contact a hospital or poison center immediately for advice on whether or not to induce vomiting. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.Shipping
UN2280 Hexamethylenediamine, solid, Hazard class: 8; Labels: 8-Corrosive material. UN1783 Hexamethylenediamine, solution, Hazard class: 8; Labels: 8-Corrosive material.Purification Methods
Crystallise it in a stream of nitrogen. It sublimes in a vacuum. [Beilstein 4 IV 1320.]Incompatibilities
May form explosive mixture with air. The aqueous solution is a strong base and a strong reducing agent. Reacts violently with oxidizers, acids, acid chlorides; acid anhydrides; carbon dioxide acids. Reacts on contact with water forming carbon dioxide. Polymermizes in temperatures >195℃.Reacts with ethylene dichloride, organic anhy drides, isocyanates, vinyl acetate, acrylates, substituted allyls, alkylene oxides, epichlorohydrin, ketones, aldehydes, alco hols, glycols, phenols, cresols, caprolactum solution. Attacks aluminum, copper, lead, tin, zinc and alloys. Absorbs carbon dioxide and water from air. Store under Nitrogen.Waste Disposal
Incineration; incinerator equipped with a scrubber or thermal unit to reduce nitrogen oxides emissions.1,6-HEXANEDIAMINE Preparation Products And Raw materials
Raw materials
Adipic acid
Silica gel
1,3-BUTADIENE
Nickel
Hexylene Glycol
1,4-Dicyanobutane
Nickel Iron (80:20wt%) in cone shaped (refer to drawing)
Caprolactam
NICKEL IRON
Celite
Preparation Products
Phosphatizing agent
antibiotic finishing agent for fabric
Hexamethylene Diisocyanate
ion exchange hollow yarn
Hexamethyleneimine
Cross-linking agent DE
1,6-HEXANEDIAMINE Suppliers
Global( 206)Suppliers
Supplier | Tel | Fax | Country | ProdList | Advantage | |
---|---|---|---|---|---|---|
Henan DaKen Chemical CO.,LTD. | +86-371-55531817 |
info@dakenchem.com | CHINA | 22059 | 58 | |
Henan Tianfu Chemical Co.,Ltd. | 0371-55170693 |
0371-55170693 | info@tianfuchem.com | CHINA | 20795 | 55 |
Mainchem Co., Ltd. | +86-0592-6210733 |
+86-0592-6210733 | sales@mainchem.com | CHINA | 32764 | 55 |
Hangzhou FandaChem Co.,Ltd. | 0086 158 5814 5714 (Mobile; WhatsApp; Telegram) |
+86-571-56059825 | fandachem@gmail.com | CHINA | 1955 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | 86-0551-65418684 18949823763 |
86-0551-65418684 | info@tnjchem.com | China | 1582 | 55 |
Kono Chem Co., Ltd | +86-132 8924 6953 |
info@konochemical.com | CHINA | 2164 | 58 | |
Nanjing Lanbai Chemical Co., Ltd. | +86 (25) 8549-9326,8549-9316,15366059326 13813836665 |
+86 (25) 8549-9357 | lanbaichem@163.com | China | 141 | 57 |
Shanghai Aladdin Bio-Chem Technology Co.,LTD | 021-20337333/400-620-6333 |
021-50323701 | sale@aladdin-e.com | China | 25127 | 65 |
J & K SCIENTIFIC LTD. | 400-666-7788 +86-10-82848833 |
+86-10-82849933 | jkinfo@jkchemical.com;market6@jkchemical.com | China | 96815 | 76 |
Meryer (Shanghai) Chemical Technology Co., Ltd. | +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing) |
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) | sh@meryer.com | China | 40399 | 62 |
124-09-4(1,6-HEXANEDIAMINE)Related Search:
N,N,N',N'-teramethyl-1,6-hexamethylenediamine 4,4'-Bipiperidine dihydrochloride Chlorhexidine Oxytetracycline dihydrate HEXAMETHONIUM BROMIDE 5-AMINO-2,2,4-TRIMETHYL-1-CYCLOPENTANEMETHYLAMINE, MIXTURE OF ISOMERS,99% Adipic dihydrazide CALYCANTHINE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE BIS(HEXAMETHYLENE)TRIAMINE 1,2-Diaminocyclohexane 1,2-Cyclohexylenedinitrilotetraacetic acid N,N'-DIMETHYL-1,6-HEXANEDIAMINE 1,6-HEXAMETHYLENEDIAMINE-N,N,N',N'-TETRACETIC ACID ADIPAMIDE Hexamethylene Diisocyanate N,N'-DIACETYL-1,6-DIAMINOHEXANE 1,6-DIISOCYANOHEXANE
- 1,6-diamino-hexan
- 1,6-Hexamethylenediamine
- H2N(CH2)6NH2
- hexamethylenediamine(1,6-hexanediamine)
- hexamethylenediamine,solid
- Hexylenediamine
- NCI-C61405
- Hexamethylendiamine
- 1,6-Diaminohexane 1 M Solution
- 1,6-Hexanediamine,~99%
- 1,6-Hexanediamine, 98+%
- 1,6-Diaminlhexane
- 1,6-Hexylenediamime
- 1,6-DIAMINOHEXANE (1,6-HEXANEDIAMINE )
- 1,6-Hexanediamine, 60 wt % aqueous soln.
- 1,6-Hexanediamine, 99.5+%
- Hexamethylenediamine, solution.
- HEXANEDIAMINE
- Hexamethylendiamin
- 1,6-Diaminohexane, 98+%
- 1,6-Diaminohexane solution, Additive Screening Solution 34/Fluka kit no 78374
- 1,6-Hexanediamine, Hexamethylenediamine
- 1,6-Hexanediamine Hexamethylenediamine 1,6-Diaminohexane
- Hexamethylenediamine,1,6-Diaminohexane, 1,6-Hexanediamine
- 1,6-DIAMINO-n-HEXANE, CRYST
- 1,6-Hexamethylenedia
- Hexamethylene Diamine (60% Aq)
- Hexamethylene Diamine (80% Aq)
- 1,6-HexanediaMine, 99.5+% 100GR
- 1,6-HexanediaMine, 99.5+% 1KG
- 1,6-HexanediaMine, 99.5+% 500GR
- 1,6-DIAMINOHEXANE FOR SYNTHESIS
- 1,6-HexanediaMine, 70 Percent Solution in Water
- 1,6-HexanediaMine, Reagent
- 124094
- NH2CH26NH2
- AMINE
- 伪,蠅-Bifunctional Alkanes
- 伪,蠅-Alkanediamines
- Monofunctional & 伪,蠅-Bifunctional Alkanes
- Building Blocks
- Organic Building Blocks
- 124-09-4
- HMDA
- HEXAMETHYLENEDIAMINE
- 1,6-DIAMINOHEXANE
- 1,6-DIAMINO-N-HEXANE
- 1,6-HEXANEDIAMINE
- 1,6-Hexylenediamine
- RARECHEM AL BW 0080
- HexaMethylenediaMine 98%
- 1,6-Diaminohexane solution
- Additive Screening Solution 34/Fluka kit no 78374
- Hexamethylenediamine technical grade, 70%
- Hexamethylenediamine 〔1,6-Diaminohexane〕
- NSC 9257
- Hexamethylene diamine (HMDA)
- 1,6-Diaminohexane 99.7%