ChemicalBook >> CAS DataBase List >>DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL
DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL
- CAS No.
- 31469-15-5
- Chemical Name:
- DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL
- Synonyms
- MTDA;((1-Methoxy-2-Methylprop-1-en-1-yl)oxy)triMethylsilane;1-Methoxy-1-tri;DIMETHYLKETENE METHYL;organosilicon monomer;1-METHOXY-2-METHYL-1-TRIMETHYL-;1-METHOXY-1-TRIMETHYLSILOXY-2-METHYLPROPENE;METHYL TRIMETHYLSILYL DIMETHYLKETENE ACETAL;DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL;1-methoxy-2-methyl-1-trimethylsiloxypropane
- CBNumber:
- CB7339664
- Molecular Formula:
- C8H18O2Si
- Molecular Weight:
- 174.31
- MDL Number:
- MFCD00010232
- MOL File:
- 31469-15-5.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Boiling point | 35 °C15 mm Hg(lit.) |
|---|---|
| Density | 0.858 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 58 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | freely sol organic solvents. |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.858 |
| Water Solubility | Hydrolyzes in water. |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | Moisture Sensitive |
| BRN | 1362893 |
| Stability | Moisture and Acid Sensitive |
| CAS DataBase Reference | 31469-15-5(CAS DataBase Reference) |
| EPA Substance Registry System | Silane, [(1-methoxy-2-methyl-1-propenyl)oxy]trimethyl- (31469-15-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 10-36/37/38 | |||||||||
| Safety Statements | 16-26-36 | |||||||||
| RIDADR | UN 3271 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 274585 | Methyl trimethylsilyl dimethylketene acetal 95% | 31469-15-5 | 5g | $61.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 274585 | Methyl trimethylsilyl dimethylketene acetal 95% | 31469-15-5 | 25g | $112.4 | 2024-03-01 | Buy |
| TCI Chemical | D1789 | Dimethylketene Methyl Trimethylsilyl Acetal >95.0%(GC) | 31469-15-5 | 5mL | $55 | 2024-03-01 | Buy |
| TCI Chemical | D1789 | Dimethylketene Methyl Trimethylsilyl Acetal >95.0%(GC) | 31469-15-5 | 25mL | $161 | 2024-03-01 | Buy |
| Alfa Aesar | L06931 | 1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, 97% | 31469-15-5 | 5g | $68.65 | 2024-03-01 | Buy |
DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL Chemical Properties,Uses,Production
Chemical Properties
Clear colorless liquid
Physical properties
bp 35 °C/15 mmHg; d 0.858 g cm?3.
Uses
1-Methoxy-2-methyl-1-(trimethylsilyloxy) propene is widely used as functional equivalent of enolate of methyl isobutyrate; ester enolate surrogate in electrophilic reactions including alkylation, aldol reaction, Michael reaction, initiator for group transfer polymerization of acrylates, nitroarylation, oxidation, dimerization, and cycloadditions.
Uses
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.
Preparation
The title compound is a prototypical ketene silyl acetal (KSA) that can been prepared by either of the two most commonly employed methods: (a) deprotonation of the |á-hydrogen of an ester followed by silylation (1),16 and (b) metal-catalyzed hydrosilylation of |á,|?-unsaturated esters(2).
Purification Methods
Add Et2O, wash with cold H2O, dry (Na2SO4), filter, evaporate Et2O, and distil the oily residue in a vacuum. [Ainsworth et al. J Organometal Chem 46 59 1972.]
DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL Preparation Products And Raw materials
Global( 169)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15932 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 | info@konochemical.com | China | 2995 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
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| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10297 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| WinWin Chemical CO., Limited | +86-0577-64498589 +8615325081899 | sales@win-winchemical.com | China | 13854 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
View Lastest Price from DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-10 | DIMETHYLKETENE METHYL
31469-15-5
|
US $7.00 / KG | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- DIMETHYLKETENE METHYL
31469-15-5
- US $7.00 / KG
- 99%
- Career Henan Chemical Co
31469-15-5(DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL)Related Search:
[(1-METHOXY-2-METHYL-1-PROPENYL)OXY]TRIMETHYLSILANE
1-METHOXY-2-METHYL-1-(TRIMETHYLSILOXY)PROPENE
DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL
METHYL TRIMETHYLSILYL DIMETHYLKETENE ACETAL
Silane,[(1-methoxy-2-methyl-1-propen-1-yl)oxy]trimethyl-
1-Methoxy-1-trimethylsiloxy-2-methyl-1-propene~Methyl trimethylsilyl dimethylketene acetal~MTDA
1-METHOXY-2-METHYL-1-TRIMETHYL-
1-METHOXY-1-(TRIMETHYLSILOXY)-2-METHYL-1-PROPENE
1-METHOXY-1-TRIMETHYLSILOXY-2-METHYLPROPENE
Silane, ((1-methoxy-2-methyl-1-propenyl)oxy)trimethyl-
Methyl Trimethylsiliyl dimethyl ketene acetal
1-methoxy-2-methyl-1-trimethylsiloxypropane
(1-Methoxy-2-methyl-1-propenyloxy)trimethylsilane, MTDA
(1-Methoxy-2-methyl-1-propenyloxy)trimethylsilane, 1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, MTDA
(1-Methoxy-2-methyl-1-propenyl)(trimethylsilyl) ether
(Trimethylsilyl)(1-methoxy-2-methyl-1-propenyl) ether
1-[(Trimethylsilyl)oxy]-1-methoxy-2-methyl-1-propene
2-Methyl-1-(trimethylsiloxy)-1-methoxy-1-propene
1-Methoxy-1-(triMethylsilyloxy)-2-Methyl-1-propene
(1-Methoxy-2-Methylprop-1-enyloxy)triMethylsilane
1-Methoxy-1-tri
Methyl triMethylsilyl diMethylketene acetal 95%
(1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
DIMETHYLKETENE METHYL
organosilicon monomer
DimethylketeneMethylTrimethylsilylAcetal>
1-Methoxy-2-methyl-1-(trimethylsilyloxy)propene
((1-Methoxy-2-Methylprop-1-en-1-yl)oxy)triMethylsilane
MTDA
31469-15-5
CH32CCOCH3OSiCH33
Building Blocks
Oxygen Compounds
Acetals/Ketals/Ortho Esters
Enol Ethers
Organic Building Blocks
Si-O Compounds
Silicon Compounds (for Synthesis)
Vinylsilanes, Allylsilanes
Monoalkoxysilanes
Si (Classes of Silicon Compounds)
Monoalkoxysilanes
Si (Classes of Silicon Compounds)
Silicon Compounds (for Synthesis)
Si-O Compounds
Synthetic Organic Chemistry
Vinylsilanes, Allylsilanes