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ALLYLIDENE DIACETATE

CAS No.
869-29-4
Chemical Name:
ALLYLIDENE DIACETATE
Synonyms
SD-345;shell345;diacetoxy;Shell 345;shellsd345;Shell SD 345;SD 345 (Ester);Diacetoxypropene;allylideneacetate;crolein diacetate
CBNumber:
CB7260131
Molecular Formula:
C7H10O4
Molecular Weight:
158.15
MDL Number:
MFCD00008708
MOL File:
869-29-4.mol
Last updated:2023-05-15 10:43:20

ALLYLIDENE DIACETATE Properties

Melting point -37.6°C
Boiling point 180°C (estimate)
Density 1.0760
refractive index 1.4193 (estimate)
CAS DataBase Reference 869-29-4(CAS DataBase Reference)
FDA UNII 5VDZ4FX754
EPA Substance Registry System 2-Propene-1,1-diol diacetate (869-29-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS06
Signal word  Danger
Hazard statements  H331-H315-H300-H335-H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P261-P271-P304+P340-P311-P321-P403+P233-P405-P501-P264-P270-P301+P310-P321-P330-P405-P501-P264-P280-P302+P352-P321-P332+P313-P362
Risk Statements  36/37/38
Safety Statements  26-36/37/39
RIDADR  2810
HazardClass  6.1(a)
PackingGroup  II
NFPA 704
2
1

ALLYLIDENE DIACETATE price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC A544513 AllylideneDiacetate 869-29-4 2.5g $330 2021-12-16 Buy
American Custom Chemicals Corporation CHM0005591 1,1-DIACETOXY-2-PROPENE 95.00% 869-29-4 100G $3396.65 2021-12-16 Buy
American Custom Chemicals Corporation CHM0005591 1,1-DIACETOXY-2-PROPENE 95.00% 869-29-4 250G $6422.58 2021-12-16 Buy
American Custom Chemicals Corporation CHM0005591 1,1-DIACETOXY-2-PROPENE 95.00% 869-29-4 500G $8154.27 2021-12-16 Buy
Product number Packaging Price Buy
A544513 2.5g $330 Buy
CHM0005591 100G $3396.65 Buy
CHM0005591 250G $6422.58 Buy
CHM0005591 500G $8154.27 Buy

ALLYLIDENE DIACETATE Chemical Properties,Uses,Production

Uses

Allylidene Diacetate is a fungicide useful for the control of pea root rot and effective against Phytophthora palmivora. It may also be useful in the formation of vitamin C conjugate of acrolein.

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 1765, 1983 DOI: 10.1021/jo00158a036

Purification Methods

Check the NMR spectrum. If it is not satisfactory, then add Ac2O and a drop of conc H2SO4 and heat at 50o for 10minutes. Then add anhydrous NaOAc (ca 3g/ 100g of liquid) and fractionate. Note that it forms an azeotrope with H2O, so do not add H2O at any time. It is a highly flammable and TOXIC liquid; keep away from the skin. [Smith et al. J Am Chem Soc 73 5282 1951, Beilstein 2 H 154, 2 I 72, 2 III 356, 2 IV 291.]

ALLYLIDENE DIACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

ALLYLIDENE DIACETATE Suppliers

Global( 26)Suppliers
Supplier Tel Email Country ProdList Advantage
Golden Pharma Co., Limited
+undefined18958062155 sales@zjgoldpharm.com China 5905 58
SUZHOU SENFEIDA CHEMICAL CO.,LTD
+86-0512-83500002 +8615195660023 sales@senfeida.com China 5100 58
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43348 58
Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32360 55
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 17691182729 18161915376 1046@dideu.com China 10008 58
ALLYLIDENE DIACETATE ACROLEIN DIACETATE 1,1-DIACETOXY-2-PROPENE 2-PROPENYLIDENE DIACETATE 2-PROPENE-1,1-DIOL DIACETATE 3,3-DIACETOXY-1-PROPENE ,3-Diacetoxy-1-propene 1-(Acetyloxy)-2-propenyl acetate 1,1-Diacetoxypropene-2 2-Propenal, monohydrate, diacetate 2-Propentyl diacetate 3,3-Diacetoxypropene Acrolein diacetyl acetal Acrolein hydrate diacetate Acrolein, monohydrate, diacetate Allylidene acetate allylideneacetate cetic acid 1-acetoxy-allyl ester crolein diacetate diacetoxy Diacetoxypropene SD 345 (Ester) SD-345 Shell 345 Shell SD 345 shell345 shellsd345 1-acetyloxyprop-2-enyl acetate 1-acetyloxyprop-2-enyl ethanoate acetic acid 1-acetoxyallyl ester 2-Propene-1,1-diol,1,1-diacetate 869-29-4 monomer